Jet loop reactor with nanofiltration and gas separator
View Patent ↗The invention relates to a device for the continuous homogeneous catalytic reaction of a liquid with a gas and optionally a further fluid, wherein the device comprises at least one jet loop reactor having an external liquid circuit driven by at least one pump, and wherein the device has at least one membrane separation unit, preferably retaining the homogeneous catalyst, which membrane separation unit is arranged in the external liquid circuit of the jet loop reactor. The object thereof is to reduce the costs of the device. This is achieved by providing an additional apparatus, namely a gas separator, which is arranged in the external liquid circuit of the jet loop reactor and is installed for separating off gas from the external liquid circuit and feeding it back into the jet loop reactor.
1. A device for the continuous homogeneous catalytic reaction of a liquid with a gas and optionally a further fluid, wherein the device comprises at least one jet loop reactor having an external liquid circuit driven by at least one pump, and wherein the device has at least one membrane separation unit, retaining the homogeneous catalyst, which membrane separation unit is arranged in the external liquid circuit of the jet loop reactor, wherein a gas separator is arranged in the external liquid circuit of the jet loop reactor, which gas separator is installed for separating off gas from the external liquid circuit and feeding it back into the jet loop reactor.
2. The device according to claim 1 , wherein in the external liquid circuit, upstream of the membrane separation unit, a heat exchanger is arranged for cooling the feed of the membrane separation unit, and in that the gas separator is arranged downstream of the heat exchanger upstream of the membrane separation unit.
3. The device according to claim 1 , wherein the pump is arranged upstream of the membrane separation unit, the gas separator, and the heat exchanger.
4. The device according to claim 1 , wherein the membrane separation unit is constructed as a multistage membrane cascade.
5. The device according to claim 1 , wherein no transport element is provided between the gas separator and jet loop reactor, in such a manner that the jet loop reactor takes in independently from the gas separator gas separated off from the external liquid circuit.
6. The device according claim 1 , wherein a tubular reaction space extends in the jet loop reactor, into which a jet nozzle for injecting the liquid into the reaction space opens out and also a suction tube for intake of gas opens out conjointly, and at which a baffle plate-shielded take-off for the external liquid circuit is provided.
7. A method for the homogeneous catalytic reaction of a liquid with a gas and optionally a further fluid, wherein the reaction is carried out in a device according to claim 1 , and in that at least one target product of the reaction is discharged from the liquid circuit with the permeate of the membrane separation unit.
8. The method according to claim 7 , wherein the external liquid circuit, upstream of the membrane separation unit is a mixture which comprises a liquid phase and a gaseous phase distributed dispersely therein, wherein volume fraction of the gaseous phase is between zero and thirty percent.
9. The method according to claim 7 , wherein the external liquid circuit, upstream of the gas separator, is a mixture which comprises a liquid phase and a gaseous phase distributed dispersely therein, wherein volume fraction of the gaseous phase is between thirty and 100 percent.
10. The method according to claim 7 wherein oxidations, epoxidations, hydroformylations, hydroaminations, hydroaminomethylations, hydrocyanations, hydrocarboxyalkylation, aminations, ammoxidation, oximations, hydrosilylations, ethoxylations, propoxylations, carbonylations, telomerizations, metatheses, Suzuki couplings or hydrogenations are carried out in the device.
11. The method according to claim 10 , wherein compounds having olefinic double bonds are reacted by hydroformylation with synthesis gas to form aldehydes and/or alcohols.