Negative electrode active material and method of manufacturing the same

1. A negative electrode active material comprising:

low crystalline artificial graphite; and

an amorphous carbon coating layer formed on the low crystalline artificial graphite, wherein a coating amount of the amorphous carbon coating layer is in a range of 0.1% by weight to 4% by weight, based on the total weight of the negative electrode active material

wherein the low crystalline artificial graphite has an interplanar spacing d 002 of a (002) plane is in a range of greater than 0.338 nm to less than 0.3396 nm, as measured by X-ray diffraction (XRD)

wherein the negative electrode active material has a non-spherical shape with an average aspect ratio (a length on a major axis/a length on a minor axis) of 0.1 to 1 and has a tap density in a range of 0.6 g/cc to 1 g/cc

wherein the negative electrode active material has a crystal orientation index with respect to an area ratio I( 110 )/I( 002 ) in a range of 0.0238 to 0.0268, the area ratio being obtained by integrating XRD peaks.

2. The negative electrode active material of claim 1 , wherein the low crystalline artificial graphite is obtained by sintering soft carbon in a temperature range of 2,000° C. or higher and less than 2,800° C.

3. The negative electrode active material of claim 2 , wherein the low crystalline artificial graphite has a peak's full width at half-maximum (FWHM) in a range of 0.5° to 0.6°, as measured by XRD.

4. The negative electrode active material of claim 1 , wherein the negative electrode active material has an I( 002 ) peak's full width at half-maximum (FWHM) in a range of 0.5° to 0.6° as measured by XRD.

5. The negative electrode active material of claim 1 , wherein the negative electrode active material has a crystallite size Lc(002) in a c-axis direction in a range of 15.1 nm to 15.7 nm, as measured by XRD.

6. The negative electrode active material of claim 1 , wherein the negative electrode active material has a specific surface area (BET) in a range of 1 m 2 /g to 10 m 2 /g.

7. A negative electrode comprising:

a current collector; and

the negative electrode active material of claim 1 formed on at least one surface of the current collector.

8. A lithium secondary battery comprising the negative electrode of claim 7 .

9. A method of manufacturing a negative electrode active material of claim 1 , the method comprising:

sintering soft carbon at a temperature range of 2,000° C. or higher to 2,800° C. to obtain low crystalline artificial graphite; and

forming an amorphous carbon coating layer on the low crystalline artificial graphite.

10. The method of claim 9 , wherein the soft carbon is formed by carbonizing one or a mixed carbonaceous material of two or more selected from the group consisting of a polyvinyl alcohol, a polyvinyl chloride, a carboniferous pitch, a petroleum-based pitch, a mesophase pitch, and heavy oil.

11. The method of claim 9 , wherein the amorphous carbon coating layer is formed by mixing low crystalline carbon particles with an amorphous carbon precursor, and thermally treating the resulting mixture.

12. The method of claim 11 , wherein the amorphous carbon precursor is one or a mixture of two or more selected from the group consisting of glucose, fructose, galactose, maltose, lactose, sucrose, a phenolic resin, a naphthalene resin, a polyvinyl alcohol resin, a urethane resin, a polyimide resin, a furan resin, a cellulose resin, an epoxy resin, a polystyrene resin, a resorcinol-based resin, a phloroglucinol-based resin, a carboniferous pitch, a petroleum-based pitch, tar, and a medium oil.

13. The method of claim 11 , wherein a mixing ratio of the low crystalline carbon particle and the amorphous carbon precursor is in a range of 100:0.2 to 20, based on the weight ratio.

14. The method of claim 11 , wherein the thermal treatment is performed at a temperature range of 160° C. to 1,400° C.