Drilling fluid adjusting agent and drilling fluid using the same
View Patent ↗A drilling fluid adjusting agent using a PVA-based resin capable of contributing to the reduction of hydration swelling of bentonite even in the presence of salts; and a drilling fluid using the same are provided. The drilling fluid adjusting agent contains a PVA containing 1,2-diol structural unit in a side chain thereof. The drilling fluid adjusting agent has excellent solubility even in the presence of salts such as potassium ion, and also has excellent reduction of hydration swelling of bentonite.
1. A drilling fluid adjusting agent comprising
(A) polyvinyl alcohol-based resin containing 1,2-diol structural unit represented by the general formulas (1), (5) and (6),
wherein, R 1 through R 3 each is independently hydrogen atom or an alkyl group having from 1 to 5 carbon atoms, X is single bond or a binding chain, and R 4 through R 6 each is independently hydrogen atom or an alkyl group having from 1 to 5 carbon atoms, R 20 is an alkyl group having from 1 to 20 carbon atoms.
2. The drilling fluid adjusting agent according to claim 1 , wherein the polyvinyl alcohol-based resin (A) has an average polymerization degree of 500 to 4000.
3. The drilling fluid adjusting agent according to claim 1 , wherein the content of the 1,2-diol structural unit with the formula (1) is from 0.1 to 20 mol %.
4. The drilling fluid adjusting agent according to claim 1 , further comprising a salt.
5. A drilling fluid comprising a liquid medium, bentonite, and a drilling fluid adjusting agent according to claim 1 .
6. The drilling fluid according to claim 5 , wherein the liquid medium is a water-based medium.
7. The drilling fluid according to claim 5 , wherein the content of the drilling fluid adjusting agent is from 0.01 to 5%.
8. The drilling fluid adjusting agent according to claim 1 , wherein the polyvinyl alcohol-based resin (A) has a saponification degree of 80 to 99.8 mol %.
9. The drilling fluid adjusting agent according to claim 8 , wherein the polyvinyl alcohol-based resin (A) has a saponification degree of 88 to 99.8 mol %.