Wavelength converting compositions, wavelength converters and devices including the same
Disclosed herein are wavelength converting compositions, wavelength converters and light sources including the same. The wavelength converting compositions include at least one poly(silphenylene-siloxane) gel matrix that contains at least one wavelength conversion material, such as one or more phosphors in powdered and/or particulate form. Methods of making such compositions and converters are also disclosed. Wavelength converted light sources such as wavelength converted light emitting diode packages are also disclosed. The poly(silphenylene-siloxane) gel matrix exhibits relatively high thermal stability, as well as desirable optical properties.
1. A wavelength converting composition comprising:
a polymeric matrix comprising at least one poly(silphenylene-siloxane) gel; and
at least one wavelength converting material contained in the polymeric matrix,
wherein the at least one poly(silphenylene-siloxane) gel comprises a poly(silphenylene-siloxane) gel of formula (I):
wherein R 1 to R 7 are the same or are different and are selected from the group consisting of hydrogen atoms, substituted or unsubstituted, saturated or unsaturated, linear, branched or cyclic aliphatic hydrocarbon groups, aromatic hydrocarbon groups, fluorocarbon groups and combinations thereof,
wherein X 2 is a linking group selected from the group consisting of an alkylene group, an oxygen atom and a group derived from a curing agent,
wherein a is an integer ranging from 1 to 3,
wherein n and m represent relative fractions of different monomer units in the gel, where 0≤n≤1, 0≤m≤1, and n+m equals 1, and
wherein sites denoted by an ellipsis represent a continuation of the polymer with the same or similar monomer units as depicted in formula (I).
2. The wavelength converting composition of claim 1 , wherein the at least one poly(silphenylene-siloxane) gel is present in the composition in an amount ranging from greater than about 50 to about 99% by weight, and wherein the wavelength converting material is present in the composition in an amount ranging from about 1 to about 50% by weight.
3. The wavelength converting composition of claim 1 ,
wherein R 1 , R 2 , R 3 , and R 4 are hydrogen atoms,
wherein R 5 and R 6 are methyl groups, and
wherein R 7 is selected from a phenyl group and a methyl group.
4. The wavelength converting composition of claim 1 ,
wherein n=0,
wherein R 1 , R 2 , R 3 , and R 4 are hydrogen atoms, and
wherein R 7 is an aryl group.
5. The wavelength converting composition of claim 4 , wherein R 7 is phenyl.
6. The wavelength converting composition of claim 1 , wherein the poly(silphenylene-siloxane) gel is crosslinked via at least one of the sites denoted by an ellipsis.
7. The wavelength converting composition of claim 1 , wherein X 2 is a linking group derived from a curing agent or a corresponding moiety of an uncured poly(silphenylene-siloxane) copolymer.
8. The wavelength converting composition of claim 7 , wherein the curing agent is of the formula:
wherein R 1 ′ to R 3 ′ are the same or are different and are selected from the group consisting of substituted or unsubstituted, saturated or unsaturated, linear, branched or cyclic aliphatic hydrocarbon groups, aromatic hydrocarbon groups, fluorocarbon groups and combinations thereof,
wherein at least one of A 1 , A 2 and A 3 are capable of crosslinking two of more chains of the poly(silphenylene-siloxane) gel via at least one of X 2 or the sites denoted by an ellipsis,
wherein A 2 corresponds to or is a precursor of X 2 , and is selected from the group consisting of an alkenyl group, a hydroxyl group, an alkoxy group, an alkenoxy group and an aryloxy group,
wherein A 1 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxy group, an alkenoxy group, an aryloxy group, an alkyl group and an alkenyl group,
wherein A 3 is one of a hydrogen atom, a linear, branched, cyclic, saturated or unsaturated aliphatic alkyl group, an alkenyl group, an allyl group, an aryl group, or a hydrogensilyl group of the formula SiZ 2 H, where Z is an alkyl group, an alkenyl group, an aryl group, or a fluorocarbon group, and
wherein 0≤c≤1, 0≤d≤1, and c+d equals 1.
9. The wavelength converting composition of claim 8 , wherein A 1 is a hydroxyl group, A 2 is an ethoxy group and A 3 is an ethoxy group.
10. The wavelength converting composition of claim 1 , wherein the wavelength converting material comprises a phosphor.
11. The wavelength converting composition of claim 10 , wherein the phosphor is selected from the group consisting of cerium-activated yttrium aluminum garnet phosphors, cerium-activated yttrium gadolinium aluminum garnet phosphors, cerium-activated lutetium aluminum garnet phosphors, europium-activated alkaline earth silicon oxynitride phosphors, europium-activated metal-SiAlON phosphors and combinations thereof.
12. The wavelength converting composition of claim 1 , further comprising at least one optically transparent inorganic particulate material.
13. An LED light source comprising:
at least one LED configured to emit primary light in a first wavelength range from a light emitting surface thereof; and
a wavelength converter disposed over the at least one LED, the wavelength converter comprising a wavelength converting composition comprising:
a polymeric matrix comprising at least one poly(silphenylene-siloxane) gel; and
at least one wavelength converting material contained in the polymeric matrix, the wavelength converting material capable of converting at least a portion of the primary light to secondary light in a second wavelength range,
wherein the at least one poly(silphenylene-siloxane) gel comprises a poly(silphenylene-siloxane) gel of formula (I):
wherein R 1 , to R 7 are the same or are different and are chosen from the group consisting of hydrogen atoms, substituted or unsubstituted, saturated or unsaturated, linear, branched or cyclic aliphatic hydrocarbon groups, aromatic hydrocarbon groups, fluorocarbon groups and combinations thereof,
wherein X 2 is a linking group selected from the group consisting of an alkylene group, an oxygen atom and a group derived from a curing agent,
wherein a is an integer ranging from 1 to 3,
wherein n and m represent relative fractions of different monomer units in the gel, where 0≤n≤1, 0≤m≤1, and n+m equals 1, and
wherein sites denoted by an ellipsis represent a continuation of the polymer with the same or similar monomer units as depicted in formula (I).
14. The LED light source of claim 13 , wherein the at least one poly(silphenylene-siloxane) gel is present in the composition in an amount ranging from greater than about 50 to about 99% by weight, and wherein the wavelength converting material is present in the composition in an amount ranging from about 1 to about 50% by weight.
15. The LED light source of claim 13 ,
wherein R 1 , R 2 , R 3 , and R 4 are hydrogen atoms,
wherein R 5 and R 6 are methyl groups, and
wherein R 7 is chosen from a phenyl group and a methyl group.
16. The LED light source of claim 13 ,
wherein n=0,
wherein R 1 , R 2 , R 3 , and R 4 are hydrogen atoms, and
wherein R 7 is an aryl group.
17. The LED light source of claim 15 , wherein R 7 is phenyl.
18. The LED light source of claim 13 , wherein the poly(silphenylene-siloxane) gel is crosslinked via at least one of the sites denoted by an ellipsis.
19. The LED light source of claim 13 , wherein the poly(silphenylene-siloxane) gel is crosslinked via a linking group derived from a curing agent.
20. The LED light source of claim 19 , wherein the curing agent is of the formula:
wherein functional groups R 1 ′ to R 3 ′ are the same or different and are chosen from the group consisting of substituted or unsubstituted, saturated or unsaturated, linear, branched or cyclic aliphatic hydrocarbon groups, aromatic hydrocarbon groups, fluorocarbon groups and combinations thereof,
wherein at least one of A 1 , A 2 and A 3 are capable of crosslinking two of more chains of the poly(silphenylene-siloxane) gel via at least one of X 2 or the sites denoted by an ellipsis,
wherein A 2 corresponds to or is a precursor of X 2 , and is selected from the group consisting of an alkenyl group, a hydroxyl group, an alkoxy group, an alkenoxy group and an aryloxy group,
wherein A 1 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxy group, an alkenoxy group, an aryloxy group, an alkyl group, an alkenyl group and an allyl group,
wherein A 3 is one of a hydrogen atom, a linear, branched, cyclic, saturated or unsaturated aliphatic alkyl group, an alkenyl group, an allyl group, an aryl group, or a hydrogensilyl group of the formula SiZ 2 H, where Z is an alkyl group, an alkenyl group, an aryl group, or a fluorocarbon group, and
wherein 0≤c≤1, 0≤d≤1, and c+d equals 1.
21. The LED light source of claim 20 , wherein A 1 is a hydroxyl group, A 2 is an ethoxy group and A 3 is an ethoxy group.
22. The LED light source of claim 13 , wherein the wavelength converting material comprises a phosphor selected from the group consisting of cerium-activated yttrium aluminum garnet phosphors, cerium-activated yttrium gadolinium aluminum garnet phosphors, cerium-activated lutetium aluminum garnet phosphors, europium-activated alkaline earth silicon oxynitride phosphors, europium-activated metal-SiAlON phosphors and combinations thereof.
23. The LED light source of claim 13 , further comprising at least one optically transparent inorganic particulate material.
24. A method of manufacturing a wavelength converting composition, the method comprising:
distributing a wavelength conversion material in an uncured resin to form a mixture, the uncured resin comprising a poly(silphenylene-siloxane) copolymer resin; and
curing the poly(silphenylene-siloxane) copolymer resin to form a poly(silphenylene-siloxane) gel containing the wavelength conversion material,
wherein the poly(silphenylene-siloxane) copolymer resin is of the formula:
wherein R 1 to R 7 are the same or different and are selected from the group consisting of hydrogen atoms, substituted or unsubstituted, saturated or unsaturated, linear, branched or cyclic aliphatic hydrocarbon groups, aromatic hydrocarbon groups, fluorocarbon groups and combinations thereof,
wherein A 2 is selected from the group consisting of an alkenyl group, an allyl group, an alkoxy group, an alkenoxy group and an aryloxy group,
wherein A 1 is selected from the group consisting of a hydrogen atom, a hydroxyl group, an alkoxy group, an alkenoxy group, an alkenyl group, an allyl group and an aryloxy group,
wherein A 3 is one of a hydrogen atom, a linear, branched, cyclic, saturated or unsaturated aliphatic alkyl group, an alkenyl group, an allyl group, an aryl group, or a hydrogensilyl group of the formula SiZ 2 H, where Z is an alkyl group, an alkenyl group, an aryl group, or a fluorocarbon group,
wherein a is an integer ranging from 1 to 3,
wherein 0≤n≤1, 0≤m≤1, and
wherein n+m=1.
25. The method of claim 24 , wherein R 1 , R 2 , R 3 and R 4 are each hydrogen, R 5 and R 6 are methyl, R 7 is a phenyl group, A 1 is a hydroxyl group, A 2 is an ethoxy group and A 3 is an ethoxy group.
26. The method of claim 24 , wherein R 3 and R 4 are each hydrogen, R 5 and R 6 are each phenyl groups, A 1 is a hydroxyl group and A 3 is a hydrogen atom.