High-strength hot-dip galvanized steel sheet and method for producing same
Disclosed is a high-strength hot-dip galvanized steel sheet produced from a steel sheet containing Si and Mn as a base material and a method for producing the same. The method using the following conditions for a heating process for annealing: (1) The rate of temperature rise when the temperature inside an annealing furnace is in a temperature range of from 450° C. to A° C. inclusive (where A is an arbitrary value selected in a range of 500≤A) is 7° C./sec. or more; (2) The maximum steel sheet temperature reached during the annealing is 600° C. or higher and 750° C. or lower; (3) When the temperature of the steel sheet is in a temperature range of from 600° C. to 750° C. inclusive during the annealing, the transit time of the steel sheet is 30 seconds or longer and 10 minutes or shorter, and the dew point of an atmosphere is −45° C. or lower.
1. A method for producing a high-strength hot-dip galvanized steel sheet including a steel sheet and a galvanized coating layer formed on the surface of the steel sheet with a coating weight of 20 to 120 g/m 2 per side of the steel sheet, the galvanized coating layer being formed after annealing of the steel sheet, the steel sheet containing, by mass %, C: 0.03 to 0.35%, Si: 0.01 to 0.50%, Mn: 3.6 to 8.0%, Al: 0.001 to 1.000%, P: 0.10% or less, and S: 0.010% or less, with the balance being Fe and unavoidable impurities,
the method comprising:
subjecting the steel sheet to annealing in a continuous galvanizing line,
wherein, in a heating process for the annealing, a rate of temperature rise of the steel sheet, when temperature of the steel sheet inside an annealing furnace is in a temperature range of from 450° C. to A° C. inclusive (where A is an arbitrary value selected in a range of 500≤A), is 7° C./sec. or more,
wherein maximum steel sheet temperature reached during the annealing is 600° C. or higher and 750° C. or lower, and
wherein, when the temperature of the steel sheet is in a temperature range of from 600° C. to 750° C. inclusive during the annealing, a transit time of the steel sheet in the temperature range of from 600° C. to 750° C. inclusive is 30 seconds or longer and 10 minutes or shorter, and the dew point of an atmosphere is −45° C. or lower; and then
subjecting the steel sheet subjected to the annealing to hot-dip galvanizing treatment.
2. The method for producing a high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the steel sheet further contains in a chemical composition thereof, by mass %, at least one element selected from B: 0.001 to 0.005%, Nb: 0.005 to 0.050%, Ti: 0.005 to 0.050%, Cr: 0.001 to 1.000%, Mo: 0.05 to 1.00%, Cu: 0.05 to 1.00%, Ni: 0.05 to 1.00%, Sn: 0.001 to 0.20%, Sb: 0.001 to 0.20%, Ta: 0.001 to 0.10%, W: 0.001 to 0.10%, and V: 0.001 to 0.10%.
3. The method for producing a high-strength hot-dip galvanized steel sheet according to claim 1 , further comprising, after the hot-dip galvanizing treatment, subjecting the steel sheet to alloying treatment by heating the steel sheet to a temperature of 450° C. or higher and 600° C. or lower to adjust the content of Fe in the coating layer within a range of 8 to 14% by mass.
4. A high-strength hot-dip galvanized steel sheet produced by the method for producing a high-strength hot-dip galvanized steel sheet according to claim 1 , comprising:
a base steel sheet and the galvanized coating layer formed on the base steel sheet,
wherein the base steel sheet has the chemical composition according to claim 1 , and
the total amount of at least one oxide selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, Ni, Sn, Sb, Ta, W, and V oxides (excluding the case where the at least one oxide includes only Fe oxides) that is present in a region within 100 μm from a surface of the base steel sheet and immediately below the galvanized coating layer is less than 0.010 g/m 2 per side of the base steel sheet.
5. The method for producing a high-strength hot-dip galvanized steel sheet according to claim 2 , further comprising, after the hot-dip galvanizing treatment, subjecting the steel sheet to alloying treatment by heating the steel sheet to a temperature of 450° C. or higher and 600° C. or lower to adjust the content of Fe in the coating layer within a range of 8 to 14% by mass.
6. A high-strength hot-dip galvanized steel sheet produced by the method for producing a high-strength hot-dip galvanized steel sheet according to claim 2 , comprising:
a base steel sheet and the galvanized coating layer formed on the base steel sheet,
wherein the base steel sheet has the chemical composition according to claim 2 , and
the total amount of at least one oxide selected from Fe, Si, Mn, Al, P, B, Nb, Ti, Cr, Mo, Cu, Ni, Sn, Sb, Ta, W, and V oxides (excluding the case where the at least one oxide includes only Fe oxides) that is present in a region within 100 μm from a surface of the base steel sheet and immediately below the galvanized coating layer is less than 0.010 g/m 2 per side of the base steel sheet.