IP Library Granted Patent US 10,174,254
Granted Patent B2
US 10,174,254 · App. 15/105,807 · Granted Jan 8, 2019

Nematic liquid crystal composition and liquid crystal display element using the same

Inventors: Go Sudo (Kita-adachi-gun, JP); Yasuo Umezu (Kita-adachi-gun, JP)
Assignee: DIC CORPORATION
C09K19/54C09K19/20C09K19/3066C09K19/322G02F1/1368G02F1/13439C09K2019/0448C09K2019/0466C09K2019/122C09K2019/301C09K2019/3004C09K2019/3016C09K2019/3019C09K2019/3078G02F2201/123
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Quick Facts
Patent No.
US 10,174,254
App. No.
15/105,807
Granted
Jan 8, 2019
Kind
B2
Abstract

The present invention relates to a liquid crystal composition, which is a liquid crystal composition containing a compound represented by General Formula (II-1) as an anti-oxidizing agent for a liquid crystal composition containing the compound represented by General Formula (II-1) and also as a first component, and a compound represented by General Formula (K) as a second component. The compound represented by General Formula (II-1) enables obtainment of a working effect of the anti-oxidizing agent, and therefore it allows provision of a liquid crystal composition containing the anti-oxidizing agent which has improved reliability like low temperature stability, while the high dielectric anisotropy is maintained.

Claims (16)

1. A liquid crystal composition which comprises:

a compound represented by General Formula (II):

in General Formula (II), M represents an alkylene group having carbon atom number of 4 to 10; and,

a compound represented by General Formula (K):

in General Formula (K), R k1 's each independently represent an alkyl group having carbon atom number of 1 to 10 or an alkenyl group having carbon atom number of 2 to 10, in which one or two or more non-adjacent —CH 2 — in the group may be each independently substituted with —C≡C—, —O—, —CO—, —COO—, or —OCO—, and one or two or more non-adjacent hydrogen atoms in the group may be each independently substituted with a fluorine atom,

ring K 1 and ring K 2 each independently represent a 1,4-cyclohexylene group in which one or two or more non-adjacent —CH 2 — in the group may be substituted with —O— or —S— or a 1,4-phenylene group in which one or two or more non-adjacent —CH═ in the group may be substituted with —N═, and the hydrogen atoms in the group may be each independently substituted with a cyano group, a fluorine atom, or a chlorine atom,

ring K 0 represents a naphthalene-2,6-diyl group or a 1,4-phenylene group in which the hydrogen atoms in the group may be each independently substituted with a fluorine atom,

Z k1 represents —OCH 2 — or —OCF 2 —,

Z k2 , or Z k3 each independently represents a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CF 2 O—, —CH 2 CH 2 CF 2 O—, —COO—, —OCO—, or —C≡C—,

n k1 's each independently represent 0, 1, 2, 3, or 4, with the proviso that, when n k1 is 2 or more, the rings K 2 may be the same as or different from each other, and

X k1 , X k2 , X k3 , and X k4 each independently represent a hydrogen atom or a fluorine atom, and Y k1 's each independently represent a fluorine atom, a cyano group, a trifluoromethyl group, a fluoromethoxy group, a difluoromethoxy group, a trifluoromethoxy group, or a 2,2,2-trifluoroethyl group,

wherein the liquid crystal composition has no drop mark in a drop mark evaluation of a liquid crystal display element prepared by the liquid crystal composition by visually evaluating a drop mark appearing white on a black screen of the liquid crystal display element.

2. The liquid crystal composition according to claim 1 , wherein the compound represented by General Formula (II) is a compound represented by General Formula (II-a):

3. The liquid crystal composition according to claim 1 , further comprising a polymerizable compound.

4. A liquid crystal display element comprising a first substrate which is provided with a common electrode formed of a transparent conductive material, a second substrate which is provided with a pixel electrode formed of a transparent conductive material and a thin film transistor for controlling a pixel electrode disposed on each pixel, and a liquid crystal composition sandwiched between the first substrate and the second substrate, in which the alignment of liquid crystal molecules in the liquid crystal composition without voltage application is approximately parallel or approximately vertical to the substrate and the liquid crystal composition described in claim 1 is used as the liquid crystal composition of the element.

5. A liquid crystal display element, wherein the liquid crystal display element is produced by polymerization of a polymerizable compound contained in the liquid crystal composition of claim 1 with voltage application or without voltage application.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2024
From: DIC CORPORATION
To: SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.
Reel/Frame 067528/0688 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 12, 2018
From: SUDO, GO; UMEZU, YASUO
To: DIC CORPORATION
Reel/Frame 047151/0743 →
Priority Claims (1)
JP 2013-267009 · Dec 25, 2013 · national
Continuity (1)
Related Publication 20160319195A1 · Nov 3, 2016