Polarizing plate and image display device comprising same
The present invention relates to a polarizing plate including a polarizer, and a protective layer formed on at least one surface of the polarizer, in which the protective layer is a cured product of (A) a first compound represented by the following [Formula 1]; (B) a radical curable second compound including at least one carboxyl group conjugated to an unsaturated double bond between carbons present at a side chain in a molecule thereof; and (C) a radical curable composition including a radical initiator, and a liquid crystal display device including the same.
1. A polarizing plate comprising:
a polarizer; and
a protective layer formed on at least one surface of the polarizer,
wherein the protective layer is a cured product of a radical curable composition comprising: (A) a first compound represented by the following [Formula I]; (B) a radical curable second compound represented by the following [Formula II]; (C) a radical initiator; and (D) a third compound having an acid value of 100 to 1,000 mg KOH/g:
wherein R 1 is an ester group or an ether group; R 2 is a C 1˜10 alkyl group, a C 4˜10 cycloalkyl group, or a combination thereof, and in this case, R 2 has at least one hydroxy substituent in a molecule thereof; and R 3 is hydrogen, or a substituted or unsubstituted C 1˜10 alkyl group,
wherein R 4 is a single bond, a substituted or unsubstituted C 1˜10 alkylene group, a substituted or unsubstituted C 4˜14 cycloalkylene group, a substituted or unsubstituted C 6˜14 arylene group, or a combination thereof; and R 5 is hydrogen; or a substituted or unsubstituted C 1˜10 alkyl group, a substituted or unsubstituted C 4˜14 cycloalkyl group, a substituted or unsubstituted C 6˜14 aryl group, or a combination thereof.
2. The polarizing plate of claim 1 , wherein the radical curable composition comprises 40 to 90 parts by weight of the first compound, 1 to 50 parts by weight of the second compound and 0.5 to 10 parts by weight of the radical initiator, based on 100 parts by weight of the radical curable composition.
3. The polarizing plate of claim 1 , wherein the first compound is one or more selected from the group consisting of compounds represented by the following [Formula 1] to [Formula 8]:
4. The polarizing plate of claim 1 , wherein the second compound is one or more selected from the group consisting of compounds represented by the following [Formula 9] to [Formula 13]:
5. The polarizing plate of claim 1 , wherein the third compound is one or more selected from the group consisting of compounds represented by the following [Formula 14] to [Formula 25]:
(wherein R′ is
and p is an integer of 1 to 5)
6. The polarizing plate of claim 1 , wherein a content of the third compound is 1 to 50 parts by weight based on 100 parts by weight of the radical curable composition.
7. The polarizing plate of claim 1 , wherein the radical curable composition further comprises a photoacid generator.
8. The polarizing plate of claim 1 , wherein the radical curable composition further comprises a polyfunctional (meth)acrylic compound, a phosphate-based compound comprising at least one (meth)acrylic group in a molecule thereof, or a combination thereof.
9. The polarizing plate of claim 1 , wherein the radical curable composition further comprises an epoxy compound comprising at least one epoxy group in a molecule thereof, and a photoacid generator.
10. The polarizing plate of claim 1 , wherein the radical curable composition after the curing has a glass transition temperature of 60° C. or more.
11. The polarizing plate of claim 1 , wherein a thickness of the protective layer is 0.5 to 20 μm.
12. The polarizing plate of claim 1 , wherein a protective film is attached, through an adhesive layer, to a surface opposite to a surface of the polarizer, on which the protective layer is formed previously.
13. The polarizing plate of claim 1 , further comprising an adhesion layer at an upper portion of the protective layer.
14. An image display device comprising the polarizing plate of claim 1 .