Insulating tape and production method thereof, stator coil and production method thereof, and rotating electric machine
An insulating tape having a mica layer, a reinforcing layer having a filler and a fiber reinforcing material laminated on the mica layer, and a cellulose derivative layer laminated on the reinforcing layer is provided. One or more hydroxyl groups in the glucose units of the cellulose derivative are substituted with a functional group such as —CH 2 CH 2 OH or —(CH 2 CH 2 O) p H (where p is any repeating number up to 50). The weight per unit area of the mica ranges from 100 g/m 2 to 200 g/m 2 . The filler has a maximum particle size of 100 μm or smaller and a weight per unit area ranging from 10 g/m 2 to 50 g/m 2 . The insulating tape is useful to form a stator coil insulating layer with high thermal conductivity, with no outflow of a filler to the exterior during production of the stator coil, and with enhanced bonding strength.
1. An insulating tape, comprising:
a mica layer containing mica;
a reinforcing layer laminated on the mica layer and containing a filler and a fiber reinforcing material; and
a cellulose derivative layer laminated on the reinforcing layer,
wherein the cellulose derivative layer contains a cellulose derivative in which one or more hydroxyl groups in the glucose units are substituted with at least one functional group selected from the group consisting of —CH 2 CH 2 OH, —CH 2 CH 2 OCH 2 CH 2 OH, —CH 2 CH(OH)CH 3 , —CH 3 , —CH 2 CH 3 , —NO 2 , —(CH 2 CH 2 O) p H, in the formula, p is any repeating number greater than 0 up to 50, —CH 2 COOH, —CH 2 CH 2 COOH, —CH 2 COOM, in the formula, M is Li, Na or K, and —(CH 2 CH 2 O) q CH 2 CH(OH)CH 2 N + (CH 3 ) 2 (n-C 12 H 25 )X − , in the formula, q is any repeating number from 0 to 50, and X − is Cl − , Br − , F − or I − ,
the weight per unit area of the mica ranges from 100 g/m 2 to 200 g/m 2 ,
the filler has a maximum particle size of 100 μm or smaller and the weight per unit area ranging from 10 g/m 2 to 50 g/m 2 , and
the weight per unit area of the cellulose derivative layer ranges from 0.001 g/m 2 to 5 g/m 2 .
2. The insulating tape according to claim 1 , wherein the filler is boron nitride.
3. The insulating tape according to claim 1 , wherein the cellulose derivative contains at least one glucose derivative in which 1 to 2 hydroxyl groups in the glucose units are substituted with a functional group selected from the group consisting of —CH 2 CH 2 OH and —(CH 2 CH 2 O) p H, in the formula, p is any repeating number from 2 to 50.
4. A method for producing an insulating tape, comprising:
forming a mica layer through sheet-forming of a dispersion containing mica;
forming a reinforcing layer by bonding a fiber reinforcing material to the mica layer and then coating the fiber reinforcing material with a slurry that contains a filler having a maximum particle size of 100 μm or smaller; and
forming a cellulose derivative layer by coating the reinforcing layer with a slurry that contains a cellulose derivative in which one or more hydroxyl groups in the glucose units are substituted with at least one functional group selected from the group consisting of —CH 2 CH 2 OH, —CH 2 CH 2 OCH 2 CH 2 OH, —CH 2 CH(OH)CH 3 , —CH 3 , —CH 2 CH 3 , —NO 2 , —(CH 2 CH 2 O) p H, in the formula, p is any repeating number greater than 0 up to 50, —CH 2 COOH, —CH 2 CH 2 COOH, —CH 2 COOM, in the formula M is Li, Na or K, and —(CH 2 CH 2 O) q CH 2 CH(OH)CH 2 N + (CH 3 ) 2 (n-C 12 H 25 )X − , in the formula, q is any repeating number from 0 to 50, and X − is Cl − , Br − , F − or I − ,
wherein the weight per unit area of the mica is set to a range from 100 g/m 2 to 200 g/m 2 ,
the weight per unit area of the filler is set to a range from 10 g/m 2 to 50 g/m 2 , and
the weight per unit area of the cellulose derivative layer is set to a range from 0.001 g/m 2 to 5 g/m 2 .
5. A stator coil, comprising:
a coil conductor; and
an insulating layer obtained by winding the insulating tape according to claim 1 around the coil conductor, impregnating the insulating tape with a liquid thermosetting resin, and performing hot-press molding.
6. A method for producing a stator coil, comprising:
winding the insulating tape according to claim 1 around a coil conductor; and
impregnating the insulating tape with a liquid thermosetting resin, and
performing hot-press molding.
7. A rotating electric machine, comprising the stator coil according to claim 5 accommodated in a slot of a stator iron core.