IP Library Granted Patent US 10,294,361
Granted Patent B2
US 10,294,361 · App. 15/106,079 · Granted May 21, 2019

Thermally stable polyoxymethylene compositions

Inventor: Makoto Kato (Utsunomiya, JP)
Assignee: E. I. DU PONT DE NEMOURS AND COMPANY
C08L59/02C08K5/005C08K5/13C08L33/26C08L77/06C08L2201/08C08L2205/03
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Quick Facts
Patent No.
US 10,294,361
App. No.
15/106,079
Granted
May 21, 2019
Kind
B2
Abstract

Polyoxymethylene compositions either consisting essentially of: polyoxymethylene polymer; at least pme amine polymer selected from the group consisting of polyacrylamides, polyallylamines, polyacrylic hydrazide, polymethacrylic hydrazide, polyaminoalkyl acrylate, polyaminoalkyl methacrylate, poly vinylalkylamine, and mixtures of these; and at least pme polyimide having a melting point that ranges between 20° C. below the melting point of (a) to 20° C. above the melting point of the polyoxymethylene polymer.

Claims (12)

1. A polyoxymethylene composition consisting essentially of:

(a) 95.85 to 99.94 weight percent polyoxymethylene polymer,

(b) 0.4 to 0.6 weight percent of an amine polymer selected from the group consisting of polyacrylamides, polyallylamines, polyacrylic hydrazide, polymethacrylic hydrazide, polyaminoalkyl acrylate, polyaminoalkyl methacrylate, poly vinylalkylamine, and mixtures of these;

(c) 0.008 to 0.08 weight percent of a polyamide having a melting point of about 140° C. to about 240° C. and wherein said melting point ranges between 40° C. below the melting point of (a) to 40° C. above the melting point of (a), and

(d) 0.01 to 4.0 weight percent of an antioxidant, wherein the polyoxymethylene composition, when molded, exhibits:

a tensile creep to 10% strain at 90° C. and 25 MPa pressure of at least 0.32 minutes, as determined according to ASTM D2990;

a time to mold deposit of at least 12 hours; and

a thermally evolved formaldehyde of less than 0.50 percent, as measured at 250° C. for a period of 0.5 hours.

2. The polyoxymethylene composition of claim 1 , wherein (c) is an aliphatic polyamide.

3. The polyoxymethylene composition of claim 2 , wherein the aliphatic polyamide (c) is polyamide 66/610/6 terpolymer.

4. The polyoxymethylene composition of claim 1 , wherein (b) is selected from the group consisting of polyacrylamides, polyallylamines, polyvinylalkylamines, and mixtures of these.

5. The polyoxymethylene composition of claim 1 , wherein the antioxidant is a hindered phenolic antioxidant.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 29, 2025
From: DUPONT POLYMERS, INC.
To: DELRIN USA, LLC
Reel/Frame 073323/0244 →
SECURITY INTEREST Recorded Nov 2, 2023
From: DELRIN USA, LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 065441/0937 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT POLYMERS, INC.
Reel/Frame 049590/0650 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 3, 2016
From: KATO, MAKOTO
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 039332/0572 →
Continuity (2)
Provisional Application 61918286 · Dec 19, 2013
Related Publication 20160319123A1 · Nov 3, 2016