IP Library Granted Patent US 9,873,928
Granted Patent B2
US 9,873,928 · App. 15/071,114 · Granted Jan 23, 2018

High strength cast iron for cylinder liners

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Quick Facts
Patent No.
US 9,873,928
App. No.
15/071,114
Granted
Jan 23, 2018
Kind
B2
Abstract

A cast iron having high strength, hardness, and thermal conductivity for a cylinder liner of an internal combustion engine is provided. The cast iron includes 3.2 wt. % to 3.8 wt. % carbon, 2.2 wt. % to 3.2 wt. % silicon, 0.5 wt. % to 1.3 wt. % copper, and at least 75.0 wt. % iron, based on the total weight of the cast iron. The cast iron further includes 0.01 wt. % to 0.5 wt. % manganese, 0.01 wt. % to 0.2 wt. % chromium, up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, and up to 0.1 wt. % magnesium, based on the total weight of the cast iron. Preferably, the cast iron is free of molybdenum, nickel, and vanadium. The cast iron is also heat treated and solidifies to achieve fully spheroidal graphite.

Claims (26)

1. A cast iron for a cylinder liner, comprising:

3.2 wt. % to 3.8 wt. % carbon, 2.2 wt. % to 3.2 wt. % silicon, 0.5 wt. % to 1.3 wt. % copper, 0.01 wt. % to 0.5 wt. % manganese, 0.01 wt. % to 0.2 wt. % chromium, not greater than 0.01 wt. % molybdenum, not greater than 0.01 wt. % nickel, and not greater than 0.01 wt. % vanadium, and at least 75.0 wt. % iron, based on the total weight of the cast iron;

the cast iron including graphite, wherein at least a portion of the graphite is spheroidal graphite; and

the cast iron having a strength ranging from 600 to 900 MPa.

2. The cast iron of claim 1 further including up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, and up to 0.1 wt. % magnesium, based on the total weight of the cast iron.

3. The cast iron of claim 1 , wherein the graphite consists of spheroidal graphite.

4. The cast iron of claim 1 further including up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, up to 0.1 wt. % magnesium, 0.0 wt. % molybdenum, 0.0 wt. % nickel, and 0.0 wt. % vanadium, based on the total weight of the cast iron; and

wherein 100% of the graphite present in the cast iron is spheroidal graphite.

5. A cylinder liner formed of cast iron, the cast iron comprising:

3.2 wt. % to 3.8 wt. % carbon, 2.2 wt. % to 3.2 wt. % silicon, 0.5 wt. % to 1.3 wt. % copper, 0.01 wt. % to 0.5 wt. % manganese, 0.01 wt. % to 0.2 wt. % chromium, not greater than 0.01 wt. % molybdenum, not greater than 0.01 wt. % nickel, and not greater than 0.01 wt. % vanadium, and at least 75.0 wt. % iron, based on the total weight of the cast iron;

the cast iron including graphite, and at least a portion of the graphite is spheroidal graphite; and

the cast iron having a strength ranging from 600 to 900 MPa.

6. The cylinder liner of claim 5 , wherein the cast iron further includes up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, and up to 0.1 wt. % magnesium, based on the total weight of the cast iron.

7. The cylinder liner of claim 5 , wherein the graphite present in the cast iron consists of spheroidal graphite.

8. The cylinder liner of claim 5 , wherein the cast iron forms a body extending circumferentially a center axis and longitudinally between opposite ends;

the body includes an inner surface facing the center axis and an outer surface facing opposite the inner surface and away from the center axis;

the inner surface of the body presents an opening having a cylindrical shape; and

the cast iron further includes up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, up to 0.1 wt. % magnesium, 0.0 wt. % molybdenum, 0.0 wt. % nickel, and 0.0 wt. % vanadium, based on the total weight of the cast iron, and wherein 100% of the graphite present in the cast iron is spheroidal graphite.

9. A method of manufacturing cast iron for a cylinder liner, comprising the steps of:

providing an alloy including 3.2 wt. % to 3.8 wt. % carbon, 2.2 wt. % to 3.2 wt. % silicon, 0.5 wt. % to 1.3 wt. % copper, 0.01 wt. % to 0.5 wt. % manganese, 0.01 wt. % to 0.2 wt. % chromium, not greater than 0.01 wt. % molybdenum, not greater than 0.01 wt. % nickel, and not greater than 0.01 wt. % vanadium, and at least 75.0 wt. % iron, based on the total weight of the alloy; and

melting and solidifying the alloy to form the cast iron including graphite, wherein at least a portion of the graphite formed is spheroidal graphite, and the cast iron having a strength ranging from 600 to 900 MPa.

10. The method of claim 9 , wherein the alloy further includes up to 0.3 wt. % phosphorous, up to 0.05 wt. % sulfur, up to 0.2 wt. % tin, and up to 0.1 wt. % magnesium, based on the total weight of the alloy.

11. The method of claim 9 , wherein the graphite formed consists of spheroidal graphite.

12. A method of manufacturing a cylinder liner formed of cast iron, comprising the steps of:

providing an alloy including 3.2 wt. % to 3.8 wt. % carbon, 2.2 wt. % to 3.2 wt. % silicon, 0.5 wt. % to 1.3 wt. % copper, 0.01 wt. % to 0.5 wt. % manganese, 0.01 wt. % to 0.2 wt. % chromium, not greater than 0.01 wt. % molybdenum, not greater than 0.01 wt. % nickel, and not greater than 0.01 wt. % vanadium, and at least 75.0 wt. % iron, based on the total weight of the alloy; and

melting and solidifying the alloy to form the cast iron including graphite, wherein at least a portion of the graphite formed is spheroidal graphite, and the cast iron having a strength ranging from 600 to 900 MPa.

Assignments (15)
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 22, 2019
From: FEDERAL-MOGUL IGNITION COMPANY
To: FEDERAL-MOGUL IGNITION LLC
Reel/Frame 049821/0536 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Sep 26, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, LLC
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 044013/0419 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Jun 23, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, INC.
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 042963/0662 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2016
From: GEKONDE, HARON; MILLER, JOHN; KANTOLA, TROY; JENNESS, BLAIR; HUNTER, JEFF
To: FEDERAL-MOGUL IGNITION COMPANY
Reel/Frame 038453/0939 →