Pyrazolyl-heteroarylamides as pesticides

1. A compound of the formula (Ic)

in which

R 1 is hydrogen or CH 3 ;

Z 1 is CF 2 CF 3 ;

Z 2 is CF 3 ;

Z 3 is CH 3 ,

A 1 is CH;

A 2 is CH or nitrogen;

A 3 is CR 4 ;

R 4 is fluorine; chlorine; hydrogen; or CH 3 ;

A 4 is CR 5 ,

R 5 is fluorine or hydrogen;

n is 0;

W is oxygen; and

Q is ethyl; isopropyl; t-butyl; cyclopentyl; phenoxyethyl; benzyloxymethyl; CF 3 CH 2 —; CHF 2 CF 2 —; MeOCH 2 —; MeOCH 2 CH 2 —; 3-pyridinyl; 4-pyridinyl; 2-F-4-pyridinyl; 3-F-4-pyridinyl; 3-F-5-pyridinyl; 3-Cl-2-pyridinyl; 2-Cl-3-pyridinyl; 2-Cl-4-pyridinyl; 2-Cl-5-pyridinyl; 2,6-Cl 2 -4-pyridinyl; 2-Cl-6-Me-4-pyridinyl; 2-Me-4-pyridinyl; 2-CN-5-pyridinyl; 2-F-5-pyridinyl; phenyl; 2-F-phenyl; 3-F-phenyl; 4-F-phenyl; 3,5-F 2 -phenyl; 2,6-F 2 -phenyl; 3-MeO-phenyl; 2,3-F 2 -phenyl; 2-EtO-phenyl; 2-CF 3 O-phenyl; 3-cyanophenyl; 4-CN-phenyl; phenylthiomethyl; 2-thiophenyl; 3-thiophenyl; 3-Cl-2-thiophenyl; 2-thiophenyl-methyl; 3-Cl-benzothiophen-2-yl; 3-Cl-6-Me-benzothiophen-2-yl; cyclopropyl; 1-CN-cyclopropyl; 1-Cl-cyclopropyl; 1-Me-cyclopropyl; 1-phenylcycloprop-1-yl; 1-oxazolyl; 5-methylisoxazol-4-yl; 2-pyrimidinyl; 4-pyrimidinyl; 7-(difluoromethyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-yl; 1-methyl-4-pyrazolyl; 1-Me-3-tBu-4-NO 2-5 -pyrazolyl; 3-CF 3 -4-Me-pyrazol-1-yl-methyl; (1,1-dimethyl)-2-fluoroethyl; cis/trans-4-MeO-cyclohex-1-yl; 1-Me-cyclohex-1-yl; 3-CF 3 -4-F-phenyl; 3-CF 3 -phenyl; 4-Me-phenyl; 2,6-(MeO) 2 -phenyl; 4-(Me 2 N)-phenyl; 2,4,6-(iPr) 3 -phenyl; 3-Me-2-benzofuranyl; 2-CF 3 -4-Me-furan-2-yl; 1,1,2,2-tetramethylethyl; (R)-1-F-ethyl; 2-Me-3-furanyl; 2-Me-prop-1-yl; 5-Me-thien-2-yl; 2,2-dimethylprop-1-yl; 2,3-dimethylphenyl; 1,1-dimethyl-2-ethoxyethyl; 2,2-difluoro-1,3-benzodioxol-5-yl; 3,4-dimethylphenyl; 3-Me, 4-F-phenyl; 3-F, 4-Me-phenyl; 3-F, 4-MeO-phenyl; 1,3-benzodioxol-5-yl; 4-Cl, 3-F-phenyl; 3-MeO, 4-Me-Ph; 3-EtO, 4-F-phenyl; 3-EtO-4-F-phenyl; 3-MeO-4-F-phenyl; 3-F-4-MeO-phenyl; 1-(4-Me-phenyl)cyclohex-1-yl; 3-CF 3 -benzyl; 3-F-benzyl; 2-Cl-4-F-benzyl; 1-methyl-1-(3-Cl-phenyl)ethyl; 1-(4-Cl-phenyl)-cyclobut-1-yl; (rac)-1-phenylethyl; (rac)-phenyl-cyclopentylmethyl; (rac)-tetralin; (rac)-1-(4-Cl-phenyl)-2-methyl-prop-1-yl; (rac)-1-phenoxy-ethyl; (rac)-1-phenyl-prop-1-yl; (rac)-1-methylpropyl; 2-phenylethyl; N′,N′-dimethyloxalyl-amide; 3-MeO, 4-F-phenyl; 3-F; or 4-MeO-phenyl.

2. The compound according to claim 1 , in which R 1 is hydrogen.

3. The compound according to claim 1 , in which R 1 is CH 3 .

4. The compound according to claim 1 , in which the compound is of the formula (Ic-1)

5. The compound according to claim 1 , in which the compound is of the formula (Ic-2)

6. A method for control of at least one of insects, arachnids, and nematodes comprising administering an effective amount of the compound according to claim 1 of the formula (Ic).

7. A pharmaceutical composition comprising at least one compound comprising to claim 1 in combination with a pharmaceutically acceptable excipient and/or an auxiliary.

8. A medicament comprising the compound according to claim 1 in combination with a pharmaceutically acceptable excipient and/or an auxiliary.

9. A method of making a crop protection composition comprising combining the compound according to claim 1 with an extender and/or a surfactant.

10. A method for controlling pests, comprising administering an effective amount of the compound according to claim 1 to plants, seeds, crops, animals, pests and/or the pest's habitat.

11. A method for protection of propagation material of plants comprising administering an effective amount of the compound according to claim 1 to the plants or their propagation material.

12. The compound according to claim 1 , in which R 4 is fluorine.

13. The compound according to claim 1 , in which R 4 is chlorine.

14. The compound according to claim 1 , in which R 4 is hydrogen.

15. The compound according to claim 1 , in which R 4 is CH 3 .

16. The compound according to claim 1 , in which R 5 is hydrogen.

17. The compound according to claim 1 , in which R 5 is fluorine.