IP Library Granted Patent US 9,862,785
Granted Patent B2
US 9,862,785 · App. 15/126,096 · Granted Jan 9, 2018

Method for producing olefin polymer

Inventors: Tatsuya Chiba (Tokyo, JP); Koichi Sato (Tokyo, JP); Teruhisa Kuroki (Tokyo, JP); Ryuichiro Furusawa (Tokyo, JP); Takeshi Omata (Tokyo, JP)
Assignee: JX NIPPON OIL & ENERGY CORPORATION
C08F110/10C08F2500/03
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Quick Facts
Patent No.
US 9,862,785
App. No.
15/126,096
Granted
Jan 9, 2018
Kind
B2
Abstract

A method for producing an olefin polymer, in which an olefin compound is polymerized in the presence of a Lewis acid catalyst at a temperature of 0° C. or lower to obtain an olefin polymer, the method comprising a step of feeding a raw material liquid including the olefin compound to a reactor provided with a cooling unit, a step of polymerizing the olefin compound in the reactor to obtain a reaction liquid including the olefin polymer, a deactivation step of adding a deactivator to the reaction liquid taken out from the reactor to deactivate the Lewis acid catalyst, and a step of supplying the reaction liquid after the deactivation step to a cold recovery unit to recover cold from the reaction liquid, wherein the amount of the Lewis acid catalyst is 0.5×10 −3 to 1.0×10 −1 mol % based on the total amount of the olefin compound.

Claims (14)

1. A method for producing an olefin polymer, in which an olefin compound is polymerized in the presence of a Lewis acid catalyst at a temperature of 0° C. or lower to obtain an olefin polymer, the method comprising:

a feeding step of feeding a raw material liquid including the olefin compound to a reactor provided with a cooling unit;

a polymerization step of polymerizing the olefin compound in the reactor to obtain a reaction liquid including the olefin polymer;

a deactivation step of adding a deactivator to the reaction liquid taken out from the reactor to deactivate the Lewis acid catalyst; and

a cold recovery step of supplying the reaction liquid after the deactivation step to a cold recovery unit to recover cold from the reaction liquid,

wherein an amount of the Lewis acid catalyst is 0.5×10 −3 to 1.0×10 −1 mol % based on a total amount of the olefin compound.

2. The method according to claim 1 , wherein the Lewis acid catalyst is an aluminum compound represented by the following formula (1) or (2):

Al(R) m (X) (3-m)   (1)

Al 2 (R) n (X) (6-m)   (2)

wherein R represents an alkyl group having 1 to 8 carbon atoms, X represents a halogen atom, m represents 1 or 2, and n represents any integer of 1 to 5.

3. The method according to claim 1 , wherein the amount of the Lewis acid catalyst is 0.5×10 −3 to 0.3×10 −2 mol % based on the total amount of the olefin compound.

4. The method according to claim 1 , wherein the raw material liquid to be fed to the reactor is cooled in advance by the cold recovered in the cold recovery unit.

5. The method according to claim 1 , wherein the olefin compound includes isobutene.

6. The method according to claim 1 , wherein the deactivator includes water or an alcohol compound.

Assignments (3)
CHANGE OF NAME Recorded Aug 25, 2020
From: JXTG NIPPON OIL ENERGY CORPORATION
To: ENEOS CORPORATION
Reel/Frame 053596/0282 →
CHANGE OF NAME Recorded Jun 15, 2018
From: JX NIPPON OIL & ENERGY CORPORATION
To: JXTG NIPPON OIL & ENERGY CORPORATION
Reel/Frame 046634/0132 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 19, 2016
From: CHIBA, TATSUYA; SATO, KOICHI; KUROKI, TERUHISA; FURUSAWA, RYUICHIRO; OMATA, TAKESHI
To: JX NIPPON OIL & ENERGY CORPORATION
Reel/Frame 040062/0970 →
Priority Claims (1)
JP 2014-056213 · Mar 19, 2014 · national
Continuity (1)
Related Publication 20170107311A1 · Apr 20, 2017