Granted Patent B2

US 10,287,824 · App. 15/060,911 · Granted May 14, 2019

Abstract

Claims (17)

1. A method of forming polycrystalline diamond, comprising:

subjecting diamond particles in the presence of a metal material comprising a Group VIII metal and aluminum to a pressure of at least 4.5 GPa and a temperature of at least 1,000° C. to form inter-granular bonds between adjacent diamond particles;

cooling the diamond particles and the metal material to a temperature below an ordered-disordered transition temperature; and

forming an ordered intermetallic gamma prime (γ′) or κ-carbide phase adjacent the diamond particles, the ordered intermetallic gamma prime (γ′) or κ-carbide phase comprising the Group VIII metal, aluminum, and a stabilizer.

2. The method of claim 1 , wherein subjecting diamond particles to a pressure of at least 4.5 GPa and a temperature of at least 1,000° C. comprises dissolving the stabilizer in a mixture of the Group VIII metal and the aluminum.

3. The method of claim 2 , wherein dissolving the stabilizer in a mixture of the Group VIII metal and the aluminum comprises dissolving carbon originating from the diamond particles into a molten alloy comprising the Group VIII metal and the aluminum.

4. The method of claim 1 , further comprising admixing the diamond particles with particles comprising at least one material selected from the group consisting of the Group VIII metal, the aluminum, and the stabilizer.

5. The method of claim 1 , further comprising disposing the diamond particles in a container with a metal foil comprising at least one material selected from the group consisting of the Group VIII metal, the aluminum, and the stabilizer.

6. The method of claim 1 , further comprising forming the polycrystalline diamond in the form of a finished cutting element comprising a diamond table including the ordered intermetallic gamma prime (γ′) or κ-carbide phase comprising the Group VIII metal, aluminum, and the stabilizer.

7. The method of claim 1 , further comprising at least substantially entirely filling interstitial spaces between the diamond particles with the gamma prime (γ′) or κ-carbide phase.

8. The method of claim 1 , wherein forming an ordered intermetallic gamma prime (γ′) or κ-carbide phase adjacent the diamond particles comprises forming the ordered intermetallic gamma prime (γ′) or κ-carbide phase comprising the Group VIII metal, aluminum, and a stabilizer selected from the group consisting of titanium, nickel, tungsten, and carbon.

9. The method of claim 1 , wherein forming an ordered intermetallic gamma prime (γ′) or κ-carbide phase comprises forming a metastable Co 3 Al phase stabilized by the stabilizer.

10. The method of claim 1 , wherein forming an ordered intermetallic gamma prime (γ′) or κ-carbide phase comprises forming a metastable (Co x Ni 3-x )Al phase stabilized by the stabilizer.

11. The method of claim 1 , further comprising forming a thermally stable polycrystalline diamond compact comprising the diamond particles without leaching.

12. The method of claim 1 , further comprising forming the polycrystalline diamond in the form of a finished cutting element comprising a diamond table including the ordered intermetallic gamma prime (γ′) or κ-carbide phase comprising the Group VIII metal, aluminum, and the stabilizer.

13. The method of claim 1 , further comprising coating the diamond particles with at least one material selected from the group consisting of the Group VIII metal, the aluminum, and the stabilizer.

14. The method of claim 1 , wherein forming an ordered intermetallic gamma prime (γ′) or κ-carbide phase adjacent the diamond particles comprises forming the ordered intermetallic gamma prime (γ′) or κ-carbide phase comprising substantially all of the Group VIII metal.

Assignments (10)