IP Library Granted Patent US 10,457,805
Granted Patent B2
US 10,457,805 · App. 15/040,151 · Granted Oct 29, 2019

Damping thermoplastic elastomers

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Quick Facts
Patent No.
US 10,457,805
App. No.
15/040,151
Granted
Oct 29, 2019
Kind
B2
Abstract

A thermoplastic elastomer compound includes styrenic block copolymer and high softening point tackifier. The styrenic block copolymer has a Copolymer Tan Delta Peak Temperature and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature while also advantageously possessing improved stability for processing and/or applications at high temperatures and upon exposure to weathering.

Claims (21)

1. A multi-component plastic article comprising at least two components formed from different thermoplastic materials, wherein at least one of the different thermoplastic materials is a thermoplastic elastomer compound and at least one other of the at least two components is a thermoplastic substrate onto which the thermoplastic elastomer compound is overmolded;

wherein the thermoplastic elastomer compound consists of:

(a) 100 parts by weight of styrenic block copolymer having a Copolymer Tan Delta Peak Temperature, wherein the styrenic block copolymer is hydrogenated;

(b) from about 50 to about 200 parts by weight of tackifier having a softening point of at least about 120° C. according to ASTM 6493;

(c) from 0 to about 200 parts by weight of plasticizer;

(d) from 0 to about 150 parts by weight of filler;

(e) from 0 to about 300 parts by weight of secondary polymer selected from polyethylene, polypropylene, butyl rubber, ethylene propylene diene monomer (EPDM) rubber, thermoplastic vulcanizate, and combinations thereof;

(f) from 0 to 300 parts by weight of bonding agent; and

(g) from 0 to about 100 parts by weight of at least one additive selected from anti-fogging agents; anti-static agents; blowing and foaming agents; dispersants; flame retardants and smoke suppressants; initiators; pigments, colorants and dyes; silanes, titanates and zirconates; stabilizers and antioxidants; stearates; ultraviolet light absorbers; waxes; and combinations thereof; and

wherein the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature, and the Compound Tan Delta Peak Temperature is greater than the Copolymer Tan Delta Peak Temperature; and

wherein either:

(x) the thermoplastic substrate comprises polyamide, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from the group consisting of maleic anhydride functionalized polyolefin, maleic anhydride functionalized styrenic block copolymer, and combinations thereof; or

(y) the thermoplastic substrate comprises polyolefin, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from polyethylene, polypropylene, and combinations thereof; or

(z) the thermoplastic substrate comprises a thermoplastic material selected from the group consisting of thermoplastic polyurethane, polycarbonate, polycarbonate/acrylonitrile butadiene styrene, and polybutylene terephthalate/polycarbonate, and wherein the bonding agent is present in the thermoplastic elastomer compound and the bonding agent is selected from thermoplastic polyurethane, copolyester elastomer, and blends of thermoplastic polyurethane and copolyester elastomer.

2. The multi-component plastic article of claim 1 , wherein the filler is selected from calcium carbonate, talc, and combinations thereof.

3. The multi-component plastic article of claim 1 , wherein the compound is essentially free of styrene-(ethylene-ethylene/propylene)-styrene block copolymer and low vinyl styrene-(ethylene/butylene)-styrene block copolymer.

4. The multi-component plastic article of claim 1 , wherein the styrenic block copolymer is selected from at least one of hydrogenated styrene-isoprene-styrene block copolymer with hydrogenated vinylic isoprene midblock and high vinyl styrene-(ethyl ene/butyl ene)-styrene block copolymer.

5. The multi-component plastic article of claim 1 , wherein the Copolymer Tan Delta Peak Temperature is greater than −40° C. but less than −10° C.

6. The multi-component plastic article of claim 1 , wherein the Compound Tan Delta Peak Temperature is at least −10° C.

7. The multi-component plastic article of claim 1 , wherein the tackifier has a weight average molecular weight ranging from about 400 to about 3,500.

8. The multi-component plastic article of claim 1 , wherein the tackifier comprises a saturated cyclo-aliphatic amorphous hydrocarbon resin.

Assignments (5)
RELEASE OF SECURITY INTERESTS IN PATENTS RECORDED AT REEL 041373, FRAME 0454. Recorded Jun 24, 2025
From: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
To: AVIENT CORPORATION (F/K/A POLYONE CORPORATION); COLORMATRIX HOLDINGS, INC.; GSDI SPECIALTY DISPERSIONS, INC.
Reel/Frame 071708/0258 →
SUPPLEMENTAL TERM LOAN PATENT SECURITY AGREEMENT Recorded Jun 17, 2025
From: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.; COLORMATRIX GROUP, INC.
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 071656/0450 →
SECURITY AGREEMENT Recorded Jun 12, 2025
From: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.; COLORMATRIX GROUP, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 071574/0571 →
CHANGE OF NAME Recorded Jul 13, 2020
From: POLYONE CORPORATION
To: AVIENT CORPORATION
Reel/Frame 053197/0141 →
SECURITY INTEREST Recorded Feb 24, 2017
From: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.; GSDI SPECIALTY DISPERSIONS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 041373/0454 →