Low vinyl bond modified elastomeric copolymers
The present invention relates to a modified elastomeric polymer obtained by reacting a living anionic elastomeric polymer and specific chain end modifying compound, wherein the living anionic elastomeric polymer comprises more than 70% and less than 99% by weight of butadiene units and more than 1% and less than 30% by weight of styrene units and has a vinyl bond content of from 2 to less than 10%, based on the polybutadiene fraction of the living anionic elastomeric polymer. The invention further relates to a method of preparing the modified elastomeric polymer and to an elastomeric polymer composition comprising the modified elastomeric polymer.
1. A modified elastomeric polymer obtained by reacting a living anionic elastomeric polymer and a modifying compound of the following formula (I):
(R″O) x (R) y Si—R′—S—SiR 3 Formula (I)
wherein R is independently C 1 -C 16 alkyl or benzyl; R″ is C 1 -C 4 alkyl; R′ is selected from C 6 -C 18 aryl, C 7 -C 50 alkylaryl, C 1 -C 50 alkyl and C 2 -C 50 dialkylether, wherein each group is optionally substituted with one or more groups selected from C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 6 -C 12 aryl, C 7 -C 16 alkylaryl, di(C 1 -C 7 hydrocarbyl)amino, bis(tri(C 1 -C 12 alkyl)silyl)amino, tris(C 1 -C 7 hydrocarbyl)silyl and C 1 -C 12 thioalkyl; x is an integer selected from 1, 2 and 3; y is an integer selected from 0, 1 and 2; and x+y=3, and
wherein the living anionic elastomeric polymer comprises at least 75% and less than 99% by weight of butadiene units and more than 1% and up to 25% by weight of styrene units and has a vinyl bond content of from 2 to less than 10%, based on the polybutadiene fraction of the living anionic elastomeric polymer.
2. The modified elastomeric polymer according to claim 1 , wherein R is independently selected from C 1 -C 5 alkyl and R′ is C 1 -C 5 alkyl.
3. The method of preparing the modified elastomeric polymer as defined in claim 1 , comprising the step of reacting the living anionic elastomeric polymer and the modifying compound of formula (I).
4. The modified elastomeric polymer according to claim 1 , obtained by reacting a living anionic elastomeric polymer with a modifying compound of the following formula (1) and at least one of the modifying compounds of the following formulas (3), (4), (5) and (6):
wherein R 2 , R 3 , R 10 , R 11 , R 12 , R 14 , R 16 , R 17 and R 18 are independently selected from C 1 -C 16 alkyl and benzyl, wherein alkyl groups for R 10 , R 11 and R 12 and for R 16 , R 17 and R 18 may bond to each other so as to form a ring comprising two Si atoms and N; R 1 and R 13 are independently selected from C 1 -C 4 alkyl; R 4 , R 9 and R 15 are independently selected from C 6 -C 18 aryl, C 7 -C 50 alkylaryl, C 1 -C 50 alkyl and C 2 -C 50 dialkylether, wherein each group is optionally substituted with one or more groups selected from C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 6 -C 12 aryl, C 7 -C 16 alkylaryl, di(C 1 -C 7 hydrocarbyl)amino, bis(tri(C 1 -C 12 alkyl)silyl)amino, tris(C 1 -C 7 hydrocarbyl)silyl and C 1 -C 12 thioalkyl; R 5 , R 6 and R 7 are independently selected from hydrogen, C 1 -C 16 alkyl and C 6 -C 12 aryl; R 8 is selected from C 1 -C 16 alkyl and C 6 -C 12 aryl; and R 19 , R 20 and R 21 are independently selected from hydrogen and C 1 -C 16 alkyl; x and p are each an integer selected from 1 and 2; y and q are each an integer selected from 1 and 2; x+y=3; and p+q=3, and
wherein the living anionic elastomeric polymer comprises at least 75% and less than 99% by weight of butadiene units and more than 1% and up to 25% by weight of styrene units and has a vinyl bond content of from 2 to less than 10%, based on the polybutadiene fraction of the living anionic elastomeric polymer.
5. The modified elastomeric polymer according to claim 4 , wherein in formulas (1) and (2) R 1 and R 13 are independently selected from C 1 -C 4 alkyl; R 3 , R 10 , R 11 and R 12 are independently selected from C 1 -C 16 alkyl and benzyl; and R 4 and R 9 are independently selected from C 1 -C 16 alkyl, C 6 -C 16 aryl and C 7 -C 16 alkylaryl.
6. The modified elastomeric polymer according to claim 4 , wherein in formulas (3), (4), (5) and (6) R 2 , R 3 , R 8 , R 10 , R 11 , R 12 , R 14 , R 16 , R 17 and R 18 are independently selected from C 1 -C 16 alkyl, R 1 and R 13 are independently selected from C 1 -C 4 alkyl, R 5 , R 6 , R 7 , R 19 , R 20 and R 21 are independently selected from hydrogen and C 1 -C 16 alkyl, and R 4 , R 9 and R 15 are independently selected from C 1 -C 16 alkyl, C 6 -C 15 aryl and C 7 -C 16 alkylaryl.
7. The modified elastomeric polymer according to claim 4 , which is obtained by reacting the living anionic elastomeric polymer with a modifying compound of formula (1) to provide a modified polymer and then reacting the modified polymer with at least one of the modifying compounds of formulas (3), (4), (5) and (6).
8. The modified elastomeric polymer according to claim 4 , which is obtained by reacting the living anionic elastomeric polymer with a modifying compound of formula (1) and a modifying compound of formula (3).
9. A method of preparing the modified elastomeric polymer as defined in claim 7 , comprising the steps of (i) reacting the living anionic elastomeric polymer with a modifying compound of formula (1) to provide a modified polymer and (ii) reacting the modified polymer with at least one of the modifying compounds of formulas (3), (4), (5) and (6).
10. The method according to claim 9 , comprising the steps of (i) reacting the living anionic elastomeric polymer with the modifying compound of formula (1) to provide a modified polymer and (ii) reacting the modified polymer with the modifying compound of formula (3).
11. The modified elastomeric polymer according to claim 1 , wherein the amount of styrene in the living anionic elastomeric polymer is at least 2% by weight.
12. The modified elastomeric polymer according to claim 11 , wherein the living anionic elastomeric polymer is a copolymer of butadiene and styrene.
13. The modified elastomeric polymer according to claim 1 , wherein the content of vinyl bonds in the polybutadiene fraction of the living anionic elastomeric polymer is from 4 to 9%.
14. An elastomeric polymer composition comprising the modified elastomeric polymer as defined in claim 1 , and one or more further components selected from components which are added to or formed as a result of the polymerization process used for making the modified elastomeric polymer and components which remain after solvent removal from the polymerization process.
15. The elastomeric polymer composition according to claim 14 , comprising one or more extender oils.
16. The elastomeric polymer composition according to claim 14 , comprising one or more fillers.
17. The elastomeric polymer composition according to claim 16 , wherein the one or more fillers are selected from carbon nanotubes, carbon black, silica, carbon-silica dual-phase filler, clay, calcium carbonate and magnesium carbonate.
18. The elastomeric polymer composition according to claim 16 , where the filler is selected from a combination of carbon black with silica, carbon-silica dual-phase filler, a combination of carbon-silica dual-phase filler with carbon black and/or silica, and a combination of carbon nanotubes with one or more of carbon-silica dual-phase filler, carbon black and silica.
19. The elastomeric polymer composition according to claim 14 , comprising one or more further elastomeric polymers.
20. The method of preparing the modified elastomeric polymer according to claim 9 , wherein the amount of styrene in the living anionic elastomeric polymer is at least 2% by weight.
21. The method of preparing the modified elastomeric polymer according to claim 20 , wherein the living anionic elastomeric polymer is a copolymer of butadiene and styrene.
22. The method of preparing the modified elastomeric polymer according to claim 9 , wherein the content of 1,2-added butadiene (vinyl bond content) in the polybutadiene fraction of the living anionic elastomeric polymer is from 4 to 9%.