Electrolytic solution and battery
An electrolytic solution for a secondary battery is provided. The electrolyte solution includes an electrolyte salt; and a solvent including a first solvent and a second solvent; wherein the first solvent includes 4-fluoro-1,3-dioxolane-2-one; and wherein the second solvent includes at least one of Chemical Formula No. 23, Chemical Formula No. 24, or Chemical Formula No. 25.
1. An electrolytic solution for a secondary battery, the electrolytic solution comprising:
an electrolyte salt; and
a solvent including a first solvent and a second solvent;
wherein the first solvent includes 4-fluoro-1,3-dioxolane-2-one; and
wherein the second solvent includes Chemical Formula No. 23 represented below:
wherein an amount of Chemical Formula No. 23 in the solvent ranges from 0.1 wt % to 1 wt %.
2. The electrolytic solution according to claim 1 , wherein the solvent further includes at least one of ethylene carbonate or dimethyl carbonate.
3. The electrolytic solution according to claim 2 , wherein the solvent further includes a cyclic carbonate including an unsaturated bond.
4. The electrolytic solution according to claim 3 , wherein the cyclic carbonate includes at least one of a vinylene carbonate-based compound, vinylene carbonate, a vinyl ethylene carbonate-based compound, vinyl ethylene carbonate, or a methylene ethylene carbonate-based compound.
5. The electrolytic solution according to claim 4 , wherein the solvent further includes at least one of a sultone, propene sultone, an acid anhydride, succinic anhydride, or sulfobenzoic anhydride.
6. The electrolytic solution according to claim 5 , wherein at least one of the sultone, propene sultone, the acid anhydride, succinic anhydride, or sulfobenzoic anhydride is in an amount from 0.5 wt % to 3 wt %.
7. The electrolytic solution according to claim 3 , wherein the cyclic carbonate is in an amount from 0.01 wt % to 5 wt %.
8. The electrolytic solution according to claim 1 , wherein the electrolyte salt includes lithium hexafluorophosphate.
9. The electrolytic solution according to claim 1 , wherein the electrolytic solution is for a lithium ion secondary battery.
10. An electrolytic solution for a secondary battery, the electrolytic solution comprising:
an electrolyte salt; and
a solvent including a first solvent and a second solvent, and the solvent does not include a trialkyl phosphate,
wherein the first solvent includes 4-fluoro-1,3-dioxolane-2-one,
the second solvent includes Chemical Formula No. 23 represented below:
and
an amount of Chemical Formula No. 23 in the solvent ranges from 0.1 wt % to 1 wt %.
11. The electrolytic solution according to claim 10 , wherein the solvent further includes at least one of ethylene carbonate or dimethyl carbonate.
12. The electrolytic solution according to claim 11 , wherein the solvent further includes a cyclic carbonate including an unsaturated bond.
13. The electrolytic solution according to claim 12 , wherein the cyclic carbonate includes at least one of a vinylene carbonate-based compound, vinylene carbonate, a vinyl ethylene carbonate-based compound, vinyl ethylene carbonate, or a methylene ethylene carbonate-based compound.
14. The electrolytic solution according to claim 13 , wherein the solvent further includes at least one of a sultone, propene sultone, an acid anhydride, succinic anhydride, or sulfobenzoic anhydride.
15. The electrolytic solution according to claim 14 , wherein at least one of the sultone, propene sultone, the acid anhydride, succinic anhydride, or sulfobenzoic anhydride is in an amount from 0.5 wt % to 3 wt %.
16. The electrolytic solution according to claim 12 , wherein the cyclic carbonate is in an amount from 0.01 wt % to 5 wt %.
17. The electrolytic solution according to claim 10 , wherein the electrolyte salt includes lithium hexafluorophosphate.
18. An electrolytic solution for a secondary battery, the electrolytic solution comprising:
at least a solvent including a first solvent and a second solvent,
wherein the second solvent includes Chemical Formula No. 23 represented below:
and
wherein an amount of Chemical Formula No. 23 in the solvent ranges from 0.1 wt % to 1 wt %.