Zinc catalyst/additive system for the polymerization of epoxide monomers
View Patent ↗The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 2 metals, preferably Mg, Ca, Sr, and Ba, more preferably Mg, (II) Li, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.
1. A catalyst formulation comprising:
(a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and
(b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from:
(I) group 2 metals,
(II) Li, and
(III) combinations of at least two metals selected from (I) and (II).
2. The catalyst formulation of claim 1 wherein the Zn compound of the Zn catalyst (a) is selected from:
(a1) a Zn alcoholate of one or more polyols, and
(a2) a heteroleptic Zn alcoholate of one or more polyols and one or more monohydric alcohols and/or water.
3. The catalyst formulation of claim 2 wherein the Zn catalyst (a) comprises a Zn alcoholate (a1) of one or more polyols and a Zn alcoholate (a3) of one or more monohydric alcohols.
4. The catalyst formulation of claim 1 wherein the Zn catalyst (a) comprises a Zn compound having alcoholate ligand(s) derived from one or more diols.
5. The catalyst formulation of claim 2 wherein the Zn compound of the Zn catalyst (a) is a heteroleptic Zn alcoholate (a2) of one or more polyols and one or more monohydric alcohols selected from monohydric aliphatic alcohols including monohydric halosubstituted aliphatic alcohols.
6. The catalyst formulation of claim 5 wherein the Zn compound of the Zn catalyst (a) is a heteroleptic Zn alcoholate (a2) of 1,4-butanediol and ethanol.
7. The catalyst formulation of claim 1 wherein the catalyst additive (b) comprises a metal compound (i) having alcoholate ligand(s) derived from one or monohydric aliphatic, cycloaliphatic or mixed aliphatic/cycloaliphatic alcohols.
8. The catalyst formulation of claim 1 wherein the metal compound (i) of the catalyst additive (b) is selected from:
(b1) a metal alcoholate of one or more monohydric alcohols, and
(b2) a heteroleptic metal complex having alcoholate ligand(s) derived from one or more monohydric alcohols and non-alcoholate ligand(s).
9. The catalyst formulation of claim 1 wherein the catalyst additive additionally comprises (ii) a monohydric alcohol.
10. A process for polymerizing an epoxide monomer comprising carrying out the process in the presence of a catalyst formulation comprising:
(a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and
(b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from:
(I) group 2 metals,
(II) Li, and
(III) combinations of at least two metals selected from (I) and (II).
11. The process of claim 10 wherein a poly(olefin oxide) having a weight average molecular weight of at least 30,000 is prepared.
12. The process of claim 10 wherein a poly(ethylene oxide) is prepared.
13. The process of claim 11 wherein a poly(ethylene oxide) is prepared.