Polyethylene composition with high flexibility and high temperature resistance suitable for pipe applications
View Patent ↗The present invention relates to a polyethylene composition comprising, preferably consisting of, a base resin comprising a copolymer of ethylene and at least two comonomers selected from alpha-olefins having from three to twelve carbon atoms, wherein the ethylene copolymer comprises a low molecular weight component (A) and a high molecular weight component (B) with the low molecular weight component (A) having a lower weight average molecular weight than the high molecular weight component (B), and optional additives, suitable for the production of an article, preferably pipe.
1. A polyethylene composition comprising
a base resin being a copolymer of ethylene and at least two different comonomers selected from alpha-olefins having from three to twelve carbon atoms,
wherein the ethylene copolymer comprises component (A) and component (B) wherein component (A) has a lower weight average molecular weight than component (B), and optional additives,
wherein the base resin has a density of more than 940.0 kg/m 3 to equal to or less than 948.0 kg/m 3 , determined according to ISO 1183, and
the composition has a melt flow rate MFR 5 (190° C., 5 kg) of equal to or more than 0.3 g/10 min to equal to or less than 1.3 g/10 min, determined according to ISO 1133, and
a Charpy Notched Impact Strength at —20° C. of equal to or more than 6.5 kJ/m 2 , determined according to ISO 179eA.
2. The polyethylene composition according to claim 1 , wherein component (A) is a copolymer of ethylene and a comonomer selected from alpha-olefins having from three to twelve carbon atoms.
3. The polyethylene composition according to claim 2 , wherein component (B) is a copolymer of ethylene and a comonomer selected from alpha-olefins having from three to twelve carbon atoms, which is different from the comonomer of component (A).
4. The polyethylene composition according to claim 1 , wherein component (A) has a melt flow rate MFR 2 (190° C., 2.16 kg) of 200 to 400 g/10 min, determined according to ISO 1133.
5. The polyethylene composition according to claim 1 , wherein component (A) has a density of equal to or more than 955 kg/m 3 , determined according to ISO 1183.
6. The polyethylene composition according to claim 1 , wherein the composition has a weight average molecular weight Mw of 100,000 g/mol to 250,000 g/mol, determined by GPC.
7. The polyethylene composition according to claim 1 , wherein the composition has a molecular weight distribution, being the ratio of weight average molecular weight to number average molecular weight Mw/Mn of 10 to 20, determined by GPC.
8. The polyethylene composition according to claim 1 , wherein the composition has a shear thinning index SHI 2.7/210 of 15-35.
9. The polyethylene composition according to claim 1 , wherein the composition has a melt flow rate MFR 21 (190° C., 21.6 kg) of 6.0 g/10 min to 25 g/10 min, determined according to ISO 1133.
10. The polyethylene composition according to claim 1 , wherein the composition has a density of 942 to 948 kg/m 3 , determined according to ISO 1183.
11. The polyethylene composition according to claim 1 , wherein the composition has a flexural modulus of equal to or less than 1000 MPa, determined according to ISO 178.
12. A process for making the polyethylene composition according to claim 1 , the process comprising
a) polymerizing ethylene and an alpha-olefin comonomer having from 3 to 12 carbon atoms in the presence of a Ziegler-Natta catalyst for obtaining an intermediate material,
b) transferring the intermediate material to a gas phase reactor
(i) feeding ethylene and an alpha-olefin comonomer having from 3 to 12 carbon atoms different from the alpha-olefin comonomer of step a) to the gas phase reactor
(ii) further polymerizing the intermediate material with the ethylene and alpha-olefin comonomer of step b)(i),
to obtain a base resin which comprises the intermediate material polymerized in step a) and a material polymerized in step b) which has a higher weight average molecular weight as the intermediate material of step a), wherein the base resin has a density of more than 940.0 kg/m 3 to equal to or less than 948.0 kg/m 3 , determined according to ISO 1183,
extruding the base resin, in the presence of optional additives, into a polyethylene composition having a melt flow rate MFR 5 (5 kg, 190° C.) of equal to or more than 0.3 g/10 min to equal to or less than 1.3 g/10 min, determined according to ISO 1133 , and a Charpy Notched Impact Strength at −20° C. of equal to or more than 6.5 kJ/m 2 , determined according to ISO 179eA.
13. An article comprising the polyethylene composition according to claim 1 .
14. The article of claim 13 , wherein the article is a pipe or pipe fitting.