Radical curable adhesive composition, and polarizing plate and optical member comprising same
The present invention relates to a radical-curable adhesive composition including a radical-polymerizable first compound that includes at least two hydroxyl groups in the molecule, and having hydroxyl value of 500 mg KOH/g or greater, and a polarizing plate and an optical member including the radical-curable adhesive composition.
1. A radical-curable adhesive composition comprising:
a (A) radical-polymerizable first compound including at least two hydroxyl groups in the molecule;
a (B) radical-polymerizable second compound including at least one hydrophilic functional group in the molecule; and
a (C) radical initiator,
wherein the radical-curable adhesive composition has a hydroxyl value of 657 to 768 mg KOH/g,
wherein the (A) radical-polymerizable first compound including at least two hydroxyl groups in the molecule is included in an amount of 5 to 90 parts by weight; the (B) radical-polymerizable second compound including at least one hydrophilic functional group in the molecule is included in an amount of 5 to 90 parts by weight; and the (C) radical initiator is included in an amount of 0.5 to 20 parts by weight, with respect to 100 parts by weight of the radical-curable adhesive composition,
wherein the (B) radical-polymerizable second compound is a compound excluding the (A) radical-polymerizable first compound,
wherein the (A) radical-polymerizable first compound includes one or more types selected from the group consisting of compounds represented by the following [Chemical Formula 1] to [Chemical Formula 17]:
2. The radical-curable adhesive composition of claim 1 , wherein the hydrophilic functional group of the (B) radical-polymerizable second compound is a hydroxyl group.
3. The radical-curable adhesive composition of claim 1 , wherein the (B) radical-polymerizable second compound is represented by the following [Chemical Formula I]:
wherein, in [Chemical Formula I], R 1 is an ester group or an ether group; R 2 is a C 1-10 alkyl group, a C 4-10 cycloalkyl group or a combination thereof, and herein, R 2 has one hydroxyl substituent in the molecule; and R 3 is hydrogen or a substituted or unsubstituted C 1-10 alkyl group.
4. The radical-curable adhesive composition of claim 1 , wherein the (B) radical-polymerizable second compound includes one or more types selected from the group consisting of compounds represented by the following [Chemical Formula 18] to [Chemical Formula 23]:
5. The radical-curable adhesive composition of claim 1 , further comprising:
a (D) multifunctional (meth)acryl-based compound;
a (E) phosphate compound including at least one (meth)acrylic group in the molecule; or
a combination thereof.
6. The radical-curable adhesive composition of claim 5 , wherein the (D) multifunctional (meth)acryl-based compound is included in 4 to 50 parts by weight with respect to 100 parts by weight of the radical-curable adhesive composition.
7. The radical-curable adhesive composition of claim 5 , wherein the (E) phosphate compound including at least one (meth)acrylic group in the molecule is included in 0.5 to 30 parts by weight with respect to 100 parts by weight of the radical-curable adhesive composition.
8. The radical-curable adhesive composition of claim 1 , further comprising:
an (F) epoxy compound including at least one epoxy group in the molecule; and
a (G) cation initiator.
9. The radical-curable adhesive composition of claim 8 , wherein the (F) epoxy compound including at least one epoxy group in the molecule is included in 1 to 30 parts by weight with respect to 100 parts by weight of the radical-curable adhesive composition.
10. The radical-curable adhesive composition of claim 8 , wherein the (G) cation initiator is included in 0.5 to 15 parts by weight with respect to 100 parts by weight of the radical-curable adhesive composition.
11. The radical-curable adhesive composition of claim 1 , which is cured by photocuring or heat curing.
12. The radical-curable adhesive composition of claim 1 , which has a glass transition temperature of 50° C. or higher after curing.
13. A polarizing plate comprising:
a polarizer;
an adhesive layer formed on at least one surface of the polarizer; and
a polarizer protective film formed on the adhesive layer;
wherein the adhesive layer is formed using the radical-curable adhesive composition of claim 1 .
14. An optical member comprising:
a display panel; and
a polarizer attached to an external-most surface of the display panel through a medium of an adhesive layer;
wherein the adhesive layer is formed using the radical-curable adhesive composition of claim 1 .