Battery cell including electrode assembly coated with inert particles
Disclosed herein is a battery cell having an electrode assembly mounted in a variable cell case in a state in which the electrode assembly is impregnated with an electrolyte, the battery cell being configured to be flexibly deformed in response to the shape of a device, in which the battery cell is mounted, wherein a coating part including inert particles is formed on at least one outer surface of the electrode assembly.
1. A battery cell having an electrode assembly mounted in a variable cell case in a state in which the electrode assembly is impregnated with an electrolyte, the battery cell being configured to be flexibly deformed in response to a shape of a device, in which the battery cell is mounted, wherein a coating part comprising inert particles is formed on at least one outer surface of the electrode assembly, and
the cell case has a concave-convex structure formed by the inert particles of the coating part formed on the at least one outer surface of the electrode assembly.
2. The battery cell according to claim 1 , wherein the coating part comprising inert particles is formed on an upper major surface and/or a lower major surface of the electrode assembly in a direction in which electrodes are stacked.
3. The battery cell according to claim 1 , wherein the coating part comprising inert particles is partially or entirely formed on the at least one outer surface of the electrode assembly.
4. The battery cell according to claim 1 , wherein the coating part comprising inert particles is an inert particle layer comprising inert particles scattered on the at least one outer surface of the electrode assembly.
5. The battery cell according to claim 1 , wherein the coating part comprising inert particles comprises a binder layer added to the at least one outer surface of the electrode assembly and inert particles scattered on the binder layer.
6. The battery cell according to claim 5 , wherein the binder layer has a thickness less than a size of each of the inert particles.
7. The battery cell according to claim 6 , wherein the thickness of the binder layer is 10 to 95% of the size of each of the inert particles.
8. The battery cell according to claim 1 , wherein the coating part comprising inert particles is a mixture layer comprising inert particles and a binder.
9. The battery cell according to claim 8 , wherein the mixture layer has a thickness of 1 to 150 micrometers.
10. The battery cell according to claim 8 , wherein a specific gravity of the inert particles is 30 to 90% of an overall specific gravity of the mixture layer.
11. The battery cell according to claim 1 , wherein each of the inert particles is a porous particle having pores formed therein.
12. The battery cell according to claim 1 , wherein each of the inert particles is an organic particle and/or an inorganic particle.
13. The battery cell according to claim 12 , wherein each of the inert particles is an organic particle.
14. The battery cell according to claim 12 , wherein the organic particle is made of a polymer or a silane-based compound.
15. The battery cell according to claim 12 , wherein the inorganic particle is one or a mixture of two or more selected from a group consisting of SiO 2 , Al 2 O 3 , MgO, TiO 2 , ZrO 2 , CaO, Y 2 O 3 , and SrO.
16. The battery cell according to claim 1 , wherein each of the inert particles is configured to have a spherical shape, an oval shape, or a polyhedral shape.
17. The battery cell according to claim 1 , wherein each of the inert particles has a size of 50 to 100 micrometers.
18. The battery cell according to claim 1 , wherein the cell case is a pouch-shaped case made of a laminate sheet comprising a resin layer and a metal layer.
19. The battery cell according to claim 1 , wherein the electrode assembly is a jelly-roll type electrode assembly, configured to have a structure in which a long sheet type positive electrode and a long sheet type negative electrode are wound while a separator is disposed between the positive electrode and the negative electrode, or a stacked/folded type electrode assembly, configured to have a structure in which positive electrodes and negative electrodes, each of which has a predetermined size, are sequentially stacked in a state in which separators are disposed respectively between the positive electrodes and the negative electrodes to constitute a bi-cell or a full cell and then bi-cells or full cells are folded using a separation film.
20. A method of manufacturing a battery cell according to claim 1 , the method comprising:
(a) preparing an electrode assembly comprising a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode;
(b) forming a coating part comprising inert particles on at least one outer surface of the electrode assembly; and
(c) placing the electrode assembly having the coating part formed thereon in a receiving part of a variable cell case and pressing the cell case such that the cell case comes into tight contact with the electrode assembly.
21. A battery module comprising two or more battery cells according to claim 1 .
22. A battery pack comprising a battery module according to claim 21 .
23. A device comprising a battery pack according to claim 22 as a power source.
24. The device according to claim 23 , wherein the device is selected from a group consisting of a mobile phone, a portable computer, a smart phone, a tablet PC, a smart pad, a netbook computer, a light electronic vehicle (LEV), an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, and a power storage apparatus.