IP Library Granted Patent US 9,919,348
Granted Patent B2
US 9,919,348 · App. 15/038,721 · Granted Mar 20, 2018

Compositions, systems, and methods for removing iron sulfide scale from oilfield components

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Quick Facts
Patent No.
US 9,919,348
App. No.
15/038,721
Granted
Mar 20, 2018
Kind
B2
Abstract

The present disclosure relates to compositions, systems and methods for removing iron sulfide scale from a solid object, such as an oilfield component. The compositions include a carbon-carbon (C—C) double bond with an electron withdrawing group bonded to at least one of the double-bonded carbons.

Claims (13)

1. A method of removing iron sulfide scale from an oilfield component with iron sulfide scale, the method comprising applying to the oilfield component in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component a removal material comprising a composition with the general structural formula:

wherein R 1 is an electron withdrawing group and R 2 is R 1 , hydrogen (H), or a moiety comprising another electron withdrawing group, and

wherein at least 80% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

2. The method of claim 1 , wherein the removal material comprises at least two distinct compositions with the general structural formula (I).

3. The method of claim 1 , wherein R 1 comprises an acetate group.

4. The method of claim 1 , wherein the removal material further comprises a polar solvent.

5. The method of claim 1 , wherein at least 85% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

6. The method of claim 1 , wherein applying occurs in a sealed container.

7. The method of claim 1 , further comprising recovering the removal material.

8. The method of claim 1 , wherein the oilfield component comprises a perforation, a casing, a production tubular, a valve, a pump, or downhole completion equipment with iron sulfide scale.

9. The method of claim 1 , wherein at least 90% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

10. The method of claim 1 , wherein at least 95% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

11. The method of claim 1 , wherein substantially all of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 20, 2019
From: HALLIBURTON ENERGY SERVICES, INC.
To: MULTI-CHEM GROUP, LLC
Reel/Frame 048384/0523 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 23, 2016
From: PENG, YANG; ZHAO, FUNIAN; YUE, ZHIWEI; SHI, LIU; QU, LIANGWEI; FAN, CHUNFANG
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 038794/0726 →