Substrate for solid-state battery
View Patent ↗Disclosed are solid-state batteries having improved energy density and methods of manufacturing the solid-state batteries having improved energy density. In some embodiments, the solid-state battery may include a substrate of yttria-stabilized zirconia, a cathode current collector formed on the substrate, an anode current collector formed on the substrate, a cathode of lithium cobalt oxide in electrical contact with the cathode current collector, an anode of lithium in electrical contact with the anode current collector, and a solid-state electrolyte of lithium phosphorous oxynitride formed between the cathode and the anode.
1. A method for forming a solid-state battery on a substrate comprising a layer of yttria-stabilized zirconia (YSZ), the method comprising:
forming a first cathode current collector in contact with a first side of the layer of YSZ;
forming a first anode current collector in contact with the first side of the layer of YSZ;
forming a first cathode comprising lithium cobalt oxide (LiCoO 2 ) in electrical contact with the first cathode current collector;
forming a first anode comprising lithium in electrical contact with the first anode current collector;
forming a first solid-state electrolyte comprising lithium phosphorous oxynitride (LiPON) between the first cathode and the first anode;
forming a second cathode current collector in contact with a second side of the layer of YSZ that is opposite the first side;
forming a second anode current collector in contact with the second side of the layer of YSZ;
forming a second cathode comprising LiCoO 2 in electrical contact with the second cathode current collector;
forming a second anode comprising lithium in electrical contact with the second anode current collector; and
forming a second solid-state electrolyte comprising LiPON between the second cathode and the second anode.
2. The method of claim 1 , wherein the layer of YSZ has a thickness between about 25 μm and about 40 μm.
3. The method of claim 1 , wherein the first cathode has a thickness between about 10 μm and about 15 μm.
4. The method of claim 1 , wherein the second cathode has a thickness between about 10 μm and about 15 μm.
5. The method of claim 1 , further comprising forming a protective coating substantially covering the first anode.
6. The method of claim 5 , wherein the protective coating comprises silicon dioxide.
7. The method of claim 5 , wherein the protective coating comprises alumina.
8. The method of claim 5 , wherein the protective coating comprises a ceramic.
9. The method of claim 1 , further comprising forming a protective coating substantially covering the second anode.
10. The method of claim 9 , wherein the protective coating comprises silicon dioxide.
11. The method of claim 9 , wherein the protective coating comprises alumina.
12. The method of claim 9 , wherein the protective coating comprises a ceramic.
13. The method of claim 1 , wherein the first anode current collector comprises stainless steel or nickel.
14. The method of claim 1 , wherein the first cathode current collector comprises stainless steel or nickel.
15. The method of claim 1 , wherein the second anode current collector comprises stainless steel or nickel.
16. The method of claim 1 , wherein the second cathode current collector comprises stainless steel or nickel.
17. The method of claim 1 , further comprising annealing the first cathode at a temperature between about 700° C. and about 800° C.
18. The method of claim 1 , further comprising annealing the second cathode at a temperature between about 700° C. and about 800° C.