IP Library Granted Patent US 9,783,548
Granted Patent B2
US 9,783,548 · App. 15/038,107 · Granted Oct 10, 2017

Production method for epoxy compound using solid catalyst

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Quick Facts
Patent No.
US 9,783,548
App. No.
15/038,107
Granted
Oct 10, 2017
Kind
B2
Abstract

A method for producing an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, aqueous hydrogen peroxide, a powder of a solid catalyst support and a powder of a solid catalyst, wherein the solid catalyst comprises an isopolyacid, and the isopolyacid is produced from a catalyst raw material comprising (a) tungstic acid or a salt thereof and (b) at least one selected from the group consisting of a salt of an alkaline earth metal and a cationic polymer.

Claims (11)

1. A method for producing an epoxy compound comprising:

reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, aqueous hydrogen peroxide, a powder of a solid catalyst support and a powder of a solid catalyst,

wherein the solid catalyst comprises an isopolyacid, and

the isopolyacid is produced from a catalyst raw material comprising (a) tungstic acid or a salt thereof and (b) a cationic polymer.

2. The method according to claim 1 , wherein the catalyst raw material comprises an ammonium tungstate.

3. The method according to claim 1 , wherein the catalyst raw material comprises at least one cationic polymer selected from the group consisting of a salt of poly 4-vinylpyridine and a salt of poly N-alkyl-4-vinylpyridine.

4. The method according to claim 1 , wherein the compound having a carbon-carbon double bond is an alicyclic olefin compound.

5. The method according to claim 1 , wherein the compound having a carbon-carbon double bond is a compound represented by the following formula (2):

wherein R 1 to R 12 each independently represent a hydrogen atom, a halogen atom, an alkyl group that may have a substituent selected from the group consisting of a halogen atom and an alkoxy group, or an alkoxy group that may have a substituent selected from the group consisting of a halogen atom and an alkoxy group.

6. The method according to claim 1 , wherein the solid catalyst support is selected from the group consisting of phosphates, diatomaceous earth, silica, alumina, kaolin, silica alumina and calcium fluoride.

7. The method according to claim 1 , wherein the solid catalyst support is apatite.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 15, 2019
From: JXTG NIPPON OIL & ENERGY CORPORATION
To: OSAKA UNIVERSITY
Reel/Frame 049753/0509 →
CHANGE OF NAME Recorded Jun 15, 2018
From: JX NIPPON OIL & ENERGY CORPORATION
To: JXTG NIPPON OIL & ENERGY CORPORATION
Reel/Frame 046634/0132 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 22, 2016
From: ICHIHARA, JUNKO; YAMAGUCHI, SHUNRO; KAMEYAMA, ATSUSHI; SUZUKI, TAKASHI; MORIKITA, TAKASHI
To: JX NIPPON OIL & ENERGY CORPORATION; OSAKA UNIVERSITY
Reel/Frame 039497/0297 →