Non-aqueous liquid electrolyte and lithium secondary battery comprising the same
The present invention provides a lithium secondary battery comprising a non-aqueous liquid electrolyte comprising lithium bis(fluorosulfonyl)imide (LiFSI) and a fluorinated benzene-based compound as additives, a positive electrode comprising a lithium-nickel-manganese-cobalt-based oxide as a positive electrode active material, a negative electrode, and a separator. With the non-aqueous liquid electrolyte for a lithium secondary battery of the present invention, a solid SEI film is formed on a negative electrode when initially charging a lithium secondary battery comprising the non-aqueous liquid electrolyte, and an output property of the lithium secondary battery is improved, and an output property and stability after high temperature storage are capable of being enhanced as well.
1. A lithium secondary battery comprising:
a non-aqueous liquid electrolyte comprising a lithium salt, and lithium bis(fluorosulfonyl)imide (LiFSI) and a fluorinated benzene-based compound as additives, wherein a molar ratio of the lithium salt and the LiFSI ranges from 1:0.01 to 1:1;
a positive electrode comprising a positive electrode active material, wherein the positive electrode active material consists of a lithium-nickel-manganese-cobalt-based oxide;
a negative electrode; and
a separator, wherein the lithium-nickel-manganese-cobalt-based oxide is represented by the following Chemical Formula 1:
Li 1+x (Ni a Co b Mn c )O 2 [Chemical Formula 1]
wherein, 0.55≤a≤0.65, 0.18≤b≤0.22, 0.18≤c≤0.22, −0.2≤x≤0.2, and x+a+b+c=1.
2. The lithium secondary battery of claim 1 , wherein the lithium bis(fluorosulfonyl)imide has a concentration of 0.01 mol/L to 2 mol/L in the non-aqueous liquid electrolyte.
3. The lithium secondary battery of claim 1 , wherein the lithium salt comprises any one or a mixture of at least two selected from the group consisting of LiPF 6 , LiAsF 6 , LiCF 3 SO 3 , LiN(CF 3 SO 2 ) 2 , LiBF 4 , LiSbF 6 , LiN(C 2 F 5 SO 2 ) 2 , LiAlO 4 , LiAlCl 4 , LiSO 3 CF 3 and LiClO 4 .
4. The lithium secondary battery of claim 1 , wherein the fluorinated benzene-based compound is one or more selected from the group consisting of compounds represented by Chemical Formula 2:
wherein, n is an integer of 1 to 3.
5. The lithium secondary battery of claim 1 , wherein the fluorinated benzene-based compound is one or more selected from the group consisting of fluorobenzene, difluorobenzene, trifluorobenzene and derivatives thereof.
6. The lithium secondary battery of claim 1 , wherein content of the fluorinated benzene-based compound is from 1% by weight to 20% by weight based on a total weight of the non-aqueous liquid electrolyte.
7. The lithium secondary battery of claim 1 , wherein the non-aqueous liquid electrolyte comprises a non-aqueous organic solvent, and the non-aqueous organic solvent comprises a nitrile-based solvent, linear carbonate, cyclic carbonate, ester, ether, ketone or combinations thereof.
8. The lithium secondary battery of claim 7 , wherein the cyclic carbonate is any one selected or a mixture of at least two from the group consisting of ethylene carbonate (EC), propylenecarbonate (PC) and butylene carbonate (BC), and the linear carbonate is any one or a mixture of at least two selected from the group consisting of dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate (DPC), ethylmethyl carbonate (EMC), methylpropyl carbonate (MPC) and ethylpropyl carbonate (EPC).
9. The lithium secondary battery of claim 7 , wherein the nitrile-based solvent is one or more selected from the group consisting of acetonitrile, propionitrile, butyronitrile, valeronitrile, caprylonitrile, heptanenitrile, cyclopentane carbonitrile, cyclohexane carbonitrile, 2-fluorobenzonitrile, 4-fluorobenzonitrile, difluorobenzonitrile, trifluorobenzonitrile, phenylacetonitrile, 2-fluorophenylacetonitrile and 4-fluorophenylacetonitrile.
10. The lithium secondary battery of claim 1 , which is a pouch-type lithium secondary battery.