Saponified ethylene-vinyl ester copolymer composition and multilayered structure using said composition
View Patent ↗Provided are: an EVOH resin composition which can exhibit excellent gas-barrier performance after being subjected to a hot water treatment and rarely generates blisters even when being placed under a high-temperature and high-humidity condition; and a multilayered structure including a layer of the resin composition as a gas-barrier layer. A hydrate-formable alkaline earth metal salt having a specific water absorption property, particularly completely or partially dehydrated alkaline earth metal salt of acid, or a mixture thereof. The acid is selected from the group consisting of lactic acid, silicic acid, phosphoric acid, and citric acid. The partially dehydrated alkaline earth metal salt of the salt has a water content of 50 wt % or less.
1. A resin composition comprising (A) a saponified ethylene-vinyl ester copolymer and (B) a hydrate-formable alkaline earth metal salt,
wherein the (B) hydrate-formable alkaline earth metal salt satisfies water absorption properties (I), (II), and (III):
(I) a ratio of X 5 /Y being in the range of 0.2 to 2.0 wherein the X 5 is an amount of water absorption when (B) hydrate-formable alkaline earth metal salt is placed under a condition of 40 ° C. and 90% relative humidity for 5 days, and (Y) is a content of crystallization water in maximum hydrate of the (B) hydrate-formable alkaline earth metal salt;
(II) an amount of water absorption (Z) based on 100 g of (B) hydrate-formable alkaline earth metal salt being 10 g or more when the (B) hydrate-formable alkaline earth metal salt is placed under a condition of 40 ° C. and 90% relative humidity for 24 hours; and
(III) a local maximum point existing in change of amount of water absorption of the (B) hydrate-formable alkaline earth metal salt while placed under a high-temperature and high-humidity condition.
2. The resin composition according to claim 1 , wherein the alkaline earth metal salt (B) is a completely or partially dehydrated alkaline earth metal salt of acid, or a mixture thereof, the acid being selected from the group consisting of lactic acid, silicic acid, phosphoric acid, and citric acid, and the partially dehydrated alkaline earth metal salt having a water content of 50 wt% or less.
3. The resin composition according to claim 1 , wherein a content ratio (A/B) in parts by weight of the (A) saponified ethylene-vinyl ester copolymer to the parts by weight of the (B) hydrate-formable alkaline earth metal salt is in the range between above 50/below 50 and 99/1.
4. The resin composition according to claim 1 , further comprising (C) polyamide resin.
5. The resin composition according to claim 1 , further comprising (D) dispersing agent.
6. A resin composition comprising (A) a saponified ethylene-vinyl ester copolymer and (B) a hydrate-formable alkaline earth metal salt,
wherein (B) hydrate-formable alkaline earth metal salt satisfies water absorption property (I), (II), and (III):
(I) a ratio of X 5 /Y being in the range of 0.2 to 2.0 wherein the X 5 is an amount of water absorption when (B) hydrate-formable alkaline earth metal salt is placed under a condition of 40 ° C. and 90% relative humidity for 5 days, and (Y) is a content of crystallization water in maximum hydrate of the (B) hydrate-formable alkaline earth metal salt;
(II) an amount of water absorption (Z) based on 100 g of (B) hydrate-formable alkaline earth metal salt being 10 g or more when the (B) hydrate-formable alkaline earth metal salt is placed under a condition of 40 ° C. and 90% relative humidity at 40 ° C.; and
(III) a local maximum point existing in change of amount of water absorption of the (B) hydrate-formable alkaline earth metal salt while placed under a high-temperature and high-humidity condition.
7. The resin composition according to claim 6 , wherein the alkaline earth metal salt (B) is a completely or partially dehydrated alkaline earth metal salt of acid, or a mixture thereof, the acid being selected from the group consisting of lactic acid, silicic acid, phosphoric acid, and citric acid, and the partially dehydrated alkaline earth metal salt having a water content of 50 wt% or less.
8. The resin composition according to claim 6 , wherein a content ratio (A/B) in parts by weight of the (A) saponified ethylene-vinyl ester copolymer to the parts by weight of the (B) hydrate-formable alkaline earth metal salt is in the range between above 50/below 50 and 99/1.
9. The resin composition according to claim 6 , further comprising (C) polyamide resin.
10. The resin composition according to claim 6 , further comprising (D) dispersing agent.
11. The resin composition according to claim 4 , wherein a content ratio (A/C) in parts by weight of the (A) saponified ethylene-vinyl ester copolymer to the (C) polyamide resin is in the range between 99/1 and 70/30.
12. The resin composition according to claim 5 , wherein the content of the (D) dispersing agent is from 0.01% by weight to 5% by weight based on the resin composition.