Titanium material or titanium alloy material having surface electrical conductivity and method for producing the same, and fuel cell separator and fuel cell using the same
View Patent ↗In a titanium material or a titanium alloy material, in an oxide film formed on a surface of a titanium or a titanium alloy, the composition ratio of TiO (I TiO /(I Ti +I TiO )×100 found from the maximum intensity of the X-ray diffraction peaks of TiO (I TiO ) and the maximum intensity of the X-ray diffraction peaks of metal titanium (I Ti ) in X-ray diffraction measured at an incident angle to the surface of 0.3° is 0.5% or more. A titanium material or a titanium alloy material, and a fuel cell separator and a polymer electrolyte fuel cell having good contact-to-carbon electrical conductivity and good durability can be provided.
1. A titanium material or a titanium alloy material, comprising:
a titanium or titanium alloy; and
a titanium oxide film on a surface of the titanium or titanium alloy, wherein an outermost surface of the titanium oxide film comprises TiO 2 ,
wherein a composition ratio of TiO (I TiO /(I Ti +I TiO ))×100 based on a maximum intensity of X-ray diffraction peaks of TiO (I TiO ) and a maximum intensity of X-ray diffraction peaks of metal titanium (I Ti ) in X-ray diffraction measured at an incident angle to a surface of 0.3° is 0.5% or more, and
wherein each of amounts of increase in contact resistance from before to after deterioration test 1 and deterioration test 2 below is 10 mΩcm 2 or less:
deterioration test 1: immersion for 4 days in a sulfuric acid aqueous solution at 80° C. adjusted to pH 3 and having a fluoride ion concentration of 20 ppm,
deterioration test 2: application of an electric potential of 1.0 V (vs. SHE) for 24 hours in a sulfuric acid solution at 80° C. and pH 3.
2. The titanium material or the titanium alloy material according to claim 1 , wherein a diffraction peak of TiO is detected in X-ray diffraction measured at the surface at an incident angle of 0.3° and the maximum intensity of the X-ray diffraction peaks of a titanium hydride is at a background level.
3. The titanium material or the titanium alloy material according to claim 1 , wherein a thickness of the oxide film is 3 to 15 nm.
4. A method for producing a titanium material or a titanium alloy material, comprising:
providing a titanium intermediate material or a titanium alloy intermediate material,
forming a titanium hydride layer on an outer layer of the titanium intermediate material or titanium alloy intermediate material, wherein a composition ratio of the titanium hydride (I Ti—H /(I Ti +I T-H )) at a surface, based on a maximum intensity of metal titanium (I Ti ) and a maximum intensity of the titanium hydride (I Ti—H ) in X-ray diffraction peaks measured at an incident angle to a surface of 0.3° is 55% or more, and
subjecting the titanium intermediate material or titanium alloy intermediate material, having the titanium hydride layer on an outer layer thereof, to a heating treatment at a temperature of not less than 260° C. and less than 350° C. in an oxidizing atmosphere to form an oxide film.
5. A fuel cell separator comprising a titanium material or a titanium alloy material, wherein:
the titanium material or titanium alloy material comprises a titanium or titanium alloy, and a titanium oxide film on a surface of the titanium or titanium alloy; and
a composition ratio of TiO (I TiO /I Ti +I TiO ))×100 based on a maximum intensity of X-ray diffraction peaks of TiO (I TiO ), and a maximum intensity of X-ray diffraction peaks of metal titanium (I Ti ) in X-ray diffraction measured at an incident angle to a surface of 0.3° is 0.5% or more.
6. A polymer electrolyte fuel cell comprising the fuel cell separator according to claim 5 .