Lubricating oil composition
A lubricating oil composition containing a lubricating base oil and on the basis of the total mass of the composition, (A) a boron-containing ashless dispersant in an amount of 100 to 500 ppm by mass as boron, (B) a phosphorous additive in an amount of 300 to 800 ppm by mass as phosphorus, (C) an amide- and/or imide-based friction modifier in an amount of 1 to 4 percent by mass, and (D) an alkali metal- and/or alkaline earth metal-based detergent in an amount of 100 to 300 ppm by mass as metal, and having a 40° C. kinematic viscosity of 30 mm2/s or lower is provided. The lubricating oil composition, which has a low viscosity to improve fuel efficiency, also has superior anti-wear, anti-seizure, and anti-shattering properties, even when the composition is degraded by oxidation or by the elution of compounds from sealing materials after long term use.
1. A lubricating oil composition comprising a lubricating base oil and on the basis of the total mass of the composition, (A) a boron-containing ashless dispersant in an amount of 100 to 500 ppm by mass as boron, (B) a phosphorus additive in an amount of 300 to 800 ppm by mass as phosphorus, (C) an amide- and/or imide-based friction modifier in an amount of 1 to 4 percent by mass, and (D) an alkali metal- and/or alkaline earth metal-based detergent in an amount of 100 to 300 ppm by mass as metal, wherein the composition has a 40° C. kinematic viscosity of 25 mm 2 /s or lower and a 100° C. kinematic viscosity of 6.5 mm 2 /s or lower,
wherein Component (B) comprises a combination of a phosphite ester and phosphoric acid having a ratio ([P2]/[P1]) of the phosphorus amount [P2] of the phosphoric acid to the phosphorus amount [P1] of the phosphite ester of 0.2 to 1.0;
wherein Component (D) comprises a metallic detergent having a base number of less than 150 mgKOH/g and has a ratio ([M]/[P]) of the metal amount [M] of the metallic detergent to the phosphorus amount [P] of Component (B) of 0.06 to 0.25;
wherein the phosphite ester is a phosphite ester having an (alkyl)aryl group having 6 to 12 carbon atoms and the metallic detergent is a calcium sulfonate detergent.
2. The lubricating oil composition according to claim 1 , wherein Component (D) further comprises a metallic detergent having a base number of 200 mgKOH/g or greater.
3. The lubricating oil composition according to claim 1 , further comprising (E) a thiadiazole in an amount of 250 to 1000 ppm by mass as sulfur on the basis of the total mass of the composition.
4. The lubricating oil composition according to claim 1 , wherein the composition is used in a vehicle transmission.
5. The lubricating oil composition according to claim 1 , wherein the amide-based friction modifier of Component (C) comprises compounds represented by formula (3):
wherein R 2 is a hydrocarbon or functionalized hydrocarbon group having 1 to 30 carbon atoms, R 3 is a hydrocarbon or functionalized hydrocarbon group having 1 to 30 carbon atoms or hydrogen and R 4 is a divalent hydrocarbon or functionalized divalent hydrocarbon group having 1 to 10 carbon atoms.
6. The lubricating oil composition according to claim 5 , wherein in formula (3), R 3 is hydrogen.
7. The lubricating oil composition according to claim 1 , wherein the imide-based friction modifier of Component (C) comprises compounds represented by formula (4) or (5):
wherein R 5 and R 6 are each independently an alkyl or alkenyl group having 8 to 30 carbon atoms, R 7 and R 8 are each independently an alkylene group having 1 to 4 carbon atoms, R 9 is hydrogen or an alkyl or alkenyl group having 1 to 30 carbon atoms and n is an integer of 1-7.
8. The lubricating oil composition according to claim 1 , wherein Component (D) further comprises a metallic detergent having a base number of 200 mgKOH/g or greater and is a calcium salicylate detergent.