Positive electrode material slurry for lithium secondary battery including at least two conductive materials and lithium secondary battery using the same
Provided is a positive electrode material slurry for secondary battery including a positive electrode active material, a conductive agent, a binder, and a solvent, wherein the conductive agent includes a first conductive agent and a second conductive agent having different particle shapes and sizes. Since the conductive agent of the present invention may be uniformly dispersed in the positive electrode active material by including a point-type conductive agent, as the first conductive agent, and carbon nanotubes (CNTs) subjected to a grinding process as the linear second conductive agent, conductivity of an electrode to be prepared may be improved and a secondary battery having improved high-rate discharge capacity characteristics may be provided.
1. A method of preparing a positive electrode material slurry for a secondary battery, the method comprising:
mixing an active material, a conductive agent, and a binder to prepare a mixture;
grinding rope carbon nanotubes to prepare linear carbon nanotubes having an average length of 1 μm to 5 μm to form ground carbon nanotubes; and
preparing a positive electrode material slurry by dispersing the ground carbon nanotubes while stirring the mixture.
2. The method of claim 1 , wherein the rope carbon nanotubes comprise any one selected from the group consisting of single-walled carbon nanotubes composed of a single layer, double-walled carbon nanotubes composed of double layers, and multi-walled carbon nanotubes composed of multiple layers of three or more layers.
3. The method of claim 1 , wherein the rope carbon nanotubes comprise bundle-type carbon nanotubes, in which a plurality of carbon nanotubes is arranged in a linear shape, a curved shape, or a mixed shape thereof, or entangled type carbon nanotubes.
4. The method of claim 1 , wherein the grinding is performed by using a wet grinding method.
5. The method of claim 1 , wherein the wet grinding method is performed using a high pressure homogenizer at a speed of 100 rpm to 5,000 rpm for 0.5 hours to 12 hours.