Zinc catalyst/additive system for the polymerization of epoxide monomers
View Patent ↗The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) first row transition metals excluding Zn, preferably Sc, Ti, V, Cr, Mn, Ni, and Co, more preferably Ti, (II) second row transition metals, preferably Y and Zr, more preferably Zr, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.
1. A process for polymerizing an epoxide monomer comprising carrying out the process in the presence of a catalyst formulation comprising:
(a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and
(b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from a monohydric alcohol wherein the metal is selected from:
(I) Ti,
(II) Zr, and
(III) a combination of Ti and Zr,
wherein water and oxygen are excluded from the catalyst formulation and a poly(olefin oxide) having a weight average molecular weight of 30,000 to 2,000,000 is prepared.
2. The process of claim 1 wherein a poly(olefin oxide) having a weight average molecular weight of 50,000 to 2,000,000 is prepared.
3. The process of claim 1 wherein the metal compound (i) is present in an amount providing a molar ratio of metal of the metal compound (i) to Zn of the Zn catalyst (a) within the range of from 0.01:1 to 20:1.
4. The process of claim 1 wherein a poly(ethylene oxide) is prepared.
5. The process of claim 2 wherein a poly(ethylene oxide) is prepared.
6. The process of claim 1 wherein a poly(ethylene oxide) is prepared which has a molecular weight of 100,000 to 2,000,000 based on viscosity determination.