Epoxy-terminated polybutadiene as oxygen scavenger
The present invention relates to the use of epoxy-terminated polydiene having terminal epoxy groups as oxygen scavenger, in particular as constituent in packaging.
1. A composite material for packaging applications, the composite material comprising an oxygen scavenger comprising a polydiene comprising terminal epoxy groups wherein the epoxy-terminated polydiene is polybutadiene having epoxy groups, wherein the polybutadiene comprises the 1,3-butadiene-derived monomer units
wherein the proportion of A in the entirety of the 1,3-butadiene-derived monomer units present in the polybutadiene is from 15 to 30 mol percent,
wherein the proportion of B in the entirety of the 1,3-butadiene derived monomer units present in the polybutadiene is from 50 to 70 mol percent and the proportion of C in the entirety of the 1,3-butadiene-derived monomer units present in the polybutadiene is from 15 to 30 mol percent, and
wherein the epoxy groups comprise the formula (I)
wherein X is a linear alkylene group of the formula —(CH 2 ) x —, where x is from 1 to 4,
and wherein the polybutadiene comprises an average of 1.5 to 3 epoxy groups, and wherein the composite material comprises of at least two layers including a nylon-6-based single layer film comprising the oxygen scavenger has an oxygen absorption of from 5.0 to 13.0 mg of oxygen/g of the nylon-6-based single layer film.
2. A coating comprising the composite material according to claim 1 .
3. The composite material according to claim 1 , wherein the at least two layers differ from one another.
4. The composite material according to claim 1 , wherein the composite material takes the form of flexible film layers, flexible pouches, self-supporting containers or combinations thereof.
5. The composite material according to claim 1 , wherein the composite material comprises layers, and wherein the polydienes comprising terminal epoxy groups are used in one, some or all of the layers of the composite material.
6. The composite material according to claim 1 , wherein the polydiene comprising epoxy groups is introduced into a layer which is composed of a main polymer that is oxygen-impermeable.
7. The composite material according to claim 6 , wherein the main polymer is selected from the group consisting of polyethylenes, polyester, polyvinyl chloride (PVC); polyvinylidene chloride (PVDC); polycaprolactone polymers and ethylene copolymers, poly(vinyl alcohol) (PVOH), ionomers, polyamides and amide copolymers.
8. The composite material according to claim 1 , wherein the polydiene comprising terminal epoxy groups is present in combination with other means of oxygen scavenging.
9. The composite material according to claim 8 , wherein the other means of oxygen scavenging and the polydiene comprising terminal epoxy groups are present in one layer.
10. The composite material according to claim 8 , wherein the other means of oxygen scavenging are constituents of a layer differing from the layer comprising the polydiene comprising terminal epoxy groups.
11. The composite material according to claim 1 , wherein the polybutadiene comprises an average of 1.75 to 2.5 epoxy groups.
12. The composite material according to claim 1 , wherein the X is a linear alkylene group of the formula —(CH 2 ) x —, where x is 1.
13. A composite-material packaging at least comprising a polydiene comprising terminal epoxy groups wherein the epoxy-terminated polydiene is polybutadiene having epoxy groups, wherein the polybutadiene comprises the 1,3-butadiene-derived monomer units
wherein the proportion of A in the entirety of the 1,3-butadiene derived monomer units present in the polybutadiene is from 15 to 30 mol percent, and wherein the proportion of B in the entirety of the 1,3-butadiene derived monomer units present in the polybutadiene is from 50 to 70 mol percent and the proportion of C in the entirety of the 1,3-butadiene-derived monomer units present in the polybutadiene is from 15 to 30 mol percent, and
wherein the epoxy groups have the formula (I)
wherein X is a linear alkylene group of the formula —(CH 2 ) x —, where x is from 1 to 4,
and wherein the polybutadiene comprises an average of 1.5 to 3 epoxy groups, and a nylon-6-based single layer film comprising the oxygen scavenger has an oxygen absorption of from 5.0 to 13.0 mg of oxygen/g of the nylon-6-based single layer film.
14. The composite-material packaging according to claim 13 , wherein the X is a linear alkylene group of the formula —(CH 2 ) x —, where x is from 1 to 4.
15. The composite-material packaging according to claim 13 , wherein the X is a linear alkylene group of the formula —(CH 2 ) x —, where x is 1.