Ultrahigh-strength steel for welding structure with excellent toughness in welding heat-affected zones thereof, and method for manufacturing same
Provided is a ultrahigh strength steel for a welded structure having superior toughness in a weld heat-affected zone (HAZ) comprising: by wt %, carbon (C): 0.05% to 0.15%, silicon (Si): 0.1% to 0.6%, manganese (Mn): 1.5% to 3.0%, nickel (Ni): 0.1% to 0.5%, molybdenum (Mo): 0.1% to 0.5%, chromium (Cr): 0.1% to 1.0%, copper (Cu): 0.1% to 0.4%, titanium (Ti): 0.005% to 0.1%, niobium (Nb): 0.01% to 0.03%, boron (B): 0.0003% to 0.004%, aluminum (Al): 0.005% to 0.1%, nitrogen (N): 0.001% to 0.006%, phosphorus (P): 0.015% or less, sulfur (S): 0.015% or less, iron (Fe) as a residual component thereof, and inevitable impurities.
1. A steel sheet for a welded structure having superior toughness in a weld heat-affected zone (HAZ), the steel sheet comprising:
by wt %, carbon (C): 0.05% to 0.15%, silicon (Si): 0.1% to 0.6%, manganese (Mn): 1.5% to 3.0%, nickel (Ni): 0.1% to 0.5%, molybdenum (Mo): 0.1% to 0.5%, chromium (Cr): 0.1% to 1.0%, copper (Cu): 0.1% to 0.4%, titanium (Ti): 0.005% to 0.1%, niobium (Nb): 0.01% to 0.03%, boron (B): 0.0003% to 0.004%, aluminum (Al): 0.005% to 0.1%, nitrogen (N): 0.001% to 0.006%, phosphorus (P): 0.015% or less, sulfur (S): 0.015% or less, iron (Fe) as a residual component thereof, and inevitable impurities,
wherein the Ti and N component contents satisfy Formula 1 below, the N and B component contents satisfy Formula 2 below, and the Mn, Cr, Mo, Ni, and Nb component contents satisfy Formula 3 below; and
wherein the steel sheet comprises: a microstructure including, by area fraction, acicular ferrite in an amount of 30% to 40% and bainite in an amount of 60% to 70%, and the microstructure comprises: TiN precipitates having a size of 0.01 μm to 0.05 μm and a density of 1.0×10 3 /mm 2 or more, and being dispersed at an interval of 50 μm or less,
3.5≤Ti/N≤7.0 [Formula 1]
1.5≤N/B≤4.0 [Formula 2]
4.0≤2Mn+Cr+Mo+Ni+3Nb≤7.0 [Formula 3]
wherein in the Formulas 1 to 3, respective component units are wt %.
2. The steel sheet of claim 1 , wherein the steel sheet further comprises, by wt %, one or more elements among vanadium (V): 0.005% to 0.2%, calcium (Ca): 0.0005% to 0.005%, and rare earth elements (REM): 0.005% to 0.05%.
3. The steel sheet of claim 1 , further comprising: a weld HAZ formed in the steel sheet, wherein the weld HAZ comprises: a microstructure including, by area fraction, acicular ferrite in an amount of 30% to 40% and bainite in an amount of 60% to 70%, and an austenite crystal grain having a size of less than 200 μm.
4. A method of manufacturing a steel sheet for a welded structure having a weld heat-affected zone (HAZ), the method comprising:
preparing a slab comprising, by wt %, carbon (C): 0.05% to 0.15%, silicon (Si): 0.1% to 0.6%, manganese (Mn): 1.5% to 3.0%, nickel (Ni): 0.1% to 0.5%, molybdenum (Mo): 0.1% to 0.5%, chromium (Cr): 0.1% to 1.0%, copper (Cu): 0.1% to 0.4%, titanium (Ti): 0.005% to 0.1%, niobium (Nb): 0.01% to 0.03%, boron (B): 0.0003% to 0.004%, aluminum (Al): 0.005% to 0.1%, nitrogen (N): 0.001% to 0.006%, phosphorus (P): 0.015% or less, sulfur (S): 0.015% or less, iron (Fe) as a residual component thereof, and inevitable impurities, wherein the Ti and N component contents satisfy Formula 1 below, the N and B component contents satisfy Formula 2 below, and the Mn, Cr, Mo, Ni, and Nb component contents satisfy Formula 3 below;
heating the slab to a temperature of 1100° C. to 1200° C.;
hot finish rolling the heated slab at a temperature of 870° C. to 900° C. to form a hot finish rolled steel sheet; and
cooling the hot finish rolled steel sheet to a temperature of 420° C. to 450° C. at a cooling speed of 4° C./s to 10° C./s to form a hot rolled steel sheet, wherein the hot-rolled steel sheet has a microstructure including, by area fraction, acicular ferrite in an amount of 30% to 40% and bainite in an amount of 60% to 70%, and the microstructure further comprises TiN precipitates having a size of 0.01 μm to 0.05 μm and a density of 1.0×10 3 /mm 2 or more, and being dispersed at an interval of 50 μm or less,
3.5≤Ti/N≤7.0 [Formula 1]
1.5≤N/B≤4.0 [Formula 2]
4.0≤2Mn+Cr+Mo+Ni+3Nb≤7.0 [Formula 3].
5. The method of claim 4 , wherein the slab further comprises, by wt %, one or more elements among V vanadium (V): 0.005% to 0.2%, calcium (Ca): 0.0005% to 0.005%, and rare earth elements (REM): 0.005% to 0.05%.
6. The method of claim 4 , further comprising; forming a weld HAZ by welding the hot-rolled steel sheet, wherein the weld HAZ has a microstructure including, by area fraction, acicular ferrite in an amount of 30% to 40% and bainite in an amount of 60% to 70%, as a microstructure, and an austenite crystal grain having a size of less than 200 μm.