Multilayer composite comprising a polyester layer
View Patent ↗A multilayer composite containing the following layers: I. a first layer (layer I) of a molding compound containing at least 40 wt. % of the following components: 1) 60 to 99 parts by wt. of a copolyamide based on hexamethylenediamine, terephthalic acid and an aliphatic dicarboxylic acid having 8 to 19 carbon atoms and 2) 40 to 1 parts by wt. of an olefinic copolymer as impact modifier, wherein the parts by wt. of 1) and 2) sum to 100; and II. a second layer (layer II) of a molding compound containing at least 60 wt. % of thermoplastic polyester, has a high heat distortion temperature, a very good impact resistance, a high elongation at break and good layer adhesion.
1. A multilayer composite, comprising in the order listed:
an outer layer of a moulding compound comprising at least 40 wt. % polymer components; wherein the polymer components consist of:
1) 60 to 99 parts by wt. of a partially aromatic copolyamide which contains monomer units which are obtained from
α) 41 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid, and
β) 59 to 10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8 to 19 carbon atoms;
wherein the mol % values relate to the sum of α) and β) and
wherein not more than 20% of the hexamethylenediamine is optionally replaced by the equivalent amount of another diamine, and/or
wherein not more than 20% of the terephthalic acid is optionally replaced by the equivalent amount of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid, and/or
wherein not more than 20% of the repeating units containing hexamethylenediamine and linear aliphatic dicarboxylic acid is optionally replaced by the equivalent quantity of units obtained from a lactam/an ω-aminocarboxylic acid having 6 to 12 carbon atoms,
2) 40 to 1 parts by wt. of an olefinic copolymer, comprising:
from 35 to 94.9 wt %, of monomer units based on ethene,
from 5 to 65 wt %, of monomer units based on a 1-alkene having 4 to 8 carbon atoms, and
from 0.1 to 2.5 wt % of monomer units based on an aliphatically unsaturated dicarboxylic anhydride, as impact modifier;
an adhesion promoter layer;
an interlayer of a moulding compound comprising at least 60 wt. % of a thermoplastic polyester;
an adhesion promoter layer; and
an inner layer of a moulding compound comprising at least 40 wt. % polymer components; wherein the polymer components consist of:
1) 60 to 99 parts by wt. of a partially aromatic copolyamide which contains monomer units which are obtained from
α) 41 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid, and
β) 59 to 10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8 to 19 carbon atoms;
wherein the mol % values relate to the sum of α) and β) and
wherein not more than 20% of the hexamethylenediamine is optionally replaced by the equivalent amount of another diamine, and/or
wherein not more than 20% of the terephthalic acid is optionally replaced by the equivalent amount of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid, and/or
wherein not more than 20% of the repeating units containing hexamethylenediamine and linear aliphatic dicarboxylic acid is optionally replaced by the equivalent quantity of units obtained from a lactam/an ω-aminocarboxylic acid having 6 to 12 carbon atoms,
2) 40 to 1 parts by wt. of an olefinic copolymer, comprising:
from 35 to 94.9 wt %, of monomer units based on ethene,
from 5 to 65 wt %, of monomer units based on a 1-alkene having 4 to 8 carbon atoms, and
from 0.1 to 2.5 wt % of monomer units based on an aliphatically unsaturated dicarboxylic anhydride, as impact modifier,
wherein the moulding compound of the outer layer and the moulding compound of the inner layer are the same.
2. The multilayer composite according to claim 1 , wherein the moulding compound of the outer layer further comprises 0.01 to 60 wt. % of at least one additive.
3. The multilayer composite according to claim 2 , wherein the at least one additive is a copper-containing stabilizer.
4. The multilayer composite according to claim 2 , wherein the at least one additive is an oxidation stabilizer.
5. The multilayer composite according to claim 1 , wherein the crystallite melting point T m of the copolyamide is from 220° C. to 300° C. when measured as per ISO 11357 at 2nd heating.
6. The multilayer composite according to claim 1 , wherein the thermoplastic polyester of the moulding compound of the interlayer is selected from the group consisting of polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, polyethylene 2,6-naphthalate), poly(propylene 2,6-naphthalate), poly(butylene 2,6-naphthalate) and mixtures thereof.
7. The multilayer composite according to claim 1 , further comprising at least one additional layer.
8. The multilayer composite according to claim 7 , wherein the at least one additional layer is selected from the group consisting of
a further interlayer,
an adhesion promoter layer,
a layer of a moulding compound based on an aliphatic polyimide,
a layer of a moulding compound based on a fluoropolymer, and
combinations thereof.
9. The multilayer composite according to claim 1 , which is a film, a sheet or a hollow article.
10. The multilayer composite according to claim 9 , which is a hollow profile.
11. The multilayer composite according to claim 10 , which further comprises one or more layers selected from the group consisting of an electrically conductive layer, an elastomer sheathing and combinations thereof.
12. The multilayer composite according to claim 10 , wherein said composite is a fuel line, a hydraulic line, a brake line, a clutch line, a coolant line, a liner for rigid or flexible pipes in the oil or gas extraction industry or a line for an umbilical.
13. The multilayer composite according to claim 10 , wherein said composite is a brake fluid container or a fuel container.
14. The multilayer composite according to claim 10 , wherein the hollow profile is a pipe, or a container.