IP Library Granted Patent US 9,890,041
Granted Patent B2
US 9,890,041 · App. 15/039,242 · Granted Feb 13, 2018

Process for the production of synthesis gas

Inventors: Thomas Sandahl Christensen (Lyngby, DK); Pia Elholm (Horsholm, DK)
Assignee: Haldor Topsoe A/S
C01B3/40C01B3/38C10G2/30C10L3/103C01B2203/0233C01B2203/0244C01B2203/0261C01B2203/04C01B2203/0495C01B2203/062C01B2203/1058C01B2203/127C01B2203/1241C01B2203/1247C01B2203/1258C01B2203/1264C01B2203/141C01B2203/142C01B2203/143C01B2203/148C01B2203/169C10L2290/541
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Quick Facts
Patent No.
US 9,890,041
App. No.
15/039,242
Granted
Feb 13, 2018
Kind
B2
Abstract

Process for the production of synthesis gas from hydrocarbon feed containing higher hydrocarbons comprising bypassing a portion of the hydrocarbon feed around a first pre-reforming stage and passing the pre-reformed and bypassed portions through at least a second pre-reforming stage.

Claims (19)

1. A process for the production of a synthesis gas for use in the production of chemical compounds from a hydrocarbon feedstock containing higher hydrocarbons comprising the steps of:

(a) splitting the hydrocarbon feedstock into at least two streams, a first hydrocarbon feedstock stream and a second hydrocarbon feedstock stream in the form of a by-pass hydrocarbon feedstock stream;

(b) adding steam to the first hydrocarbon feedstock stream and pre-reforming this stream to a pre-reformed gas containing methane, hydrogen, carbon monoxide, carbon dioxide and higher hydrocarbons;

(c) combining the bypassed hydrocarbon feedstock stream of step (a) with the pre-reformed gas of step (b) and pre-reforming the thus combined gas to a pre-reformed gas containing methane, hydrogen, carbon monoxide and carbon dioxide, wherein a steam-to-carbon ratio of the pre-reforming in step (b) is higher than a steam-to-carbon ratio of the pre-reforming in step (c);

(d) reforming in a reforming stage the pre-reformed gas of step (c) into a synthesis gas containing hydrogen, carbon monoxide and carbon dioxide.

2. The process according to claim 1 further comprising the step of a hydrodesulfurization stage removing sulphur compounds in the hydrocarbon feedstock prior to splitting in step (a).

3. The process according to claim 1 further comprising prior to the pre-reforming stage of step (b) or (c) the step of: a hydrodesulfurization stage removing sulphur compounds in the first hydrocarbon feed stock stream, or the second hydrocarbon feedstock stream, or both.

4. The process according to claim 1 in which the pre-reforming stage of step (b) is operated at a steam-to-carbon ratio in the range 0.60-1.30 calculated as steam-to-carbon ratio, while the pre-reforming stage of step (c) is operated at a lower steam-to-carbon ratio and which is in the range 0.30-0.80 calculated as steam-to-carbon ratio.

5. The process according to claim 1 in which the first hydrocarbon feedstock stream formed after the split is at least 30% vol of the hydrocarbon feedstock.

6. The process according to claim 1 in which the steam addition of step (b) is high pressure steam from a process condensate stripper located downstream the reforming stage (d).

7. The process of claim 1 in which the steam is solely added to the first hydrocarbon feedstock stream passed to the pre-reforming stage of step (b).

8. The process according to claim 1 in which the mixture resulting from adding steam to the first hydrocarbon feedstock stream is preheated to a feed temperature of 380-480° C. before entering the pre-reforming stage of step (b).

9. The process according to claim 1 in which the pre-reforming stage of either step (b) or (c) or both is adiabatic pre-reforming under the presence of catalyst.

10. The process according to claim 9 in which the catalyst is a solid nickel containing steam reforming catalyst suitable for operation at temperatures below 650° C.

11. The process according to claim 1 in which the reforming stage of step (d) consists of SMR, HER, ATR, CPO, POx, or a combination thereof.

12. The process according to claim 11 in which the reforming stage is ATR or CPO or POx.

13. The process according to claim 1 in which the synthesis gas of step (d) is subjected to synthesis of liquid hydrocarbons, including the Fischer-Tropsch synthesis and synthesis of gasoline.

14. The process of claim 13 , in which tail gas or off-gas from the synthesis of the liquid hydrocarbons is recycled to the pre-reforming stage (b), pre-reforming stage (c), reforming stage (d), or a combination thereof.

15. The process according to claim 1 , wherein the hydrocarbon feedstock containing higher hydrocarbons is selected from associated gas or shale gas or associated petroleum gas.

Assignments (2)
CHANGE OF NAME Recorded Oct 3, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065108/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2016
From: CHRISTENSEN, THOMAS SANDAHL; ELHOLM, PIA
To: HALDOR TOPSOE A/S
Reel/Frame 039352/0081 →
Priority Claims (1)
DK 2013 70764 · Dec 12, 2013 · national
Continuity (1)
Related Publication 20170022056A1 · Jan 26, 2017