Water repellent, soil resistant, fluorine-free compositions

1. A fluorine-free composition comprising:

a. a first composition comprising

i. an aqueous silicone emulsion having a non-volatile silicone content of from 10 to 30 wt. %, based on the total weight of said aqueous emulsion, and having a particle size, d 50 , from 25 to 100 nm,

ii. an aqueous dispersion of a silane quaternary ammonium salt having a solid content of from 1.0 to 7.0 wt %, based on the total weight of said dispersion,

wherein the combination of (i) and (ii) has an average zeta potential of 0.07 according to the Zeta Potential Test, and

iii. water,

whereby the mixing ratio is from 0.5 to 4.0 volume parts for (i), from 0.7 to 1.5 volume parts for (ii), and from 1.0 to 4.0 volume parts for (iii), and

b. a second composition comprising a soil repellency component that is an aqueous dispersion of colloidal organosiloxanes, organosiloxane polymers or organosiloxane copolymers, and which has an overall cationic or anionic charge, and that are of average particle size between 25 and 400 nm.

2. The composition according to claim 1 , wherein the combination of (i) and (ii) has an average particle size diameter of from 10 to 400 nm as determined using the Particle Size test method.

3. The composition according to claim 1 , wherein the silicone is an aminopolysiloxanes of Formula 1:

R 1 a R 2 b (OR 3 ) c SiO (4-a-b-c) /2  (I)

wherein:

R 1 means identical or different monovalent, nitrogen-free, optionally halogen substituted, SiC-bonded C 1 -C 6 alkyl radicals,

R 2 means identical or different monovalent, optionally halogen-substituted SiC-bonded, basic nitrogen containing C 1 -C 6 alkyl radicals,

R 3 is H or a C 1 -C 8 alkyl radical,

a is 0, 1, 2 or 3, preferably 0, 1 or 2,

b is 0, 1, 2 or 3, preferably 0, 1 or 2, or at least an average of 0.05, and

c is 0 or 1,

with the proviso that the sum of a, b, and c is less than or equal to 3 and that the amine number of the organopolysiloxane is at least 0.01.

4. The composition according to claim 1 , wherein the silane quaternary ammonium salt is a compound of the formula III

(R 6 O) 3 SiR 7 N + (R 8 )(R 9 )(R 10 )Y −   (III)

wherein:

R 6 is H, methyl, ethyl, propyl, or butyl,

R 7 is C 1 -C 6 alkyl,

R 8 and R 9 are, independently, H, methyl, ethyl, propyl, or butyl,

R 10 is C 1 -C 22 alykl, and

Y is Cl or Br.

5. The composition according to claim 1 , wherein the soil repellency component includes aqueous cationic or anionic sol dispersions of solid organosiloxane copolymers consisting of:

R 11 SiO 3/2 units,  (IV)

and/or R 12 2 SiO units,  (V)

and/or R 13 3 SiO 1/2 units  (VI)

wherein each of R 11 , R 12 , or R 13 is independently selected from the group consisting of alkyl and substituted alkyl radicals containing 1 to 7 carbon atoms.

6. The composition according to claim 1 , wherein the soil repellency component is a colloidal aqueous dispersions containing:

a. organopolysiloxane units of general Formula VII:

R 14 x Si(OR 15 ) y O (4-x-y)/2   (VII)

where

x is 0, 1, 2 or 3 and y is 0, 1 or 2,

with the proviso that the sum total x+y is ≤3,

R 14 in each occurrence is the same or different and represents an SiC-bonded monovalent alkyl radical having 1 to 18 carbon atoms per radical, and

R 15 in each occurrence is the same or different and represents a hydrogen atom or a alkyl radical having 1 to 18 carbon atoms per radical which are or are not interrupted by one or more mutually separated oxygen atoms, or is a radical of the formula —COCH 3 , —COC 2 H 5 or —CH 2 CH 2 OH,

b. optionally water-soluble or self-dispersing silane-containing polyvinyl alcohols and/or polyvinyl esters and/or copolymers with the proviso that more than 50 mol-% of fully or partially saponified vinyl ester units are present, wherein at least one of the monomer units contains an attached silane,

c. optionally surface-active compounds, such as emulsifiers, and

d. water.

7. The composition according to claim 1 , which additionally contains one or more stain-blocker(s).

8. An article of manufacture, especially a carpet or a textile floor covering, which is treated with the composition of claim 1 , whereby the article is rendered water repellent and soil resistant.

9. A method for the treatment of textiles or fibres of synthetic or natural origin with a composition as defined in claim 1 in an effective amount to render the textiles or fibres water repellent and soil resistant.

10. The method of claim 9 , wherein treatment is by spray application.

11. The method of claim 9 , wherein treatment is by foam application.

12. A kit providing in separate containers:

a. a mixture of the components (i)-(iii) of the first composition defined in claim 1 in the given mixing ratio, and

b. the second composition as claimed in claim 1 .