IP Library Granted Patent US 10,208,182
Granted Patent B2
US 10,208,182 · App. 15/100,176 · Granted Feb 19, 2019

Polypropylene composition suitable for primerless painting

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Quick Facts
Patent No.
US 10,208,182
App. No.
15/100,176
Granted
Feb 19, 2019
Kind
B2
Abstract

The present invention is directed to a polypropylene composition (C), an article comprising the polypropylene composition (C) and the use of the polypropylene composition (C) to reduce paintability failure of a molded article. The polypropylene composition (C) comprises (a) 40.0 to 80.0 wt. %, based on the total weight of the composition, of a propylene copolymer (R-PP) having: (a1) a comonomer content in the range of 1.5 to 8.0 wt. %, and (a2) a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 5.0 to 100.0 g/10 min, and (b) 20.0 to 40.0 wt. %, based on the total weight of the composition, of a mineral filler (F) being selected from the group consisting of talcum, wollastonite, kaolin, and mica, wherein the polypropylene composition (C) has a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 5.0 to 45.0 g/10 min.

Claims (91)

1. Polypropylene composition (C), the polypropylene composition (C) comprising:

(a) 40.0 to 80.0 wt. %, based on the total weight of the composition, of a propylene copolymer (R-PP) wherein the propylene copolymer (R-PP) comprises two fractions, a first propylene copolymer fraction (R-PP1) and a second propylene copolymer fraction (R-PP2), said first propylene copolymer fraction (R-PP1) differs from said second propylene copolymer fraction (R-PP2) in the comonomer content; wherein the propylene copolymer (R-PP) having

(a1) a comonomer content in the range of 1.5 to 8.0 wt. %, and

(a2) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 5.0 to 100.0 g/10 min, and

wherein the propylene copolymer (R-PP) has:

(a3) a glass transition temperature in the range of −12 to +2° C.; and/or

(a4) no glass transition temperature below −20° C.; and

(b) 20.0 to 40.0 wt. %, based on the total weight of the composition, of a mineral filler (F) being selected from the group consisting of talcum, wollastonite, kaolin, and mica,

wherein the polypropylene composition (C) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 5.0 to 45.0 g/10 min.

2. The polypropylene composition (C) according to claim 1 , wherein the propylene copolymer (R-PP) has:

(a) a melting temperature in the range of 135 to 165° C., and/or

(b) a tensile modulus of at least 800 MPa, and/or

(c) a Charpy notched impact strength at +23° C. of ≥4 kJ/m 2 .

3. The polypropylene composition (C) according to claim 1 , wherein the propylene copolymer (R-PP):

is monophasic.

4. The polypropylene composition (C) according to claim 1 , wherein the propylene copolymer (R-PP) comprises a comonomer selected from ethylene, C 4 to C 12 α-olefin, and mixtures thereof.

5. The polypropylene composition (C) according to claim 1 , wherein:

(a) the weight ratio between the first propylene copolymer fraction (R-PP1) and the second propylene copolymer fraction (R-PP2) of the propylene copolymer (R-PP) [(R-PP1):(R-PP2)] is 70:30 to 30:70; and/or

(b) the comonomers for the first propylene copolymer fraction (R-PP1) and the second propylene copolymer fraction (R-PP2) of the propylene copolymer (R-PP) are selected from ethylene, C 4 to C 12 α-olefin, and mixtures thereof.

6. The polypropylene composition (C) according to claim 1 , wherein

(a) the first propylene copolymer fraction (R-PP1) of the propylene copolymer (R-PP) is the comonomer lean fraction and the second propylene copolymer fraction (R-PP2) of the propylene copolymer (R-PP) is the comonomer rich fraction, and/or

(b) the first propylene copolymer fraction (R-PP1) of the propylene copolymer (R-PP) has a lower comonomer content than the propylene copolymer (R-PP).

7. The polypropylene composition (C) according to claim 1 , wherein:

(a) the first propylene copolymer fraction (R-PP1) and the second propylene copolymer fraction (R-PP2) of the propylene copolymer (R-PP) fulfill together the in-equation (I)

Co

(

R

-

PP

2

)

Co

(

R

-

PP

1

)

1.0

;

(

I

)

wherein;

Co(R-PP1) is the comonomer content [wt. %] of the first propylene copolymer fraction (R-PP1),

Co(R-PP2) is the comonomer content [wt. %] of the second propylene copolymer fraction (R-PP2), and/or,

(b) the first propylene copolymer fraction (R-PP1) and the propylene copolymer fraction (R-PP) fulfill together the in-equation (II):

Co

(

R

-

PP

)

Co

(

R

-

PP

1

)

1.0

(

II

)

wherein;

Co(R-PP1) is the comonomer content [wt. %] of the first propylene copolymer fraction (R-PP1),

Co(R-PP) is the comonomer content [wt. %] of the propylene copolymer (R-PP).

8. The polypropylene composition (C) according to claim 1 , wherein the mineral filler (F) is talcum.

9. The polypropylene composition (C) according to claim 1 , wherein the polypropylene composition (C) comprises 2.0 to 15.0 wt. %, based on the total weight of the composition, of an elastomeric copolymer (E) comprising units derived from ethylene and C 4 to C 8 α-olefins.

10. The polypropylene composition (C) according to claim 9 , wherein the elastomeric copolymer (E) has:

(a) a density of equal or less than 935 kg/m 3 , and/or

(b) a melt flow rate MFR 2 (190° C.) measured according to ISO 1133 in the range of 0.25 to 30.0 g/10 min.

11. Article comprising a polypropylene composition (C) according to claim 1 .

12. The article according to claim 11 , wherein the article is an automotive article selected from the group consisting of bumpers, body panels, rocker panels, side trims, step assists, spoilers and dash boards.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2016
From: GLOGER, DIETRICH; KNIESEL, CLAUDIA; GRESTENBERGER, GEORG; MILEVA, DANIELA
To: BOREALIS AG
Reel/Frame 039031/0579 →