Rosin esters and compositions thereof
View Patent ↗Rosin esters are provided. The rosin esters can exhibit improved color (e.g., the rosin ester can have a neat Gardner color of 8.5 or less), improved oxidative stability (e.g., when 1000 ppm or less of an antioxidant is present in combination with the rosin ester, the rosin ester can exhibit an oxidative-induction time at 130° C. of at least 75 minutes), improved color stability (e.g., the rosin ester can exhibit less than a 10% change in neat Gardner color when heated to a temperature of 160° C. for a period of three hours), or combinations thereof. Also provided polymeric compositions comprising the rosin esters, as well as methods of making the rosin esters.
1. A rosin ester comprising at least 70% by weight of an esterified dehydroabietic acid and an esterified dihydroabietic acid, wherein, when 1000 ppm or less of an antioxidant is present in combination with the rosin ester, the rosin ester exhibits an oxidative-induction time at 130° C. of at least 75 minutes, as measured using the methods specified in ASTM D5483-05(2010) wherein the rosin ester has a weight average molecular weight of at least 800 g/mol as determined using gel permeation chromatography as determined by ASTM D5296-05.
2. The rosin ester of claim 1 , wherein the weight ratio of the esterified dehydroabietic acid to the esterified dihydroabietic acid ranges from 1.3:1 to 1:2.6.
3. A rosin ester comprising at least 70% by weight of an esterified dehydroabietic acid and an esterified dihydroabietic acid,
wherein, when 1000 ppm or less of an antioxidant is present in combination with the rosin ester, the rosin ester exhibits an oxidative-induction time at 130° C. of at least 10 minutes as measured using the methods specified in ASTM D5483-05(2010), and
wherein the weight ratio of the esterified dehydroabietic acid to the esterified dihydroabietic acid ranges from 1:0.70 to 1:0.25,
wherein the rosin ester has a weight average molecular weight of at least 800 g/mol as determined using gel permeation chromatography as determined by ASTM D5296-05.
4. The rosin ester of claim 3 , wherein the rosin ester exhibits less than a 10% change in neat Gardner color when heated to a temperature of 160° C. for a period of three hours.
5. A composition comprising
(a) a polymer derived from one or more ethylenically-unsaturated monomers, or a blend of two or more polymers derived from one or more ethylenically-unsaturated monomers, and
(b) a rosin ester comprising at least 70% by weight of an esterified dehydroabietic acid and an esterified dihydroabietic acid, wherein the weight ratio of the esterified dehydroabietic acid to the esterified dihydroabietic acid ranges from 1.3:1 to 1:2.6, wherein the rosin ester has a weight average molecular weight of at least 800 g/mol as determined using gel permeation chromatography as determined by ASTM D529605.
6. The composition of claim 5 , wherein the polymer is a copolymer.
7. A composition comprising
(a) 45% by weight to 75% by weight of an oil, and
(b) 25% by weight to 55% by weight of a rosin ester defined by claim 1 .