Composition for solid lubricating coating, threaded connection for pipe or tube including the solid lubricating coating formed from the composition, and method of producing the threaded connection
This invention provides a threaded connection for pipe or tube that has a non-sticky surface and that suppresses the occurrence of rust and exhibits excellent galling resistance and airtightness even in an extremely low temperature environment without using compound grease, a method of producing the same, and a composition for forming a solid lubricating coating on the threaded connection. A solid lubricating coating ( 24 ) formed from a composition containing a binder, a fluorine addition agent, a solid lubricant and a rust proof addition agent is coated as a topmost surface treatment coating on a contact surface of at least one of a pin and a box. Even when exposed to an extremely low temperature environment, the solid lubricating coating ( 24 ) can maintain adhesiveness and exhibit a lubricating function, can suppress the occurrence of galling of a threaded connection, and can also secure airtightness after fastening.
1. A composition for forming a solid lubricating coating on a threaded connection for pipe or tube, by comprising:
a binder,
a fluorine addition agent
a solid lubricant, and
a rust proof addition agent;
characterized in that:
the binder comprises:
an ethylene-vinyl acetate resin,
a polyolefin resin, and
a wax having a fusing point of 110° C. or less;
a ratio of a mass of the ethylene-vinyl acetate resin to a mass of the polyolefin resin is from 1.0 to 1.8; and
a ratio of a total mass of the polyolefin resin and the ethylene-vinyl acetate resin to a mass of the wax is from 0.7 to 1.6.
2. The composition according to claim 1 , comprising:
60 to 80% by mass of the binder,
8 to 18% by mass of the fluorine addition agent,
5 to 15% by mass of the solid lubricant, and
2 to 10% by mass of the rust proof addition agent.
3. The composition according to claim 1 , further comprising 2 to 15% by mass of talc.
4. The composition according to claim 2 , further comprising 2 to 15% by mass of talc.
5. The composition according to claim 3 , wherein
a particle size of the talc is 1 to 12 μm, and a specific surface area of the talc is 4 to 12 m 2 /g.
6. The composition according to claim 4 , wherein
a particle size of the talc is 1 to 12 μm, and a specific surface area of the talc is 4 to 12 m 2 /g.
7. A threaded connection for pipe or tube comprising a pin and a box, wherein
each of the pin and the box comprises a contact surface including a mutually contacting portion, and the threaded connection for pipe or tube comprises a solid lubricating coating on the contact surface of at least one of the pin and the box;
the solid lubricating coating comprises:
a binder,
a fluorine addition agent,
a solid lubricant, and
a rust proof addition agent;
the binder comprises:
an ethylene-vinyl acetate resin,
a polyolefin resin, and
a wax having a fusing point of 110° C. or less;
a ratio of a mass of the ethylene-vinyl acetate resin to a mass of the polyolefin resin is from 1.0 to 1.8; and
a ratio of a total mass of the polyolefin resin and the ethylene-vinyl acetate resin to a mass of the wax is from 0.7 to 1.6.
8. The threaded connection for pipe or tube according to claim 7 , wherein
the solid lubricating coating comprises:
60 to 80% by mass of the binder,
8 to 18% by mass of the fluorine addition agent,
5 to 15% by mass of the solid lubricant, and
2 to 10% by mass of the rust proof addition agent.
9. The threaded connection for pipe or tube according to claim 7 , wherein
the solid lubricating coating further comprises 2 to 15% by mass of talc.
10. The threaded connection for pipe or tube according to claim 8 , wherein
the solid lubricating coating further comprises 2 to 15% by mass of talc.
11. The threaded connection for pipe or tube according to claim 9 , wherein
a particle size of the talc is 1 to 12 μm, and a specific surface area of the talc is 4 to 12 m 2 /g.
12. The threaded connection for pipe or tube according to claim 10 , wherein
a particle size of the talc is 1 to 12 μm, and a specific surface area of the talc is 4 to 12 m 2 /g.
13. The threaded connection for pipe or tube according to claim 7 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
14. The threaded connection for pipe or tube according to claim 8 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
15. The threaded connection for pipe or tube according to claim 9 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
16. The threaded connection for pipe or tube according to claim 10 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
17. The threaded connection for pipe or tube according to claim 11 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
18. The threaded connection for pipe or tube according to claim 12 , further comprising:
a solid anticorrosive coating comprising an ultraviolet curing resin, wherein
the solid lubricating coating is formed on the contact surface of one of the pin and the box, and the solid anticorrosive coating is formed on the contact surface of the other of the pin and the box.
19. The threaded connection for pipe or tube according to claim 13 , wherein
a thickness of the solid anticorrosive coating is 5 to 50 μm.
20. The threaded connection for pipe or tube according to claim 7 , wherein
a thickness of the solid lubricating coating is 10 to 200 μm.
21. The threaded connection for pipe or tube according to claim 7 , wherein
the threaded connection for pipe or tube is used for an oil well pipe.
22. A method of producing a threaded connection for pipe or tube comprising a pin and a box, each of the pin and the box comprising a contact surface including a mutually contacting portion, the threaded connection for pipe or tube further comprising a solid lubricating coating on the contact surface of at least one of the pin and the box, the method comprising:
a step of applying a composition according to claim 1 onto the contact surface to form the solid lubricating coating on the contact surface.
23. The method of producing a threaded connection for pipe or tube according to claim 22 , wherein
in the step of forming the solid lubricating coating, forming the solid lubricating coating on the contact surface of one of the pin and the box,
the method further comprising:
a step of applying a composition for a solid anticorrosive coating including a ultraviolet curing resin onto the contact surface of the other of the pin and the box, and
a step of irradiating ultraviolet rays onto the composition for the solid anticorrosive coating that is applied to form the solid anticorrosive coating.