Filament
A filament according to an aspect of the present invention includes a predetermined chemical composition, in which a diameter r of the filament is 0.15 mm to 0.35 mm, a soft portion is formed along an outer circumference of the filament, the Vickers hardness of the soft portion is lower than that of a position of the filament at a depth of ¼ of the diameter r by Hv 50 or higher, the thickness of the soft portion is 1 μm to 0.1×r mm, the metallographic structure of a center portion of the filament contains 95% to 100% of pearlite by area %, the average lamellar spacing of pearlite in a portion from a surface of the filament to a depth of 1 μm is less than that of pearlite at the center of the filament, the difference between the average lamellar spacing of pearlite in the portion from the surface of the filament to the depth of 1 μm and the average lamellar spacing of pearlite at the center of the filament is 2.0 nm or less, and the tensile strength is 3200 MPa or higher.
1. A filament comprising, as a chemical composition, by mass %,
C: 0.70% to 1.20%,
Si: 0.15% to 0.60%,
Mn: 0.10% to 1.00%,
N: 0.0010% to 0.0050%,
Al: 0% to 0.010%,
Ti: 0% to 0.10%,
Cr: 0% to 0.50%,
Co: 0% to 0.50%,
V: 0% to 0.50%,
Cu: 0% to 0.20%,
Nb: 0% to 0.100%,
Mo: 0% to 0.20%,
W: 0% to 0.200%,
B: 0% to 0.0030%,
REM: 0% to 0.0050%,
Ca: 0% to 0.0050%,
Mg: 0% to 0.0050%,
Zr: 0% to 0.0100%, and
a remainder including Fe and impurities,
wherein a diameter r of the filament is 0.15 mm to 0.35 mm,
a soft portion is formed along an outer circumference of the filament,
a Vickers hardness of the soft portion is lower than that of the filament at a depth of ¼ of the diameter r by a Hv 50 or higher,
a thickness of the soft portion is 1 μm to 0.1×r mm,
a metallographic structure of the filament other than the soft portion contains 95% to 100% of pearlite by area %,
an average lamellar spacing of the pearlite in a region from a surface of the filament to a depth of 1 μm is less than that of the pearlite at the center of the filament,
a difference between the average lamellar spacing of the pearlite in the region from the surface of the filament to the depth of 1 μm and the average lamellar spacing of the pearlite at the center of the filament is 2.0 nm or less, and
a tensile strength is 3200 MPa or higher.
2. The filament according to claim 1 ,
wherein the thickness of the soft portion is 2 μm to 0.08×r mm.
3. The filament according to claim 1 ,
wherein the difference between the average lamellar spacing in the region from the surface of the filament to the depth of 1 μm and the average lamellar spacing of the center of the filament is 1.7 nm or less.
4. The filament according to claim 1 , further comprising, as the chemical composition, by mass %, one element or two or more elements selected from the group consisting of:
Ti: 0.005% to 0.10%,
Cr: more than 0% to 0.50%,
Co: more than 0% to 0.50%,
V: more than 0% to 0.50%,
Cu: more than 0% to 0.20%,
Nb: more than 0% to 0.100%,
Mo: more than 0% to 0.20%,
W: more than 0% to 0.20%,
B: more than 0% to 0.0030%,
REM: more than 0% to 0.0050%,
Ca: more than 0.0005% to 0.0050%,
Mg: more than 0.0005% to 0.0050%, and
Zr: more than 0.0005% to 0.0100%.
5. The filament according to claim 2 ,
wherein the difference between the average lamellar spacing in the region from the surface of the filament to the depth of 1 μm and the average lamellar spacing of the center of the filament is 1.7 nm or less.
6. The filament according to claim 2 , further comprising, as the chemical composition, by mass %, one element or two or more elements selected from the group consisting of:
Ti: 0.005% to 0.10%,
Cr: more than 0% to 0.50%,
Co: more than 0% to 0.50%,
V: more than 0% to 0.50%,
Cu: more than 0% to 0.20%,
Nb: more than 0% to 0.100%,
Mo: more than 0% to 0.20%,
W: more than 0% to 0.20%,
B: more than 0% to 0.0030%,
REM: more than 0% to 0.0050%,
Ca: more than 0.0005% to 0.0050%,
Mg: more than 0.0005% to 0.0050%, and
Zr: more than 0.0005% to 0.0100%.
7. The filament according to claim 3 , further comprising, as the chemical composition, by mass %, one element or two or more elements selected from the group consisting of:
Ti: 0.005% to 0.10%,
Cr: more than 0% to 0.50%,
Co: more than 0% to 0.50%,
V: more than 0% to 0.50%,
Cu: more than 0% to 0.20%,
Nb: more than 0% to 0.100%,
Mo: more than 0% to 0.20%,
W: more than 0% to 0.20%,
B: more than 0% to 0.0030%,
REM: more than 0% to 0.0050%,
Ca: more than 0.0005% to 0.0050%,
Mg: more than 0.0005% to 0.0050%, and
Zr: more than 0.0005% to 0.0100%.
8. The filament according to claim 5 , further comprising, as the chemical composition, by mass %, one element or two or more elements selected from the group consisting of:
Ti: 0.005% to 0.10%,
Cr: more than 0% to 0.50%,
Co: more than 0% to 0.50%,
V: more than 0% to 0.50%,
Cu: more than 0% to 0.20%,
Nb: more than 0% to 0.100%,
Mo: more than 0% to 0.20%,
W: more than 0% to 0.20%,
B: more than 0% to 0.0030%,
REM: more than 0% to 0.0050%,
Ca: more than 0.0005% to 0.0050%,
Mg: more than 0.0005% to 0.0050%, and
Zr: more than 0.0005% to 0.0100%.