Thermal insulation

1. A method of coating at least a portion of at least one surface of an object with a thermal insulation material, comprising:

combining a resin composition comprising a cyclic olefin composition with a catalyst composition comprising at least one metal carbene olefin metathesis catalyst, thereby forming a ROMP composition,

wherein the cyclic olefin composition comprises 10.0 mol % to 80.0 mol % of at least one cyclic olefin containing multiunsaturation, and up to 90.0 mol % of at least one cyclic olefin containing monounsaturation,

wherein the at least one cyclic olefin containing multiunsaturation may be substituted or unsubstituted;

wherein the at least one cyclic olefin containing monounsaturation may be substituted or unsubstituted;

contacting the ROMP composition with at least a portion of at least one surface of the object; and

subjecting the ROMP composition to conditions effective to promote a ROMP reaction of the cyclic olefin composition in the presence of the at least one metal carbene olefin metathesis catalyst, wherein the thermal insulation material is a ROMP polymer or a ROMP polymer composite.

2. The method according to claim 1 , wherein the object is a pipe, pipeline, pipe fitting, hose, hose fitting, tank, container, drum, manifold, riser, field joint, a subsea Christmas tree, jumper, spool piece, pipeline end termination, pipeline end manifold, robotic part, a robotic device, a robotic vehicle, wellhead equipment, a subsea dog house, or a combination thereof.

3. The method according to claim 1 , wherein the at least one cyclic olefin containing multiunsaturation is selected from dicyclopentadiene, tricyclopentadiene, cyclopentadiene tetramer, cyclopentadiene pentamer, 5-vinyl-2-norbornene, 5-ethylidene-2-norbornene, 5-isopropenyl-2-norbornene, 5-propenyl-2-norbornene, and 5-butenyl-2-norbornene.

4. The method according to claim 1 , wherein the at least one cyclic olefin containing monounsaturation is selected from 5-tolyl-2-norbornene, 5-phenyl-2-norbornene, 5-butyl-2-norbornene, 5-hexyl-2-norbornene, 5-octyl-2-norbornene, 5-decyl-2-norbornene, and 5-dodecyl-2-norbornene.

5. The method according to claim 1 , wherein the at least one cyclic olefin containing multiunsaturation is selected from dicyclopentadiene, tricyclopentadiene, cyclopentadiene tetramer, cyclopentadiene pentamer, 5-vinyl-2-norbornene, 5-ethylidene-2-norbornene, 5-isopropenyl-2-norbornene, 5-propenyl-2-norbornene, and 5-butenyl-2-norbornene; and

wherein the at least one cyclic olefin containing monounsaturation is selected from 5-tolyl-2-norbornene, 5-phenyl-2-norbornene, 5-butyl-2-norbornene, 5-hexyl-2-norbornene, 5-octyl-2-norbornene, 5-decyl-2-norbornene, and 5-dodecyl-2-norbornene.

6. The method according to claim 1 , wherein the at least one cyclic olefin containing multiunsaturation is selected from dicyclopentadiene, tricyclopentadiene and cyclopentadiene tetramer; and wherein the at least one cyclic olefin containing monounsaturation is selected from 5-tolyl-2-norbornene, 5-phenyl-2-norbornene, and 5-octyl-2-norbornene.

7. The method according to claim 1 , wherein the at least one at least one metal carbene olefin metathesis catalyst is a Group 8 transition metal complex having the structure of formula (I):

in which:

M is a Group 8 transition metal;

L 1 , L 2 , and L 3 are neutral electron donor ligands;

n is 0 or 1, such that L 3 may or may not be present;

m is 0, 1, or 2;

k is 0 or 1;

X 1 and X 2 are anionic ligands; and

R 1 and R 2 are independently selected from hydrogen, hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl,

wherein any two or more of X 1 , X 2 , L 1 , L 2 , L 3 , R 1 , and R 2 can be taken together to form one or more cyclic groups, and further wherein any one or more of X 1 , X 2 , L 1 , L 2 , L 3 , R 1 , and R 2 may be attached to a support.

8. The method according to claim 7 , wherein the at least one at least one metal carbene olefin metathesis catalyst is a Group 8 transition metal complex having the structure of formula (I), wherein:

M is ruthenium

n is O;

m is O;

k is 1;

L 1 and L 2 are trisubstituted phosphines independently selected from the group consisting of tri-n-butylphosphine (Pn-Bu 3 ), tricyclopentylphosphine (PCp 3 ), tricyclohexylphosphine (PCy 3 ), triisopropylphosphine (P-i-Pr 3 ), triphenylphosphine (PPh 3 ), methyldiphenylphosphine (PMePh 2 ), dimethylphenylphosphine (PMe 2 Ph), and diethylphenylphosphine (PEt 2 Ph); or

L 1 is an N-heterocyclic carbene selected from 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene, 1,3-bis(2,6-di-isopropylphenyl)-2-imidazolidinylidene, 1,3-bis(2,4,6-trimethylphenyl)-2-imidazol-2-ylidene, and 1,3-bis(2,6-di-isopropylphenyl)-2-imidazol-2-ylidene; and L2 is a trisubstituted phosphine selected from the group consisting of tri-n-butylphosphine (Pn-Bu 3 ), tricyclopentylphosphine (PCp 3 ), tricyclohexylphosphine (PCy 3 ), triisopropylphosphine (P-i-Pr 3 ), triphenylphosphine (PPh 3 ), methyldiphenylphosphine (PMePh 2 ), dimethylphenylphosphine (PMe 2 Ph), and diethylphenylphosphine (PEt 2 Ph);

X 1 and X 2 are chlorine; and

R 1 is hydrogen and R 2 is phenyl or —CH═C(CH 3 ) 2 ; or R 1 and R 2 are taken together to form an indenylidene moiety.

9. The method according to claim 1 , wherein the at least one at least one metal carbene olefin metathesis catalyst is a Group 8 transition metal complex having the structure of formula (VII):

wherein,

M is a Group 8 transition metal;

X 1 and X 2 are anionic ligands;

L 1 is a neutral electron donor ligand;

Y is a heteroatom selected from N, O, S, and P;

R 5 , R 6 , R 7 , and R 8 are each, independently, selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, aryl, heteroalkyl, heteroatom containing alkenyl, heteroalkenyl, heteroaryl, alkoxy, alkenyloxy, aryloxy, alkoxycarbonyl, carbonyl, alkylamino, alkylthio, aminosulfonyl, monoalkylaminosulfonyl, dialkylaminosulfonyl, alkylsulfonyl, nitrile, nitro, alkylsulfinyl, trihaloalkyl, perfluoroalkyl, carboxylic acid, ketone, aldehyde, nitrate, isocyanate, hydroxyl, ester, ether, amine, imine, amide, trifluoroamide, sulfide, disulfide, sultanate, carbamate, silane, siloxane, phosphine, phosphate, borate, or -A-Fn, wherein A is a divalent hydrocarbon moiety selected from alkylene and arylalkylene, wherein the alkyl portion of the alkylene and arylalkylene groups can be linear or branched, saturated or unsaturated, cyclic or acyclic, and substituted or unsubstituted, wherein the aryl portion of the of arylalkylene can be substituted or unsubstituted, and wherein hetero atoms and/or functional groups may be present in either the aryl or the alkyl portions of the alkylene and

arylalkylene groups, and Fn is a functional group; and any combination of R 5 , R 6 , R 7 , and R 8 can be linked to form one or more cyclic groups;

n is 1 or 2, such that n is 1 for the divalent heteroatoms 0 or S, and n is 2 for the trivalent heteroatoms N or P; and

Z is a group selected from hydrogen, alkyl, aryl, functionalized alkyl, functionalized aryl where the functional group may independently be one or more or the following: alkoxy, aryloxy, halogen, carboxylic acid, ketone, aldehyde, nitrate, isocyanate, hydroxyl, ester, ether, amine, imine, amide, trifluoroamide, sulfide, disulfide, carbamate, silane, siloxane, phosphine, phosphate, or borate; methyl, isopropyl, sec-butyl, t-butyl, neopentyl, benzyl, phenyl and trimethylsilyl; and

wherein any combination or combinations of X 1 , X 2 , L 1 , V, Z, R 5 , R 6 , R 7 , and R 8 may be linked to a support.

10. The method according to claim 1 , wherein the cyclic olefin composition comprises 20.0 mol % to 80.0 mol % of the at least one cyclic olefin containing multiunsaturation, and up to 80.0 mol % of the at least one cyclic olefin containing monounsaturation.

11. The method according to claim 10 , wherein the cyclic olefin composition comprises 30.0 mol % to 80.0 mol % of the at least one cyclic olefin containing multiunsaturation, and up to 70.0 mol % of the at least one cyclic olefin containing monounsaturation.

12. The method according to claim 11 , wherein the cyclic olefin composition comprises 40.0 mol % to 80.0 mol % of the at least one cyclic olefin containing multiunsaturation, and up to 60.0 mol % of the at least one cyclic olefin containing monounsaturation.

13. The method according to claim 12 , wherein the cyclic olefin composition comprises 40.0 mol % to 70.0 mol % of the at least one cyclic olefin containing multiunsaturation, and 30.0 mol % to 60.0 mol % of the at least one cyclic olefin containing monounsaturation.

14. The method according to claim 13 , wherein the cyclic olefin composition comprises 40.0 mol % to 60.0 mol % of the at least one cyclic olefin containing multiunsaturation, and 40.0 mol % to 60.0 mol % of the at least one cyclic olefin containing monounsaturation.

15. The method according to claim 14 , wherein the cyclic olefin composition comprises 50.0 mol % to 60.0 mol % of the at least one cyclic olefin containing multiunsaturation, and 40.0 mol % to 50.0 mol % of the at least one cyclic olefin containing monounsaturation.

16. The method according to claim 3 , wherein the at least one cyclic olefin containing multiunsaturation is dicyclopentadiene, tricyclopentadiene, and optionally cyclopentadiene tetramer.

17. The method according to claim 4 , wherein the at least one cyclic olefin containing monounsaturation is selected from 5-tolyl-2-norbornene, 5-hexyl-2-norbornene, 5-octyl-2-norbornene, and 5-decyl-2-norbornene.

18. The method according to claim 5 , wherein the at least one cyclic olefin containing multiunsaturation is dicyclopentadiene, tricyclopentadiene, and optionally cyclopentadiene tetramer;

wherein the at least one cyclic olefin containing monounsaturation is selected from 5-tolyl-2-norbornene, 5-hexyl-2-norbornene, 5-octyl-2-norbornene, and 5-decyl-2-norbornene.

19. The method according to claim 1 , wherein the thermal insulation material has a thermal conductivity of less than 0.180 W/m·K.

20. The method according to claim 1 , further comprising at least one additive.