Fluorinated elastomer composition and method for its production, molded product, cross-linked product, and covered electric wire
View Patent ↗To provide a fluorinated elastomer composition which is excellent in heat discoloration resistance and moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a fluorinated rubber (a) and a fluorinated copolymer (b), wherein the fluorinated copolymer (b) has units (A) derived from tetrafluoroethylene and units (B) derived from ethylene in a molar ratio [(A)/(B)] of the units (A) to the units (B) of from 25/75 to 80/20; the fluorinated copolymer (b) has a crystallization temperature of from 100 to 210° C. and a melt flow rate of from 0.1 to 1,000 g/10 min.; and the mass ratio [(a)/(b)] of the fluorinated rubber (a) to the fluorinated copolymer (b) is from 80/20 to 20/80.
1. A fluorinated elastomer composition comprising a fluorinated rubber (a) and a fluorinated copolymer (b), wherein
the fluorinated copolymer (b) has units (A) derived from tetrafluoroethylene and units (B) derived from ethylene in a molar ratio [(A)/(B)] of the units (A) to the units (B) of from 25/75 to 80/20,
the fluorinated copolymer (b) has a crystallization temperature of from 100 to 210° C. and a melt flow rate of from 0.1 to 1,000 g/10 min., and
the mass ratio [(a)/(b)] of the fluorinated rubber (a) to the fluorinated copolymer (b) is from 80/20 to 20/80.
2. The fluorinated elastomer composition according to claim 1 , wherein the fluorinated rubber (a) is a copolymer comprising from 35 to 70 mol % of units derived from tetrafluoroethylene, from 20 to 55 mol % of units derived from propylene, and from 0 to 40 mol % of units derived from other monomer.
3. The fluorinated elastomer composition according to claim 1 , wherein the fluorinated copolymer (b) further contains units (C) derived from CH 2 ═CH(CF 2 ) Q F (wherein Q is an integer of from 2 to 10), in a molar ratio [(A)/(C)] of the units (A) to the units (C) of from 85/15 to 99.9/0.1.
4. The fluorinated elastomer composition according to claim 3 , wherein the fluorinated copolymer (b) further contains units (D) derived from other monomer, in a molar ratio [(A)/(D)] of the units (A) to the units (D) of from 70/30 to 99.9/0.1.
5. The fluorinated elastomer composition according to claim 4 , wherein the units (D) contains units derived from hexafluoropropylene.
6. The fluorinated elastomer composition according to claim 1 , which further contains an ethylene copolymer (c) containing epoxy groups, in a mass ratio [(b)/(c)] of the fluorinated copolymer (b) to the ethylene copolymer (c) containing epoxy groups of from 100/0.1 to 100/10.
7. A method for producing the fluorinated elastomer composition as defined in claim 1 , which comprises a step of kneading a material containing the fluorinated rubber (a) and the fluorinated copolymer (b) under a heating condition of from 100 to 240° C.
8. The method for producing the fluorinated elastomer composition according to claim 7 , wherein the kneading step is a step of kneading the mixture by an extruder for from 1 to 30 minutes.
9. A molded product obtained by molding the fluorinated elastomer composition as defined in claim 1 .
10. A cross-linked product obtained by cross-linking the fluorinated elastomer composition as defined in claim 1 .
11. A covered electric wire comprising a conductor and a covering material for covering the conductor, wherein the covering material is the fluorinated elastomer composition as defined in claim 1 .
12. A covered electric wire comprising a conductor and a covering material for covering the conductor, wherein the covering material is the cross-linked product as defined in claim 10 .