α+β titanium alloy cold-rolled and annealed sheet having high strength and high young's modulus and method for producing the same
An object of the present invention is to provide an α+β titanium alloy cold-rolled and annealed sheet having a high strength and a high Young's modulus in the sheet width direction. A titanium alloy sheet in which, when the texture in the sheet plane direction is analyzed, the ratio XTD/XND between the X-ray relative intensity peak value (XTD) in directions close to the sheet width direction and the X-ray relative intensity peak value (XND) in directions close to the normal-to-sheet-plane direction on the (0002) pole figure of the α-phase is 5.0 or more and which contains, in mass %, Fe: 0.8% to 1.5% and N: 0.020% or less and has an oxygen-equivalent Q of 0.34 to 0.55. Annealing of the titanium alloy sheet is performed at not less than 500° C. and less than 800° C. in the case where the cold rolling rate is less than 25% and at not less than 500° C. and less than 620° C. in the case where the cold rolling rate is 25% or more.
1. An α+β titanium alloy cold-rolled and annealed sheet, consisting of, in mass %,
Fe: 0.8% to 1.5%,
N: 0.020% or less, and
the balance: Ti and impurities, and
satisfying Q shown in Formula (1) below =0.34 to 0.55,
wherein, when a texture in a sheet plane direction is analyzed, assuming that a normal-to-rolling-plane direction of a cold-rolled and annealed sheet is denoted by ND, a sheet longitudinal direction is denoted by RD, the sheet width direction is denoted by TD, a direction normal to a (0001) plane of an α-phase is taken as a c-axis direction, an angle between the c-axis direction and ND is denoted by θ, an angle between a line of projection of the c-axis direction onto the sheet plane and the sheet width direction (TD) is denoted by φ, a strongest intensity out of (0002)-reflection relative intensities of X-rays caused by crystal grains falling within a range of angle θ of not less than 0 degrees and not more than 30 degrees and angle φ of −180 degrees to 180 degrees is denoted by XND, and a strongest intensity out of (0002)-reflection relative intensities of X-rays caused by crystal grains falling within a range of angle θ of not less than 80 degrees and less than 100 degrees and angle φ of ±10 degrees is denoted by XTD, a ratio XTD/XND is 5.0 or more,
Q =[O]+2.77 * [N]+0.1* [Fe] (1)
where [Fe], [O], and [N] represent the amounts of the respective elements contained [mass %], and
wherein the α+β titanium alloy cold-rolled and annealed sheet has more than 130 GPa of Young's modulus and above 900 MPa of a tensile strength in the sheet width direction.
2. A method for producing the α+β titanium alloy cold-rolled and annealed sheet according to claim 1 ,
the method comprising:
producing an α+β titanium alloy cold-rolled and annealed sheet by performing unidirectional cold rolling in the same direction as a direction of hot rolling and annealing using, as a material, a unidirectionally hot-rolled sheet consisting of, in mass %,
Fe: 0.8% to 1.5%,
N: 0.020% or less, and
the balance: Ti and impurities, and
satisfying Q shown in Formula (1) below =0.34 to 0.55,
wherein annealing for a holding time of not less than t of Formula (2) below is performed at not less than 500° C. and less than 800° C. in a case where a cold rolling rate of the unidirectional cold rolling is less than 25% and annealing for a holding time of not less than t of Formula (2) below is performed at not less than 500° C. and less than 620° C. in a case where the cold rolling rate is 25% or more,
Q =[O]+2.77* [N]+0.1* [Fe] (1)
where [Fe], [O], and [N] represent the amounts of the respective elements contained [mass %],
t =exp(19180/ T− 15.6) (2)
where t: holding time (s), and T: holding temperature (K).