GOLF BALL INCORPORATING AT LEAST ONE NON-ISOCYANATE-CONTAINING POLYURETHANE LAYER
A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of: at least one amine or polyamine, having an average functionality of 2.0 or greater, and at least one cyclo-carbonate. The amine may be selected for example from the group consisting of: ethylenediamine, hexamethylenediamine, or tris(2-aimnoethyl)amine, or blends thereof; and the polyamine may be selected for example from the group consisting of polyoxypropylene diamines, polyoxypropylene triamines, and combinations thereof. The cyclo-carbonate may comprise for example bis(cyclo-carbonate). Other possible reaction products include: (i) the at least one amine or polyamine and at least one epoxy-cyclo-carbonate oligomer, wherein the non-isocyanate-containing polyurethane composition can be modified with at least one of acrylic or siloxane; or (ii) the at least one amine or polyamine and at least one cyclo-carbonated soybean oil; or (iii) at least one lignin-based polyamine and at least one cyclo-carbonated soybean oil.
1 . A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one amine or polyamine having an average functionality of 2.0 or greater, and at least one cyclo-carbonate.
2 . The golf ball of claim 1 , wherein the at least one cyclo-carbonate comprises bis(cyclo-carbonate).
3 . The golf ball of claim 2 , wherein the at least one amine is selected from the group consisting of: ethylenediamine, hexamethylenediamine, or tris(2-aimnoethyl)amine, or blends thereof.
4 . The golf ball of claim 3 , wherein the at least one polyamine is selected from the group consisting of polyoxypropylene diamines, polyoxypropylene triamines, and combinations thereof.
5 . The golf ball of claim 1 , wherein the at least one layer is a core layer.
6 . The golf ball of claim 1 , wherein the at least one layer is an intermediate layer disposed about a thermoset core.
7 . The golf ball of claim 1 , wherein the at least one layer is a cover layer.
8 . The golf ball of claim 1 , wherein the at least one layer is a coating layer that is formed about an outermost cover layer of the golf ball.
9 . The golf ball of claim 1 , wherein the at least one layer is a tie layer that is disposed between and adjacent to two differing golf ball layers that do not comprise the non-isocyanate-containing polyurethane composition.
10 . The golf ball of claim 1 , wherein the non-isocyanate-containing polyurethane composition further comprises density-adjusting fillers, process aides, plasticizers, blowing or foaming agents, fillers such as metal powder, metal alloy powder, metal oxide, metal stearates, particulates, flakes, fibers, carbonaceous material, or combinations thereof.
11 . A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one amine or polyamine, having an average functionality of 2.0 or greater, and at least one epoxy-cyclo-carbonate oligomer.
12 . The golf ball of claim 11 , wherein the non-isocyanate-containing polyurethane composition is modified with at least one of acrylic or siloxane.
13 . The golf ball of claim 11 , wherein the at least one layer is a cover layer.
14 . The golf ball of claim 11 , wherein the at least one layer is a coating layer that is formed about an outermost cover layer of the golf ball.
15 . The golf ball of claim 11 , wherein the at least one layer is a tie layer that is disposed between and adjacent to two golf ball layers that are formed from different materials and do not comprise the non-isocyanate-containing polyurethane composition.
16 . The golf ball of claim 11 , wherein the non-isocyanate-containing polyurethane composition further comprises density-adjusting fillers, process aides, plasticizers, blowing or foaming agents, fillers such as metal powder, metal alloy powder, metal oxide, metal stearates, particulates, flakes, fibers, carbonaceous material, or combinations thereof.
17 . A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one amine or polyamine having an average functionality of 2.0 or greater, and at least one cyclo-carbonated soybean oil.
18 . The golf ball of claim 17 , wherein the at least one layer is a cover layer.
19 . The golf ball of claim 17 , wherein the at least one layer is a coating layer that is formed about an outermost cover layer of the golf ball.
20 . The golf ball of claim 17 , wherein the at least one layer is a tie layer that is disposed between and adjacent to two golf ball layers that are formed from different materials and do not comprise the non-isocyanate-containing polyurethane composition.
21 . The golf ball of claim 17 , wherein the non-isocyanate-containing polyurethane composition further comprises density-adjusting fillers, process aides, plasticizers, blowing or foaming agents, fillers such as metal powder, metal alloy powder, metal oxide, metal stearates, particulates, flakes, fibers, carbonaceous material, or combinations thereof.
22 . A golf ball comprising at least one layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one lignin-based polyamine and at least one cyclo-carbonated soybean oil.
23 . The golf ball of claim 22 , wherein the at least one layer is a cover layer.
24 . The golf ball of claim 22 , wherein the at least one layer is a coating layer that is formed about an outermost cover layer of the golf ball.
25 . The golf ball of claim 22 , wherein the at least one layer is a tie layer that is disposed between and adjacent to two golf ball layers that are formed from different materials and do not comprise the non-isocyanate-containing polyurethane composition.
23 . The golf ball of claim 22 , wherein the non-isocyanate-containing polyurethane composition further comprises density-adjusting fillers, process aides, plasticizers, blowing or foaming agents, fillers such as metal powder, metal alloy powder, metal oxide, metal stearates, particulates, flakes, fibers, carbonaceous material, or combinations thereof.
24 . A golf ball comprising:
a first layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one amine or polyamine having an average functionality of 2.0 or greater, and at least one cyclo-carbonate;
wherein the first layer is disposed between and adjacent to a second inner layer and third outer layer, each which do not contain the non-isocyanate-containing polyurethane composition of the first layer;
wherein the first layer has a first coefficient of restitution that is less than a second coefficient of restitution of the second inner layer and less than a third coefficient of restitution of the third outer layer; and
wherein the golf ball as a whole has a ball coefficient of restitution that is greater than the first coefficient of restitution and less than at least one of the second coefficient of restitution and the third coefficient of restitution.
25 . A golf ball comprising:
a first layer consisting of a non-isocyanate-containing polyurethane composition comprising the reaction product of at least one amine or polyamine having an average functionality of 2.0 or greater, and at least one cyclo-carbonate;
wherein the first layer is adjacent to a second layer that does not contain the non-isocyanate-containing polyurethane composition of the first layer;
wherein the first layer has a first coefficient of restitution that is less than a second coefficient of restitution of the second layer; and
wherein the golf ball as a whole has a ball coefficient of restitution that is greater than the first coefficient of restitution.