Electrode composition, electrode manufactured using the same, and solar cell
An electrode composition, including a conductive powder; a glass frit; and an organic vehicle including an organic binder, a multi-functional (meth)acrylate compound, and a solvent, the multi-functional (meth)acrylate compound having a molecular weight of about 200 to about 500, and being present in an amount of about 0.15 wt % to about 2 wt % based on 100 wt % of the electrode composition.
1. An electrode composition to form an electrode in which a multi-functional (meth)acrylate compound in the electrode composition remains uncured in the electrode, the electrode composition consisting essentially of:
a conductive powder;
a glass frit;
an organic vehicle including an organic binder, a multi-functional (meth)acrylate compound, and a solvent, and
at least one additive selected from a surface-treatment agent, a dispersing agent, a thixotropic agent, a plasticizer, a viscosity stabilizer, an antifoaming agent, a pigment, an ultraviolet (UV) stabilizer, an antioxidant, and a coupling agent;
the organic binder having a weight average molecular weight of about 30,000 to about 150,000 and the multi-functional (meth)acrylate compound having a molecular weight of about 200 to about 500, the multi-functional (meth)acrylate compound being present in an amount of about 0.15 wt % to about 2 wt % based on 100 wt % of the electrode composition.
2. The electrode composition as claimed in claim 1 , wherein the multi-functional (meth)acrylate compound is one or more of a di(meth)acrylate compound, a tri(meth)acrylate compound, or a tetra(meth)acrylate compound.
3. The electrode composition as claimed in claim 1 , wherein the multi-functional (meth)acrylate compound is one or more of trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, butanediol di(meth)acrylate, hexanediol di(meth)acrylate, pentaerythritol tri(meth)acrylate, trimethylol tri(meth)acrylate, or pentaerythritol tetra(meth)acrylate.
4. The electrode composition as claimed in claim 1 , wherein the multi-functional (meth)acrylate compound is present in an amount of about 0.2 wt % to about 2 wt % based on 100 wt % of the electrode composition.
5. The electrode composition as claimed in claim 1 , wherein the molecular weight of the multi-functional (meth)acrylate compound is about 250 to about 400.
6. The electrode composition as claimed in claim 1 , wherein the multi-functional (meth)acrylate compound remains in a resultant film after heat treatment at about 200° C. to about 400° C.
7. The electrode composition as claimed in claim 1 , wherein the glass frit is one or more of a bismuth-based glass frit or a lead-based glass fit.
8. The electrode composition as claimed in claim 7 , wherein the bismuth-based glass frit is bismuth (Bi)-tellurium (Te) glass frit.
9. The electrode composition as claimed in claim 8 , wherein the bismuth (Bi)-tellurium (Te) glass frit includes about 20 to about 80 mol % of tellurium oxide and about 20 to about 80 mol % of bismuth oxide.
10. The electrode composition as claimed in claim 1 , wherein the electrode composition includes about 60 to about 95 wt % of the conductive powder, about 0.5 to about 20 wt % of the glass fit, and about 1 to about 30 wt % of the organic vehicle.
11. An electrode manufactured using the electrode composition as claimed in claim 1 , the electrode including the multi-functional (meth)acrylate compound in an uncured state in the electrode.
12. A solar cell, comprising the electrode as claimed in claim 11 .