Solid electrolyte compositions
A battery having an anode, a soft-solid electrolyte, and a cathode. The soft-solid electrolyte includes a polymer soft-solid material formed from polymer combined with a solvent such as butylene carbonate, butyl sulfoxide, n-methyl-2-pyrrolidone, or γ-caprolactone.
1. A battery, comprising:
an anode;
a cathode comprising a lithium-containing electrode active material having a spinel structure or a layered oxide structure; and
an electrolyte film including a lithium salt and a polymer soft-solid material, the polymer soft-solid material comprising a solvent selected from the group consisting of butylene carbonate, butyl sulfoxide, N-methyl-2-pyrrolidone, and γ-caprolactone and comprising an ethylene oxide polymer at a concentration of at least 15% of the total weight of the electrolyte film.
2. The battery of claim 1 , wherein the solvent comprises butylene carbonate.
3. The battery of claim 1 , wherein the solvent comprises butyl sulfoxide.
4. The battery of claim 1 , wherein the solvent comprises N-methyl-2-pyrrolidone.
5. The battery of claim 1 , wherein the solvent comprises γ-caprolactone.
6. The battery of claim 2 , wherein the lithium salt comprises lithium bis(trifluoromethanesulfonyl)imide.
7. The battery of claim 1 , wherein the solvent comprises butylene carbonate and about 20 molar percent lithium bis(trifluoromethanesulfonyl)imide.
8. The battery of claim 4 , wherein the lithium salt comprises lithium bis(trifluoromethanesulfonyl)imide.
9. The battery of claim 1 , wherein the solvent comprises N-methyl-2-pyrrolidone and about 20 molar percent lithium bis(trifluoromethanesulfonyl)imide.
10. The battery of claim 2 , wherein the lithium salt comprises lithium tetrafluoroborate.
11. The battery of claim 1 , wherein the solvent comprises butylene carbonate and about 20 molar percent lithium tetrafluoroborate.
12. The battery of claim 3 , wherein the lithium salt comprises lithium tetrafluoroborate.
13. The battery of claim 1 , wherein the solvent comprises butyl sulfoxide and about 20 molar percent lithium tetrafluoroborate.