Multilayer composite comprising a fluoropolymer layer
A multilayer composite containing the following layers: I. a first layer (layer I) of a moulding compound containing at least 40 wt. % of the following components: 1) 60 to 99 parts by wt. of a copolyamide based on hexamethylenediamine, terephthalic acid and an aliphatic dicarboxylic acid having 8 to 19 carbon atoms and 2) 40 to 1 parts by wt. of an olefinic copolymer as impact modifier, wherein the parts by wt. of 1) and 2) sum to 100; and II. a second layer (layer II) of a moulding compound containing at least 60 wt. % of fluoropolymer, has a high heat distortion temperature, a very good impact resistance, a high elongation at break and good layer adhesion.
1. A multilayer composite, comprising layers I and II:
wherein layer I comprises
at least 40 wt. % of components 1) and 2):
1) a copolyamide having a crystallite m.p. of from 240 to 290° C. when measured as per ISO 11357 at 2nd heating, which contains as copolymerized monomer units:
α) 30 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid, and
β) 70 to 10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8 to 19 carbon atoms;
wherein the mol % values relate to the sum of α) and β) and
optionally, wherein not more than 20 mol % of the hexamethylenediamine is replaced by the equivalent amount of another diamine, and/or
optionally, wherein not more than 20 mol % of the terephthalic acid is replaced by the equivalent amount of another aromatic dicarboxylic acid and/or 1,4-cyclohexanedicarboxylic acid, and/or
optionally, wherein not more than 20 mol % of the repeating units containing hexamethylenediamine and linear aliphatic dicarboxylic acid is replaced by the equivalent quantity of units obtained from a lactam/an ω-aminocarboxylic acid having 6 to 12 carbon atoms,
2) an olefinic copolymer as impact modifier, the olefinic copolymer consisting of:
a) 50 to 99.9 wt % of ethene and 1-butene, and
c) 0.1 to 50 wt % of an olefinically unsaturated dicarboxylic anhydride;
wherein when total parts by weight of 1) and 2) is 100 parts, the parts of 2) is from 1 to 40,
and at least 0.01 wt % of
3) at least one additive selected from the group consisting of stabilizers, plasticizers, pigments, dyes, and an additive to increase electrical conductivity;
wherein the total wt % of components 1), 2), and 3) is 100% relative to the total weight of layer I, and
II. a second layer (layer II) of a moulding compound comprising at least 60 wt. % of fluoropolymer; wherein the layer II is in contact with the layer I.
2. The multilayer composite according to claim 1 , wherein layer I comprises 0.01 to 60 wt. % of the at least one additive.
3. The multilayer composite according to claim 2 , wherein the at least one additive comprises a copper-containing stabilizer.
4. The multilayer composite according to claim 2 , wherein the at least one additive comprises an oxidation stabilizer.
5. The multilayer composite according to claim 1 , wherein the fluoropolymer of the moulding compound of layer II comprises a polymer selected from the group consisting of
a polyvinylidene fluoride (PVDF),
a copolymer based on vinylidene fluoride comprising up to 40 wt. % of another monomer,
an ethylene-tetrafluoroethylene copolymer (ETFE),
an ETFE modified using a ter component,
an ethylene-chlorotrifluoroethylene copolymer (E-CTFE),
a polychlorotrifluoroethylene (PCTFE),
a tetrafluoroethylene-hexafluoropropene-vinylidene fluoride copolymer (THV),
a tetrafluoroethylene-hexafluoropropene copolymer (FEP),
a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), and
mixtures thereof.
6. The multilayer composite according to claim 1 , further comprising one or more layers.
7. The multilayer composite according to claim 6 , wherein the further comprised layer or the further comprised layers are selected from the group consisting of
an additional layer of composition I,
an additional layer of composition II,
an adhesion promoter layer,
a layer of a moulding compound based on an aliphatic polyamide,
a layer of a polyester moulding compound,
a layer of an EVOH moulding compound, and
combinations thereof.
8. The multilayer composite according to claim 1 , which is a film, a sheet or a hollow article.
9. The multilayer composite according to claim 8 , which is a hollow article and wherein the hollow article is a hollow profile.
10. The multilayer composite hollow profile according to claim 9 , which further comprising one or more layers selected from the group consisting of an electrically conductive layer, an elastomer sheathing and combinations thereof.
11. The multilayer composite hollow profile according to claim 9 , wherein said composite is a fuel line, a hydraulic line, a brake line, a clutch line, a coolant line, a liner for rigid or flexible pipes in the oil or gas extraction industry or a line for an umbilical.
12. The multilayer composite hollow profile according to claim 9 , wherein said composite is a brake fluid container or a fuel container.
13. The multilayer composite according to claim 5 , wherein the moulding compound of layer II comprises an ETFE polymer comprising propene, hexafluoropropene, vinyl fluoride, or vinylidene fluoride.
14. The multilayer composite according to claim 9 , wherein the hollow profile is a pipe or a container.