Low MFR polymer composition, power cable insulation and power cable
The present invention relates to a polymer composition comprising a polyolefin, peroxide and a sulphur containing antioxidant, wherein said peroxide is present in an amount which corresponds to X mmol —O—O—/kg polymer composition and said sulphur containing antioxidant is present in an amount which corresponds to Y mmol —OH/kg polymer composition, wherein Y 1 ≤Y≤Y 2 , X≤45 and 0.9*Y+m≤X≤n−k*Y, wherein Y 1 is 0.50 and Y 2 is 10, and m is 0.8, n is 70 and k is 4.7; and wherein said polymer composition has a melt flow rate (MFR) of less than 1.7, and said polymer composition comprises less than 0.05% by weight (wt %) 2,4-Diphenyl-4-methyl-1-pentene; a crosslinked polymer composition, and use thereof, a power cable insulation, a power cable, useful in high voltage (HV DC) and extra high voltage (EHV DC) direct current applications, and a method for reducing electrical conductivity of a crosslinked polymer composition.
1. A crosslinkable polymer composition comprising:
a polyolefin, a peroxide, and a phenolic sulfur containing antioxidant;
wherein said peroxide is present in an amount which corresponds to X mmol —O—O—/kg polymer composition;
wherein said phenolic sulfur containing antioxidant is present in an amount which corresponds to Y mmol —OH/kg polymer composition;
wherein 2.0≤Y≤8.0, X<35, and 0.9*Y+3.0≤X≤65−4.7*Y;
wherein said polyolefin is:
a low density polyethylene (LDPE) homopolymer having a total amount of carbon-carbon double bonds, which originate from vinyl groups, vinylidene groups, trans-vinylene groups, or a combination thereof, of more than 0.3/1000 carbon atoms; or
an unsaturated LDPE copolymer of ethylene and with at least one polyunsaturated comonomer, the unsaturated LDPE copolymer having a total amount of carbon-carbon double bonds, which originate from vinyl groups, vinylidene groups, trans-vinylene groups, or a combination thereof, of more than more than 0.3/1000 carbon atoms;
wherein said polyolefin has a melt flow rate, MFR 2 , determined according to ISO1133, of less than 1.7 g/10 min;
wherein said crosslinkable polymer composition comprises 0% by weight (wt %) 2,4-diphenyl-4-methyl-1-pentene; and
when crosslinked to form a crosslinked polymer composition, the crosslinked polymer composition has:
an electrical conductivity of from 1 to 35 fS/m, when measured according to DC conductivity method as described under “Determination Methods”, and an Oxidation Induction Time of from 1 to 14 minutes as determined according to ASTM-D3895, ISO/CD 11357 and EN 728 using a Differential Scanning Calorimeter (DSC).
2. The crosslinkable polymer composition according to claim 1 , wherein 2.0≤Y≤6.5.
3. The crosslinkable polymer composition according to claim 1 , wherein the polyolefin is a low density polyethylene (LDPE) homopolymer having a total amount of carbon-carbon double bonds, which originate from vinyl groups, vinylidene groups, trans-vinylene groups, or a combination thereof, of more than more than 0.3/1000 carbon atoms.
4. The crosslinkable polymer composition according to claim 1 , wherein the polyolefin is an unsaturated LDPE copolymer of ethylene with at least one polyunsaturated comonomer and optionally with one or more other comonomer(s), wherein the polyunsaturated comonomer comprises a straight carbon chain with at least 8 carbon atoms and at least 4 carbons between the non-conjugated double bonds, of which at least one is terminal.
5. A crosslinked polymer composition obtained by crosslinking the crosslinkable polymer composition of claim 1 .
6. A crosslinked polymer composition formed by exposing the crosslinkable polymer composition of claim 1 to a curing procedure, wherein said crosslinkable polymer composition is crosslinked during said curing procedure.
7. The crosslinked polymer composition according to claim 6 , wherein during said curing procedure the maximum temperature of said crosslinkable polymer composition is above 150° C.
8. A power cable insulation comprising the crosslinked polymer composition according to claim 5 .
9. The power cable insulation according to claim 8 , wherein the power cable insulation is an HV DC power cable insulation or an EHV DC power cable insulation.
10. A power cable comprising the power cable insulation of claim 8 .
11. The power cable according to claim 10 , wherein the power cable is an HV DC power cable or an EHV DC power cable.
12. A method for providing a crosslinked polymer composition with low electrical conductivity, the method comprising crosslinking the crosslinkable polymer composition of claim 1 .
13. A method of making a power cable insulation, the method comprising the steps of:
providing at least a polymer-based electrical insulator comprising at least one crosslinkable polymer composition according to claim 1 , wherein the polymer-based electrical insulator surrounds an electrical conductor of a power cable; and
exposing the polymer-based electrical insulator to a curing procedure, wherein the crosslinkable polymer composition is crosslinked during the curing procedure, and wherein during the curing procedure the maximum temperature of the polymer-based electrical insulator is above 150° C.
14. A crosslinked power cable comprising a conductor surrounded by at least an inner semiconductive layer, an insulation layer and an outer semiconductive layer, in that order, wherein at least the insulation layer comprises the crosslinked polymer composition of claim 5 , and optionally surrounded by one or more further layer(s) selected from a group comprising screen(s), a jacketing layer(s) or other protective layer(s).
15. The crosslinkable polymer composition according to claim 1 , wherein the polyolefin is an unsaturated LDPE copolymer of ethylene with at least one polyunsaturated comonomer and optionally with one or more other comonomer(s), wherein the polyunsaturated comonomer is a diene selected from 1,7-octadiene, 1,9-decadiene, 1,11-dodecadiene, 1,13-tetradecadiene, 7-methyl-1,6-octadiene, 9-methyl-1,8-decadiene, or mixtures thereof.