Zinc catalyst/additive system for the polymerization of epoxide monomers
View Patent ↗The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 13 metals, preferably B, Al, Ga, and In, more preferably Al, (II) combinations of Al with group 14 metals or semi-metals, preferably a combination of Al and Si, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.
1. A process for polymerizing an epoxide monomer comprising carrying out the process in the presence of a catalyst formulation comprising:
(a) a Zn catalyst comprising one single Zn compound having alcoholate ligand(s) derived from one or more polyols, and
(b) a catalyst additive comprising a single metal compound (i) having alcoholate ligand(s) derived from one or more monohydric alcohols wherein the metal is selected from:
(I) Al and
(II) a combination of Al with Si.
2. The process of claim 1 wherein a poly(olefin oxide) having a weight average molecular weight of at least 30,000 is prepared.
3. The process of claim 1 wherein the metal compound (i) is present in an amount providing a molar ratio of metal of the metal compound (i) to Zn of the Zn catalyst (a) within the range of from 0.01:1 to 20:1.
4. The process of claim 1 wherein a poly(ethylene oxide) is prepared.
5. The process of claim 2 wherein a poly(ethylene oxide) is prepared.
6. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the Zn compound of the Zn catalyst (a) is selected from:
(a1) a Zn alcoholate of one or more polyols, and
(a2) a heteroleptic Zn alcoholate of one or more polyols and one or more monohydric alcohols.
7. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the Zn catalyst (a) comprises a zn alcoholate (a1) of one or more polyols and a Zn alcoholate (a3) of one or more monohydric alcohols.
8. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the Zn compound of the Zn catalyst (a) is a heteroleptic Zn alcoholate (a2) of 1,4-butanediol and ethanol.
9. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the catalyst additive (b) comprises a metal compound (i) having alcoholate ligand(s) derived from one or monohydric aliphatic, cycloaliphatic or mixed aliphatic/cycloaliphatic alcohols.
10. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the metal compound (i) of the catalyst additive (b) is selected from:
(b1) a metal alcoholate of one or more monohydric alcohols, and
(b2) a heteroleptic metal complex having alcoholate ligand(s) derived from one or more monohydric alcohols and non-alcoholate ligands(s).
11. The process of claim 1 comprising carrying out the process in the presence of a catalyst formulation wherein the catalyst additive additionally comprises (ii) a monohydric alcohol.