Titanium dioxide pigment grind dispersion and paint

1. A pigment grind dispersion comprising non-adsorbed titanium dioxide particles dispersed in an aqueous emulsion containing a mixture of:

(a) water-insoluble film-forming first polymer particles that adsorb to titanium dioxide particles, the first polymer particle amount in the emulsion being less than the saturation level of adsorption when another polymer is not present,

(b) water-insoluble film-forming second polymer particles that do not by themselves form composite particles with titanium dioxide particles, the second polymer particle amount in the emulsion being sufficient to inhibit or interfere with adsorption of the first polymer particles to titanium dioxide particles, and

(c) extender particles,

wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60.

2. A pigment grind dispersion according to claim 1 , further comprising a dispersing agent.

3. A pigment grind dispersion according to claim 2 , wherein the dispersion is circulating.

4. A pigment grind dispersion according to claim 3 , further comprising a defoamer.

5. A pigment grind dispersion according to claim 1 , having a titanium dioxide pigment volume concentration of about 30 to about 50.

6. A pigment grind dispersion according to claim 1 , having a titania composite ratio of about 32 to about 50.

7. A pigment grind dispersion according to claim 1 , containing about 27 to about 37 weight percent titanium dioxide particles, about 18 to about 49 weight percent first polymer particles, and about 55 to about 14 weight percent second polymer particles, based on the dry weights of these particles compared to the total dry weight of ingredients in the pigment grind dispersion.

8. A pigment grind dispersion according to claim 7 , containing up to about 100 weight percent extender particles based on the weight of titanium dioxide particles.

9. A pigment grind dispersion according to claim 1 , wherein the first polymer particles include pendant phosphorus groups, acetoacetoxy groups, 1,3-dicarbonyl groups, aldehyde groups, acid groups, amine groups, epoxy groups, isocyanate groups, thiorane groups, isothiocyanate groups, alcohol groups, carbodiimide groups, aziridine groups, haloalkane groups, or halophenyl groups.

10. A pigment grind dispersion according to claim 1 , wherein the first polymer particles include pendant phosphorus groups.

11. A pigment grind dispersion according to claim 10 , wherein the phosphorus groups include acid groups.

12. A pigment grind dispersion according to claim 10 , wherein the phosphorus groups include dihydrogen phosphate groups.

13. A pigment grind dispersion according to claim 1 , wherein the first polymer particles are multistage polymers.

14. A pigment grind dispersion according to claim 1 , wherein the first polymer particles are free of voids.

15. A pigment grind dispersion according to claim 1 , wherein the second polymer particles comprise acrylic, ethylene vinyl acetate, polybutadiene, polyvinylidene, styrene acrylic, vinyl acrylic or vinyl acetate-vinyl versatate particles, or a mixture thereof.

16. A pigment grind dispersion according to claim 1 , wherein the second polymer particles are acrylic latex particles.

17. A coating composition comprising a pigment grind dispersion according to claim 1 , and additional water-insoluble film-forming emulsion polymer particles that do not adsorb to the titanium dioxide particles.

18. A coating composition according to claim 17 , further comprising one or more pigments other than titanium dioxide.

19. A coating composition according to claim 17 , further comprising one or more coalescents, cosolvents or plasticizers.

20. A coating composition according to claim 17 , further comprising one or more rheology modifiers.