Low ash lubricant and fuel additive comprising alkoxylated amine
View Patent ↗A lubricating oil detergent composition comprises an overbased calcium sulfonate and a low ash detergent, which low ash detergent is metal free and comprises the reaction product of an acidic organic compound such as an alkylated salicylic acid, a boron compound and an amine component.
1. A lubricant composition comprising:
at least 70 wt % of an oil of lubricating viscosity based on the weight of the lubricant composition, of an oil of lubricating viscosity and
a detergent composition for lubricants and fuels, said detergent composition comprising
an overbased calcium sulfonate having a TBN of about 410 and
4 to 7 wt % of a low ash detergent, based on the weight of the combination of overbased calcium sulfonate and low ash detergent,
wherein the detergent composition contains no phenate, and the low ash detergent is the reaction product of:
a) one or more alkylated salicylic acids of formula I:
wherein R 1 is selected from the group consisting of dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl and isomers thereof, and ‘a’ is an integer of 1 or 2;
b) boric acid; and
c) ethoxylated tallow amine
wherein the low ash detergent has a TBN of from 96 to 115 and contains no metals, phosphorus or sulfur, and the lubricant composition contains no phenate.
2. The lubricant composition according to claim 1 comprising from about 80 to about 99.5 wt. % of the oil of lubricating viscosity.
3. The lubricant composition according to claim 1 wherein the oil of lubricating viscosity is a marine cylinder oil.
4. The lubricant composition according to claim 1 , which lubricant composition has a TBN of 70.
5. The lubricant composition according to claim 1 wherein R1 in formula I is selected from the group consisting of tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl and isomers thereof.
6. The lubricant composition according to claim 5 comprising from about 80 to about 99.5 wt. % of the oil of lubricating viscosity.
7. The lubricant composition according to claim 5 wherein the oil of lubricating viscosity is a marine cylinder oil.
8. The lubricant composition according to claim 5 , which lubricant composition has a TBN of 70.
9. The lubricant composition according to claim 5 wherein R1 in formula I is selected from the group consisting of tetradecyl, hexadecyl, octadecyl and isomers thereof.
10. The lubricant composition according to claim 9 comprising from about 80 to about 99.5 wt. % of the oil of lubricating viscosity.
11. The lubricant composition according to claim 9 wherein the oil of lubricating viscosity is a marine cylinder oil.
12. The lubricant composition according to claim 9 which lubricant composition has a TBN of 70.