Lithographic printing plate precursors and coating
View Patent ↗A coating for use with a hydrophilic sheet substrate to form a lithographic printing plate precursor, including at least one Compound A silane compound and at least one Compound B phosphinic acid or organic derivative thereof. Compounds A and B experience a synergistic interaction which substantially increases adhesion to the substrate of areas imaged by radiation. The resulting plate is exhibits high on-press durability suitable for high volume commercial uses without a preheat step prior to development, even when imaged with lower levels of radiation such as violet lasers. A method of preparing a lithographic printing plate includes imagewise exposing the coating on a surface of a hydrophilic substrate to violet radiation and developing in an alkaline aqueous solution without preheating.
1. A coating composition for use on a hydrophilic sheet substrate to form a lithographic printing plate precursor, comprising:
(a) an initiator component capable of generating free radicals;
(b) a free radically polymerizable component;
(c) a polymeric binder component;
(d) a Compound A component including one or more silane compounds of the structure R n SiX (4-n) , wherein X comprises at least one hydrolysable group, R comprises at least one organic group, and n is an integer between 0 and 4; and
(e) a non-polymeric phosphate ester.
2. The coating composition of claim 1 , wherein the Compound A component is an organic silane having the structure
wherein each X is independently selected from a hydroxy and alkoxy group, and R is an organic group, and the non-polymeric phosphate ester has the structure
wherein R 1 , R 2 and R 3 are independently selected from H, an organic radical and a silyl radical.
3. The coating composition of claim 1 , wherein the Compound A component is selected from one or more of (3-mercaptopropyl)trimethoxysilane, (3-glycidyloxypropyl)trimethoxysilane, or 3-(trimethoxysilylpropyl)acrylate, 3-(trimethoxysilylpropyl)methacrylate.
4. The coating composition of claim 3 , wherein the non-polymeric phosphate ester component contains an ethylenically unsaturated bond capable of taking part in the photopolymerization process.
5. A method for producing a lithographic printing plate, comprising:
(a) selecting a plate having a photopolymerizable oleophilic coating adhered to a hydrophilic substrate, the coating having
(i) a first component comprising one or more silane compounds of the structure R n SiX (4-n) , wherein X is at least one hydrolysable group, and R is at least one organic group, and
(ii) a second component comprising a non-polymeric phosphate ester;
(b) imagewise exposing the coating to violet radiation to produce a pattern of photopolymerized image areas and nonimage areas not affected by the radiation;
(c) without preheating the plate above ambient temperature, developing the plate in an alkaline solution to remove nonimage areas of the coating from the substrate while retaining the image areas on the substrate; and
(d) without further radiation treatment of the plate, mounting the developed plate on a lithographic printing press.
6. The method of claim 5 , wherein the coating comprises:
(a) an initiator component capable of generating free radicals;
(b) a free radically polymerizable component; and
(c) a polymeric binder component.
7. The method of claim 5 , wherein the step of developing is performed with the plate in a single tank which includes the alkaline solution and a gum.
8. The method of claim 5 , wherein the imagewise exposure is with radiation within the range of 45 to 70 microjoules/cm 2 .
9. The method of claim 5 , wherein the step of developing is performed in an aqueous alkaline solution having a pH below 12.
10. The method of claim 5 , wherein the step of developing is performed in an aqueous alkaline solution having a pH no greater than 10.
11. A lithographic printing plate precursor, comprising:
(a) a hydrophilic substrate sheet defining a first surface; and
(b) a violet polymerizable coating non-ionically adhered to the substrate first surface, comprising:
(i) a first component including one or more silane compounds of the structure R n SiX (4-n) , wherein X comprises at least one hydrolysable group, R comprises at least one organic group, and n is an integer between 0 and 4, and
(ii) a second component including a non-polymeric phosphate ester.
12. The lithographic printing plate precursor of claim 11 , wherein the polymerizable coating comprises:
(iii) an initiator composition component capable of generating free radicals;
(iv) a free radically polymerizable component; and
(v) a polymeric binder component.
13. The method of claim 5 , wherein the silane compound is an organic silane having the structure
wherein each X is independently selected from a hydroxy and alkoxy group, and R is an organic group, and the non-polymeric phosphate ester has the structure
wherein R 1 , R 2 and R 3 are independently selected from H, an organic radical and a silyl radical.
14. The coating composition of claim 3 , wherein the non-polymeric phosphate ester component is an acrylated phosphate ester.